全文获取类型
收费全文 | 1350篇 |
免费 | 39篇 |
国内免费 | 5篇 |
专业分类
电工技术 | 22篇 |
综合类 | 2篇 |
化学工业 | 269篇 |
金属工艺 | 31篇 |
机械仪表 | 24篇 |
建筑科学 | 56篇 |
能源动力 | 99篇 |
轻工业 | 97篇 |
水利工程 | 18篇 |
石油天然气 | 15篇 |
无线电 | 216篇 |
一般工业技术 | 276篇 |
冶金工业 | 101篇 |
原子能技术 | 3篇 |
自动化技术 | 165篇 |
出版年
2024年 | 5篇 |
2023年 | 20篇 |
2022年 | 35篇 |
2021年 | 75篇 |
2020年 | 46篇 |
2019年 | 42篇 |
2018年 | 65篇 |
2017年 | 42篇 |
2016年 | 46篇 |
2015年 | 37篇 |
2014年 | 68篇 |
2013年 | 103篇 |
2012年 | 77篇 |
2011年 | 79篇 |
2010年 | 68篇 |
2009年 | 61篇 |
2008年 | 55篇 |
2007年 | 49篇 |
2006年 | 51篇 |
2005年 | 36篇 |
2004年 | 26篇 |
2003年 | 30篇 |
2002年 | 21篇 |
2001年 | 16篇 |
2000年 | 16篇 |
1999年 | 17篇 |
1998年 | 29篇 |
1997年 | 21篇 |
1996年 | 21篇 |
1995年 | 8篇 |
1994年 | 9篇 |
1993年 | 5篇 |
1992年 | 12篇 |
1991年 | 5篇 |
1989年 | 6篇 |
1987年 | 6篇 |
1986年 | 13篇 |
1985年 | 11篇 |
1984年 | 4篇 |
1983年 | 5篇 |
1981年 | 5篇 |
1980年 | 7篇 |
1979年 | 7篇 |
1978年 | 4篇 |
1977年 | 4篇 |
1976年 | 7篇 |
1972年 | 2篇 |
1971年 | 2篇 |
1970年 | 3篇 |
1969年 | 2篇 |
排序方式: 共有1394条查询结果,搜索用时 31 毫秒
51.
This paper presents a resistance-based hydrogen gas sensor using polyaniline (emeraldine)/TiO2 nanocomposite (PT–NC) thin film. It is demonstrated that different gas sensing features can arise when various TiO2 phases (anatase and rutile) are applied. The different wt% of TiO2 phases were dispersed into an acidic solution of aniline monomers and PT–NCs were synthesized by an in-situ self-assembly chemical oxidative polymerization method of aniline. PT–NCs deposited on an epoxy glass substrate having Cu-interdigited electrodes for hydrogen gas sensing at air pressure and room temperature. Our results show that the better sensitivity of the sensor strongly depends on the sensor surface morphology and its components. Furthermore, hydrogen gas sensing mechanism of the sensor based contact areas between Pani chains and TiO2 grains was studied. 相似文献
52.
53.
54.
Mohammad Maududul Huq Md. Robiur Rahman Masnun Naher Mohammad Mizanur Rahman Khan Mostafa Kamal Masud Golam Mohammad Golzar Hossain Nianyong Zhu Yih Hsing Lo Muhammad Younus Wai-Yeung Wong 《Journal of Inorganic and Organometallic Polymers and Materials》2016,26(6):1243-1252
Two palladium(II) nitroaryl complexes trans-[bromo(p-nitrophenyl)bis(triphenylphosphine)palladium(II)] 1 and trans-[bromo(2,4-dinitrophenyl)bis(triphenylphosphine)palladium(II)] 2 have been synthesized. The complexes were characterized by FTIR and NMR (1H, 13C and 31P) spectroscopy and elemental analysis. The molecular structure of complex 2, as confirmed by X-ray crystallography, reveals that the Pd atom and its neighboring groups (two PPh3, Br and phenylene group) lie in a slightly distorted square plane. In the UV–Vis spectra of the complexes 1 and 2, the palladium to aryl charge transfer bands were observed. The emission peaks from the singlet excited states (S1 → S0) were observed in the photoluminescence spectra of the complexes. The thermal stability of the complexes has been studied by thermal gravimetric analysis (TGA). TGA data showed that both complexes are thermally stable up to 200 °C, and complex 1 is more stable than 2. The catalytic efficiency of the new palladium(II) complexes was studied as demonstrated using the Sonogashira coupling reactions with good yields. The experimental results suggest that the Sonogashira coupling reactions can be performed at moderate temperature (50 °C) using these new palladium(II) complexes as catalysts. 相似文献
55.
N. E. Wijeysundera M. N. A. Hawlader Chan Wee Boon Andy M. Kamal Hossain 《International Journal of Refrigeration》2004,27(5):1997
An ice slurry generation system was developed using direct contact heat transfer between water and the coolant, Fluroinert FC-84. The location of the coolant nozzle is an important design consideration to avoid clogging due to freezing of water. An ice fraction of up to about 40 percent was obtained with the nozzle located at the bottom of the ice slurry tank and the jet directed upwards into the water. Two simplified model were developed to extract the heat transfer coefficient between the coolant drops and the water. The first model requires as input the average drop diameter and the residence time while the second model uses the measured drop diameter distribution. The estimated heat transfer coefficients are much smaller than those computed using single-sphere correlations. 相似文献
56.
High quality organic-inorganic heterojunction photodiodes based on nanostructured copper (II) phthalocyanine (CuPc) and intrinsic zinc oxide (i-ZnO) have been fabricated. The i-ZnO thin films/layers were grown by RF magnetron sputtering on clean indium tin oxide (ITO) coated glass substrates. These films have been characterized by optical absorption and field emission scanning electron microscopy (FESEM). CuPc thin films deposited at room temperature on i-ZnO have exhibited a change in their surface morphology with the post-deposition annealing temperature under normal atmosphere. The electrical dark conductivity and the photoconductivity of ITO/i-ZnO/CuPc/Au sandwich structures have been measured under various photoexcitation intensities using a xenon light source. The devices have shown excellent reproducibility of their electrical characteristics and high rectification ratios. The highest rectification ratio is nearly 831 calculated above the threshold voltage at room temperature for the sample annealed at 250?°C (i.e.?Pc 250). The effects of the annealing temperature of CuPc on the surface morphology, rectification ratio, and optical properties have been discussed. 相似文献
57.
Daichi Yazaki Tokuhisa Kawawaki Daisuke Hirayama Masanobu Kawachi Kosaku Kato Sota Oguchi Yuichi Yamaguchi Soichi Kikkawa Yoshiya Ueki Sakiat Hossain D. J. Osborn Fumihiko Ozaki Shunsuke Tanaka Jun Yoshinobu Gregory F. Metha Seiji Yamazoe Akihiko Kudo Akira Yamakata Yuichi Negishi 《Small (Weinheim an der Bergstrasse, Germany)》2023,19(34):2208287
For the realization of a next-generation energy society, further improvement in the activity of water-splitting photocatalysts is essential. Platinum (Pt) is predicted to be the most effective cocatalyst for hydrogen evolution from water. However, when the number of active sites is increased by decreasing the particle size, the Pt cocatalyst is easily oxidized and thereby loses its activity. In this study, a method to load ultrafine, monodisperse, metallic Pt nanoclusters (NCs) on graphitic carbon nitride is developed, which is a promising visible-light-driven photocatalyst. In this photocatalyst, a part of the surface of the Pt NCs is protected by sulfur atoms, preventing oxidation. Consequently, the hydrogen-evolution activity per loading weight of Pt cocatalyst is significantly improved, 53 times, compared with that of a Pt-cocatalyst loaded photocatalyst by the conventional method. The developed method is also effective to enhance the overall water-splitting activity of other advanced photocatalysts such as SrTiO3 and BaLa4Ti4O15. 相似文献
58.
The aim of this paper was to predict the colour strength of viscose knitted fabrics by using fuzzy logic (FL) model based on dye concentration, salt concentration and alkali concentration as input variables. Moreover, the performance of fuzzy logic (FL) model is compared with that of artificial neural network (ANN) model. In addition, same parameters and data have been used in ANN model. From the experimental study, it was found that dye concentration has the main and greatest effects on the colour strength of viscose knitted fabrics. The coefficient of determination (R2), root mean square (RMS) and mean absolute errors (MAE) between the experimental colour strength and that predicted by FL model are found to be 0.977, 1.025 and 4.61%, respectively. Further, the coefficient of determination (R2), root mean square (RMS) and mean absolute errors (MAE) between the experimental colour strength and that predicted by ANN model are found to be 0.992, 0.726 and 3.28%, respectively. It was found that both ANN and FL models have ability and accuracy to predict the fabric colour strength effectively in non-linear domain. However, ANN prediction model shows higher prediction accuracy than that of Fuzzy model. 相似文献
59.
Kensey Daly Shahryar K. Ahmad Matthew Bonnema Claire Beveridge Faisal Hossain Bart Nijssen Gordon Holtgrieve 《Lakes & Reservoirs: Research and Management》2020,25(2):133-142
Tonle Sap Lake in Cambodia is arguably the world's most productive freshwater ecosystems, as well as the dominant source of animal protein for the country. The rapid rise of hydropower schemes, deforestation, land development and climate change impacts in the Mekong River Basin, however, now represent serious concerns in regard to Tonle Sap Lake's ecological health and its role in future food security. To this end, the present study identifies significant recent warming of lake temperature and discusses how each of these anthropogenic perturbations in Tonle Sap's floodplain and the Mekong River Basin may be influencing this trend. The lake's dry season monthly average temperature increased by 0.03°C/year between 1988 and 2018, being largely in synchrony with warming trends of the local air temperature and upstream rivers. The impacts of deforestation and agriculture development in the lake's floodplain also exhibited a high correlation with an increased number of warm days observed in the lake, particularly in its southeast region (agriculture R2 = .61; deforestation R2 = .39). A total of 79 dams, resulting in 72 km3 of volumetric water capacity, were constructed between 2003 and 2018 in the Mekong River Basin. This dam development coincided with a decreasing trend in the number of dry season warm days per year in the lower Mekong River, while Tonle Sap Lake's number of dry season warm days continued to increase during this same period. The present study revealed that Tonle Sap Lake's temperature trends are highly influenced by temperature trends in the local climate, agriculture development and deforestation of the lake's watershed. Although there were no noticeable impacts observed from upstream dam development in the Mekong River Basin, local‐to‐regional agricultural and land management of the lake's watershed appear to be effective strategies for maintaining a stable thermal regime in the lake in order to facilitate maximum ecosystem health. 相似文献
60.
Thupakula U Khan AH Bal JK Ariga K Acharya S 《Journal of nanoscience and nanotechnology》2011,11(9):7709-7714
We report on the synthesis of CdSe nanocrystal quantum dots (QDs) of different radii (R). Size dependent optical properties like increase in the confinement energy with decreasing radius for different excitonic transitions are studied. Different excitonic transitions are calculated from the second derivative of UV-vis absorption spectra of as synthesized CdSe QDs. The transitions are assigned to specific states by calculating the transition energies using effective mass approximation. A close matching of the transition energies with the experiment suggesting that the second derivative of the absorption spectra could provide a direct knowledge of the electronic transition for the direct band gap semiconductor quantum dots. 相似文献