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101.
Micheline Abbas Amélie Pouplin Olivier Masbernat Alain Liné Sandrine Décarre 《American Institute of Chemical Engineers》2017,63(11):5182-5195
The flow field of a 70% concentrated noncolloidal o/w emulsion in a pipe has been investigated by means of Particle Image Velocimetry in a matched refractive index medium. At steady state and in laminar regime, the shape of axial velocity profiles is not parabolic and exhibits a shear‐thinning behavior of the dense emulsion, with a flow index of 0.5 and a negligible yield stress (less than 1 Pa). However, instead of a square root law, the pressure drop increases linearly with Um. To explain this apparent inconsistency, two mechanisms of different nature are considered. The first originates from a possible relation between the consistency factor and the drop mean diameter. The second mechanism is shear‐induced migration and leads to the development of a concentration gradient in the pipe cross section. Both mechanisms considered reconcile the experimental data, the apparent local shear‐thinning behavior and the linear evolution of the pressure drop with the flow rate. © 2017 American Institute of Chemical Engineers AIChE J, 2017 相似文献
102.
This work was aimed at studying the emulsification efficiency of graft copolymers and the effect of feeding mode on the emulsification efficiency using the emulsification curve approach. The blends were composed of polystyrene (PS) and polyamide 6 (PA6). PS was always the matrix and PA6 the dispersed phase. A series of graft copolymers of PS and PA6, denoted as PS-g-PA6, with different molecular structures were used as emulsifiers. Feeding mode had a very significant effect on the size of the dispersed phase domains at short mixing time and its effect decreased or became negligible at long mixing time. This indicates that feeding mode affected mostly the time necessary for the PS-g-PA6 emulsifier to reach and emulsify the PS/PA6 interfaces. The molecular structure of the PS-g-PA6 graft copolymer also had a profound effect on its emulsification efficiency. The longer the PA6 grafts (from 1.7 to 5.1 kg/mol), the higher the emulsification efficiency. On the other hand, the number of PA6 grafts had little effect on the emulsification efficiency when the PA6 grafts were short (1.6-1.7 kg/mol). The effect of the blend composition was also investigated. 相似文献
103.
Patrice Mélé Sandrine MarceauDavid Brown Yves de PuydtNicole Dominique Albérola 《Polymer》2002,43(20):5577-5586
A quantitative morphological analysis has been performed using AFM and SAXS measurements in order to determine the spatial distribution of fillers in silica SBR composites. The proportion of fillers in agglomerates or aggregates of silica has thus been separated. Additional measurements have been carried out to quantify the amount of modified polymer in the vicinity of the filler surface, i.e. the bound rubber. It is shown that the reinforcing phase, constituting both silica particles and bound rubber, can be considered either as the dispersed or the continuous phase depending on the filler content.The linear dynamic mechanical properties of composites are then analysed. The variations of the shear modulus as a function of the filler content are then related to either the reinforcement effect induced by fillers or the development of specific additional interactions between phases, i.e. the interface effects. To separate the respective contribution of these effects from the overall dynamic behaviour of composites, micromechanical modelling is then performed. In a first step, the viscoelasticity of composites reinforced by 5.7 vol% of silica is predicted with the help of Christensen and Lo's model. For composites filled with 10 and 15 vol% of silica, self-consistent modelling, applied in a reverse mode, confirmed that the reinforcing phase, i.e. silica particles and bound rubber, acts as the continuous phase, in agreement with the morphological analysis. From the predicted dynamic mechanical properties of the reinforcing phase, the bound rubber behaviour is thus extracted as a function of the filler content and compared to that of unfilled SBR. 相似文献
104.
105.
Marie-Noëlle de Noirfontaine Sandrine Tusseau-Nenez Marcel Signes-Frehel Gilles Gasecki Caroline Girod-Labianca 《Journal of the American Ceramic Society》2009,92(10):2337-2344
Alite is the major compound of anhydrous Portland cement: it is composed of tricalcium silicate Ca3 SiO5 (C3 S) modified in composition and crystal structure by ionic substitutions. Alite is also the main hydraulic phase of cement and the most important for subsequent strength development. Using raw meals (rich in Ca3 P2 O8 ) as alternative fuels in cement plants raises the question about the effect of phosphorus on C3 S and its consequences on reactivity with water. This paper deals with a systematic study of C3 S triclinic T1 polymorph doped with P2 O5 in the range 0–0.9 wt%. All the samples were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), and electron-microprobe analysis. The appearance of a phase rich in phosphorus is shown. It displays a structure derivative of the α'H –Ca2 SiO4 polymorph, noted α'H –C2 S(P). As phosphorus content increases, C3 S is more and more decomposed into free lime and α'H –C2 S(P). The α'H phase was detected from 0.1 wt% P2 O5 and located at the interfaces of C3 S grains. Two identification keys are proposed in order to highlight the α'H –C2 S(P) phase: the XRD angular window at 2θCu =32.8°–33.2° and a smooth aspect on SEM micrographs. 相似文献
106.
Guillaume BonnefontGilbert Fantozzi Sandrine TrombertLionel Bonneau 《Ceramics International》2012,38(1):131-140
A high transmittance/small grain size combination for pure spinel ceramics from commercially available nanopowders without sintering aids can be obtained by SPS sintering. By using a low heating rate ≤10 °C/min and a sintering temperature ≤1300 °C, a transparent polycrystalline MgAl2O4 spinel was fabricated by SPS with an in-line transmission of 74% and 84% for 550 nm (visible) and 2000 nm (NIR) wavelengths respectively. A small average grain size of about 250 nm was obtained and the pores located at the multiple grain junctions have a mean size of about 20 nm. The high in-line transmission is linked not only to the low residual porosity but particularly to the very small size of pores. 相似文献
107.
Florent Monestier Jean-Jacques Simon Philippe Torchio Ludovic Escoubas Franois Flory Sandrine Bailly Remi de Bettignies Stephane Guillerez Christophe Defranoux 《Solar Energy Materials & Solar Cells》2007,91(5):405-410
We have investigated the short-circuit current density of organic solar cells based on poly (3-hexylthiophene)(P3HT)/6,6-phenyl C61-butyric acid methyl ester (PCBM) blend. In order to model charge collection efficiencies with respect to short circuit density in such blends, a full optical modeling of the cell is performed. From the distribution of the electromagnetic field, we compute the rate of exciton generation. This exciton generation rate is used as input in the transport equations of holes and electrons. Charge densities at steady state are obtained as solutions are used for computing short-circuit current densities generated in the cell. The dependence of short-circuit current densities versus the thickness of the blend is analyzed and compared with our experimental data and with data extracted from the literature. 相似文献
108.
Sophie Dulon Sandrine Parot Marie-Line Delia Alain Bergel 《Journal of Applied Electrochemistry》2007,37(1):173-179
This work demonstrates that electrochemical reactions can be catalysed by the natural biofilms that form on electrode surfaces
dipping into drinking water or compost. In drinking water, oxygen reduction was monitored with stainless steel ultra-microelectrodes
under constant potential electrolysis at −0.30 V/SCE for 13 days. 16 independent experiments were conducted in drinking water,
either pure or with the addition of acetate or dextrose. In most cases, the current increased and reached 1.5–9.5 times the
initial current. The current increase was attributed to biofilm forming on the electrode in a similar way to that has been
observed in seawater. Epifluorescence microscopy showed that the bacteria size and the biofilm morphology depended on the
nutrients added, but no quantitative correlation between biofilm morphology and current was established. In compost, the oxidation
process was investigated using a titanium based electrode under constant polarisation in the range 0.10–0.70 V/SCE. It was
demonstrated that the indigenous micro-organisms were responsible for the current increase observed after a few days, up to
60 mA m−2. Adding 10 mm acetate to the compost amplified the current density to 145 mA m−2 at 0.50 V/SCE. The study suggests that many natural environments, other than marine sediments, waste waters and seawaters
that have been predominantly investigated until now, may be able to produce electrochemically active biofilms. 相似文献
109.
Neill Taylor Sergio Ciattaglia Pierre Cortes Markus Iseli Sandrine Rosanvallon Leonid Topilski 《Fusion Engineering and Design》2012,87(5-6):476-481
Safety files were submitted by the ITER Organization to the French nuclear safety authorities in March 2010 as a part of the licensing process. These included the preliminary safety report (RPrS) which presents the extensive safety analyses performed for ITER. The report has been the subject of examination by the authorities and their advisors, and discussions with them have been held on many topics. In the light of this process, this paper discusses some of the topics that remain prominent in the safety analysis of ITER. In particular, the provision of the two safety functions, confinement of radioactive material and limitation of exposure to radiation, is explained and some of the potential challenges to them are identified. Amongst these are the risks of fire and explosion, and external events such as earthquake and loss of all electric power. Provisions in the ITER design, together with the characteristics of fusion, ensure that a very good safety performance will be achieved. 相似文献
110.
Sandrine Bourlot Philippe Blanchard Stéphanie Robert 《Journal of power sources》2011,196(16):6841-6846
High power lithium-ion batteries need to exhibit long service life to meet targets of automotive applications. This article describes the deep investigation of the so-called VL6P cells, high power lithium-ion cells mass produced by Johnson Controls - Saft (JC-S), in order to understand the root causes of their aging. Cells aged by calendar and cycle life are investigated here compared to fresh cells. Among the results of the different analyses, the most significant is that more active lithium is detected in negative electrode after aging. This tends to indicate that effect of aging is due to increase of positive electrode limitation. Results of this investigation will allow JC-S to continue to improve life of the lithium-ion cells. 相似文献