Chloroform Hydrodechlorination on Palladium Surfaces: A Comparative DFT Study on Pd(111), Pd(100), and Pd(211)

Topics in Catalysis - Palladium has been shown to be an effective catalyst for chloroform hydrodechlorination, which serves as a promising treatment method for industrial chloroform waste. To...     

Geospatial technology applied to spatiotemporal assessment of Harike Wetland,Punjab

The Harike Wetland situated in Punjab is a Ramsar site and a wetland of national importance. The present study was undertaken to assess the spatiotemporal dynamics of the wetland on the basis of geospatial technology and ground‐based studies. Landsat images for the years 2002 and 2014 were acquired from the United States Geological Survey and classified digitally to generate landuse/land cover maps involving four classes (water, grassland (including water hyacinth), agriculture, built‐up (settlement), barren land). The total area of the Harike Wetland was found to be 8023.68 ha. Water sampling at eleven sites was carried out and evaluated for physicochemical parameters. The water quality at several sampling points was found to be severely degraded. Change detection analysis revealed the submerged area (area under water) and grassland (including water hyacinth) had decreased over the past 12 years, whereas that area under agriculture and built‐up land has increased, indicating a shrinkage in the total wetland area. The present study also indicated that the near‐infrared band is a good indicator of water quality parameters, as indicated by the significant positive correlation between the near‐infrared band and relevant water parameters. Because the wetland is important from both an ecological perspective and economic perspective, regular monitoring is recommended, for which geospatial technology has proven to be very useful.     

Characterization and fracture behavior of bismuth–tin thermal fuse alloy wires produced by the Ohno continuous casting process

Bismuth–tin binary alloys containing high bismuth concentrations of 40 to 77% were continuously cast into wires of approximately 2 mm in diameter with casting speeds between 15 and 150 mm min^?1 using the Ohno Continuous Casting (OCC) process. The microstructure was examined and tensile tests were performed for wires cast at various speeds. It was found that for slowly cast wires containing large primary bismuth dendrites, bismuth fracture occurring along the (111) plane exerted a key role in wire fracture, while microstructures with refined bismuth dendrites exhibited a mixture of bismuth cracks and inter-phase decohesion, allowing the accommodation of larger strain before wire fracture. For wires with microstructures containing primary tin dendrites, inter-phase decohesion played a key role in wire fracture.     

Acrylic acid–methyl methacrylate copolymer for oral prolonged drug release

Acrylic acid (AA)–methyl methacrylate (MMA) based copolymers, in different molar ratios (3:7, 4:6, 5:5, 6:4, and 7:3) were synthesized using tetrahydrofuran as solvent and AIBN as free radical initiator. Increase in acrylic acid concentration promoted pH-dependent swelling of copolymer and copolymer AA:MMA (3:7) was selected due to minimum swelling. ATR/FTIR and ¹H NMR spectra of the copolymer showed absence of vinyl bond/protons present in the monomers suggesting successful polymerization. The copolymer was hemocompatible. Flurbiprofen sodium microspheres made with the copolymer, by oil/oil solvent evaporation, were spherical, anionic (zeta potential −59.0 mV) and contained 4.53% drug. ATR spectrum of microspheres showed peaks for aromatic C=C stretching and substituted benzene ring, indicating entrapment of flurbiprofen. XRD analysis revealed crystalline structure of flurbiprofen while copolymer and microspheres were amorphous. DSC thermograms showed a sharp melting endotherm of flurbiprofen sodium at 129.26°C against broad endotherms of copolymer and microspheres having peaks at 82.24 and 86.59°C, respectively. The thermogram of microspheres did not show the melting peak of flurbiprofen. The microspheres exhibited no drug release at pH <6.8 and released 83.4 and 99% drug at pH 6.8 and 7.4 in 3 h. The microspheres did not adhere on gastric mucosa at pH 1.2 but showed mucoadhesion time of 28 min on intestinal mucosa at pH 6.8. Thus, the microspheres on oral administration, would release the drug in distal ileum, suggesting the potential of the hemocompatible copolymer for enteric coating for prolonged drug release.     

Cognitive Mapping and Planning for Visual Navigation

International Journal of Computer Vision - We introduce a neural architecture for navigation in novel environments. Our proposed architecture learns to map from first-person views and plans a...     

Varna-based optimization: a novel method for capacitated controller placement problem in SDN

Recently,software defined networking(SDN)is a promising paradigm shift that decouples the control plane from the data plane.It can centrally monitor and control the network through softwarization,i.e.,controller.Multiple controllers are a necessity of current SDN based WAN.Placing multiple controllers in an optimum way is known as controller placement problem(CPP).Earlier,solutions of CPP only concentrated on propagation latency but overlooked the capacity of controllers and the dynamic load on switches,which is a significant factor in real networks.In this paper,we develop a novel optimization algorithm named varna-based optimization(VBO)and use it to solve CPP.To the best of our knowledge,this is the first attempt to minimize the total average latency of SDN along with the implementation of TLBO and Jaya algorithms to solve CPP for all twelve possible scenarios.Our experimental results show that TLBO outperforms PSO,and VBO outperforms TLBO and Jaya algorithms in all scenarios for all topologies.     

A simple and efficient XFEM approach for 3-D cracks simulations

In this work, a simple and efficient XFEM approach has been presented to solve 3-D crack problems in linear elastic materials. In XFEM, displacement approximation is enriched by additional functions using the concept of partition of unity. In the proposed approach, a crack front is divided into a number of piecewise curve segments to avoid an iterative solution. A nearest point on the crack front from an arbitrary (Gauss) point is obtained for each crack segment. In crack front elements, the level set functions are approximated by higher order shape functions which assure the accurate modeling of the crack front. The values of stress intensity factors are obtained from XFEM solution by domain based interaction integral approach. Many benchmark crack problems are solved by the proposed XFEM approach. A convergence study has been conducted for few test problems. The results obtained by proposed XFEM approach are compared with the analytical/reference solutions.     

Aggregation in sensor networks: an energy–accuracy trade-off

Wireless ad hoc sensor networks (WASNs) are in need of the study of useful applications that will help the researchers view them as distributed physically coupled systems, a collective that estimates the physical environment, and not just energy-limited ad hoc networks. We develop this perspective using a large and interesting class of WASN applications called aggregation applications. In particular, we consider the challenging periodic aggregation problem where the WASN provides the user with periodic estimates of the environment, as opposed to simpler and previously studied snapshot aggregation problems. In periodic aggregation our approach allows the spatial–temporal correlation among values sensed at the various nodes to be exploited towards energy-efficient estimation of the aggregated value of interest. Our approach also creates a system level energy vs. accuracy knob whereby the more the estimation error that the user can tolerate, the less is the energy consumed. We present a distributed estimation algorithm that can be applied to explore the energy–accuracy subspace for a subclass of periodic aggregation problems, and present extensive simulation results that validate our approach. The resulting algorithm, apart from being more flexible in the energy–accuracy subspace and more robust, can also bring considerable energy savings for a typical accuracy requirement (fivefold decrease in energy consumption for 5% estimation error) compared to repeated snapshot aggregations.     

Parameterized algorithms for feedback set problems and their duals in tournaments

The parameterized feedback vertex (arc) set problem is to find whether there are k vertices (arcs) in a given graph whose removal makes the graph acyclic. The parameterized complexity of this problem in general directed graphs is a long standing open problem. We investigate the problems on tournaments, a well studied class of directed graphs. We consider both weighted and unweighted versions.     

Growth and characterizations of dual ion beam sputtered CIGS thin films for photovoltaic applications

The growth of CIGS thin films on soda-lime glass substrates at different substrate temperatures by dual ion beam sputtering system in a single-step route from a single quaternary sputtering target with the composition of Cu (In_0.70 Ga_0.30) Se₂ was reported. The effects of the substrate temperature on structural, optical, morphological and electrical properties of CIGS films were investigated. Stoichiometry of one such film was investigated by X-ray photoelectron spectroscopy. All CIGS films had demonstrated a strong (112) orientation located at 2θ ~26.70^o, which indicated the chalcopyrite structure of films. The value of full-width at half-maximum of (112) peak was reduced from 0.58° to 0.19° and crystallite size was enlarged from 14.98 to 43.05 nm as growth temperature was increased from 100 to 400 °C. However, atomic force microscope results showed a smooth and uniform surface at lower growth temperature and the surface roughness was observed to increase with increasing growth temperature. Hall measurements exhibited the minimum film resistivity of 0.09 Ω cm with a hole concentration of 2.42 × 10¹⁸ cm^?3 and mobility of 28.60 cm² V^?1 s^?1 for CIGS film grown at 100 °C. Film absorption coefficient was found to enhance nominally from 1 × 10⁵ to 2.3 × 10⁵ cm^?1 with increasing growth temperature from 100 to 400 °C.