Charge transfer in thin films of donor–acceptor complexes studied by infrared spectroscopy

The degree of charge transfer in thin films of organic charge transfer (CT)-complexes, which are deposited via thermal evaporation, is examined via infrared-spectroscopy. We demonstrate a linear relationship between the shift in the excitation energy of the CN-stretching mode of CT-complexes with the acceptor 7,7,8,8-tetracyanoquinodimethane (TCNQ) and the charge transfer. The measured correlation corresponds very well with DFT calculations. For Na-TCNQ we observe a splitting in the peak of the CN-stretching mode, which can be explained by the coupling of two modes and was confirmed by the calculations. In CT-complexes with partial charge transfer the appearance of an electronic excitation is demonstrated.     

Recycling von marinen Sekundärrohstoffen

As a waste product, oyster shells pose a major environmental pollution problem and the reuse of the material is becoming increasingly important. Since the comminution process in the recycling of secondary raw materials defines the properties of the material, oyster shells were grinded using a planetary ball mill and an impact mill and the fractions obtained were analyzed in terms of size and shape and compared with each other. A comminuted material from the impact mill was used for a series of wetting experiments, which helped to demonstrate the surface free energy of the material.     

High-Speed Trains Automatic Operation with Protection Constraints: A Resilient Nonlinear Gain-based Feedback Control Approach

This paper addresses the control design for automatic train operation of high-speed trains with protection constraints. A new resilient nonlinear gain-based feedback control approach is proposed, which is capable of guaranteeing, under some proper non-restrictive initial conditions, the protection constraints control raised by the distance-to-go (moving authority) curve and automatic train protection in practice. A new hyperbolic tangent function-based model is presented to mimic the whole operation process of high-speed trains. The proposed feedback control methods are easily implementable and computationally inexpensive because the presence of only two feedback gains guarantee satisfactory tracking performance and closed-loop stability, no adaptations of unknown parameters, function approximation of unknown nonlinearities, and attenuation of external disturbances in the proposed control strategies. Finally, rigorous proofs and comparative simulation results are given to demonstrate the effectiveness of the proposed approaches.      

Mo–Si–B alloys for ultra-high-temperature space and ground applications: liquid-assisted fabrication under various temperature and time conditions

Journal of Materials Science - Boron-doped molybdenum silicides have been already recognized as attractive candidates for space and ground ultra-high-temperature applications far beyond limits of...