Effect of HBT on the stability of laccase during the decolourization of textile wastewaters

BACKGROUND: This study concerns the assessment of laccase stability during textile industry effluent treatment by laccase in the presence of a mediator RESULTS: The effects of 1‐hydroxybenzotriazole (HBT) and textile wastewater on the stability of a crude laccase prepared from cultures of Trametes trogii during the process of textile industry effluent decolourization were determined. HBT was essential for decolourization of effluent by laccase. Decolourization efficiency decreased when effluent was repeatedly added to the reaction mixture, suggesting inhibition of laccase during the process. Stability of the laccase was not affected by different concentrations of effluent, but inactivation was proportional to HBT concentration. CONCLUSION: Experimental results showed that a redox mediator such as HBT was required for high decolourization rate of textile industry effluent; however free radicals generated from this compound inactivated the laccase used in the process. Copyright © 2009 Society of Chemical Industry     

Live Load Distribution in Girder Bridges Subject to Oversized Trucks

A significant challenge facing motor carriers and engineers in this nation is the limitation of vehicle size and weight based on pavement and bridge capacity. However, the current demands of society and industry occasionally require a truck to carry a load that exceeds the size and weight of the legal limit. In these cases, engineering analysis is required before a permit is issued to ensure the safety of the structures and roadways on the vehicle's route. A truck with a wheel gauge larger than the standard 1.83 m (6 ft) gauge requires additional engineering effort because the wheel load girder distribution factors (GDFs) established by AASHTO cannot be used to accurately estimate the live load in the girders. In this study, the finite-element method is used to develop modification factors for the AASHTO flexure and shear GDFs to account for oversized trucks. The results of the analysis showed that the use of the proposed modification factors with the specification-based GDFs can help increase the allowable loads on slab-on-girder bridges.     

Comprehensive ESD protection for RF inputs

We demonstrate that narrow-band tuned circuits may be used for ESD protection of RF inputs, and a figure of merit for optimization of these circuits is presented. The performance of the ESD-protected RF circuit is dependent on the quality factor of the ESD device, and various protection devices are evaluated in this work. Record-breaking human body model (HBM) protection levels, exceeding 5 kV, have been achieved without significantly degrading the RF performance at 5 GHz. Broadband circuit protection is also addressed.     

A comparison analysis of prefiltering methods in space-time trellis-based reduced-state turbo-detection

In this paper, we investigate two different prefiltering strategies, i.e., multiple input multiple output (MIMO) channel shortening and MIMO whitened matched filtering, to decode iteratively a space time bit interleaved coded modulation transmitted over MIMO block fading intersymbol interference channels using a trellis-based post-detector. Indeed, resorting to such front-ends allows significant complexity gain when compared to the optimal maximum a posteriori-based turbo-receiver. While those two approaches have been exhaustively visited in the past, their fair comparison in terms of trade-off between complexity and performance has – to our knowledge – never been tackled before. This paper aims at giving some valuable insights about the respective benefits of these two prefiltering methods with respect to the channel characteristics and overall receiver complexity.     

Transient electromagnetic field of a vertical magnetic dipole on atwo-layer conducting Earth

The transient field-frequency domain of magnetic dipole in a two-layered conducting Earth has been studied. It is obtained as a summation of waveguide modes plus contributions from branch cuts in the complex-plane of the longitudinal wave number. Results can be used to evaluate numerical solutions of more complicated modeling algorithms     

Synthesis and rheological properties of an associative star polymer in aqueous solutions

Rheological properties of aqueous solutions and hydrogels formed by an amphiphilic star block copolymer, poly(acrylic acid)-block-polystyrene (PAA₅₄-b-PS₆)₄, were investigated as a function of the polymer concentration (C_p), temperature, and added salt concentration. The water-soluble polymer synthesised by atom transfer radical polymerization (ATRP) was found to form hydrogels at room temperature at polymer concentrations, C_p, over 22 g/L due to the interpolymer hydrophobic association of the PS blocks. Increasing C_p leads to stronger elastic networks at room temperature that show a gel-to-solution transition with increasing temperature. Increase of ionic strength decreases the moduli compared with the pure hydrogel but did not affect the gel-sol transition temperature significantly. Small-angle X-ray experiments showed two distinct scattering correlation peaks for samples above the gelling C_p, which indicates the aggregates formed due to hydrophobic association. Upon heating the intensity of the scattering correlation peaks was found to decrease indicating the loss of the network structure due to thermal motion.     

Flexural Behavior of Concrete-Filled Fiber-Reinforced Polymer Circular Tubes

This paper presents the experimental results of large-scale concrete-filled glass fiber reinforced polymer (GFRP) circular tubes and control hollow GFRP and steel tubes tested in bending. The diameter of the beams ranged from 89 to 942 mm and the spans ranged from 1.07 to 10.4 m. The study investigated the effects of concrete filling, cross-sectional configurations including tubes with a central hole, tube-in-tube with concrete filling in between, and different laminate structures of the GFRP tubes. The study demonstrated the benefits of concrete filling, and showed that a higher strength-to-weight ratio can be achieved by providing a central hole. The results indicated that the flexural behavior is highly dependent on the stiffness and diameter-to-thickness ratio of the tube, and, to a much less extent, on the concrete strength. Test results suggest that the contribution of concrete confinement to the flexural strength is insignificant; however, the ductility of the member is improved. A strain compatibility model has been developed, verified by the experimental results, and used to provide a parametric study of the different parameters, significantly affecting the behavior. The parametric study covered a wide range of FRP sections filled with concrete, including under-reinforced, balanced, and over-reinforced sections.     

The role of human factors in flexibility management: A survey

Flexibility can be defined as the ability to respond effectively to the ever‐changing and increasing needs of the customer. For this demand to be satisfied, flexibility should be built into the total chain of acquisition, processing, and distribution stages. As a result, there is an increasing interest in flexibility and flexibility enabling mechanisms/parameters to achieve the best strategy for obtaining the right and desired output. Although quite a number of flexibility definitions and mechanisms can be found in the literature, flexibility remains poorly understood and utilized in practice. That is due to the lack of standardization in the terminology about the flexibility definitions and mechanisms. This article presents the finding of an extensive literature survey to determine the Intra flexibility mechanisms/parameters. These mechanisms/parameters are then classified, according to their contribution to the supply chain stages and their interaction with Inter Flexibility mechanisms (e.g., Organizational structure flexibility, Technology flexibility, Information system flexibility, and Human resource flexibility). In addition, the crucial role of human factors and its relationship with flexibility mechanisms are investigated, and related flexibility mechanisms are identified. © 2002 John Wiley & Sons, Inc.     

Determination of flavan-3-ols and trans-resveratrol in grapes and wine using HPLC with fluorescence detection

Concentrations of trans-resveratrol, catechin and epicatechin were analyzed in musts and wines produced from seven red and four white grape cultivars from various wine growing regions of Turkey. Phenolics were quantified using an HPLC method optimized for the separation of wine phenolics. Wine samples contained higher phenolics levels than the corresponding musts. With the exception of Semillion, white wines and musts contained lower concentrations of phenolics than red wines and musts. However, the white cultivar Semillion had the highest concentrations of catechin and epicatechin among all wine and must samples. Semillion wine catechin and epicatechin were 13.7 and 11.8 mg/L, respectively. The highest level of trans-resveratrol among the white cultivars was found in Narince wine (1.93 mg/L). Within the red wine and must cultivars, Bo?azkere, Öküzgozü, and Cabernet contained the highest concentrations of flavan-3-ols and trans-resveratrol. Catechin was the major phenolic in all wines and most musts. Epicatechin was the major phenolic in 6 of the 11 must samples, but none of the wine samples. trans-Resveratrol was generally found in lowest concentrations in both wines and musts.     

Temperature modeling and measurement of an electrokinetic separation chip

This work presents experimental [infrared (IR) thermography] and computational (finite element model) results of temperature distributions of an electrokinetic separation chip. Thermal characteristics of both the electrolyte solution and the polymer chip (SU-8) are taken into account in modeling temperature distributions during electrokinetic flow. Multiphysics and multiscale simulation couples electrostatics, heat transfer, and fluid dynamics. The accompanying IR thermography is a non-contact method, which can measure fractional temperature differences with sub-second time resolution. Any structures or temperature marker molecules interfering with the experiment are not needed. Nominal spot size in the IR measurements is 30 μm with a field of view of several millimeters enabling both local and chip-scale temperature monitoring simultaneously. As a result, we present a computer model for electrokinetic chips, which enables simulation of fractional temperature changes during electrophoresis under real operating conditions. The accuracy of the model is within ±1°C when the deviation in electrochemical processes is taken into account. The simulation results also suggest that the temperature on the chip surface qualitatively reflects the temperature inside the microchannel with an average offset of 1–2°C.