The effects of soaking of whole, dehulled and ground millet and soybean seeds on phytate degradation and Phy/Fe and Phy/Zn molar ratios

The degradation and leaching of phytates, phytase activity and iron and zinc concentrations have been studied after soaking of whole seeds, dehulled seeds and flours of millet and soybean, in order to investigate the efficiency of soaking on reducing Phy/Fe and Phy/Zn molar ratios. When using millet grains, dehulling and milling before soaking facilitated the leaching of phytates and phytases in the aqueous medium and hence phytate degradation. Dehulling of soybean seeds led to a marked increase in phytate content, whereas milling favoured reactions between phytases and phytates. The Phy/Fe and Phy/Zn molar ratios decreased only slightly during soaking. The highest decreases for millet were obtained after soaking of flour for 8 h (Phy/Fe: 10.8–7.7 and Phy/Zn: 20.3–15.1), and after soaking of whole seeds for 24 h for soybean (Phy/Fe: 10.4–9.4 and Phy/Zn: 23.8–19.1). Cooking of flours with water used for soaking did not increase phytate degradation.     

Agarose-based hydrogel as an electrografting cell

An agarose gel was used as an electrochemical cell to graft vinylic polymer layers on conductive surfaces by electro-initiated radical electrografting of various water-soluble and hydrophobic vinylic monomers in the presence of diazonium ions. The process was followed by in situ electrochemical measurements and the resulting grafted layer was characterized by infrared (IRRAS) and photoelectron (XPS) spectroscopy. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

《可持续发展设计指南》选载(之六)如何利用新能源和系统来发展零能源建筑和周边环境

一、规划和设计生物气候型建筑■建筑工程项目的每一阶段都要尽量减少能量消耗设计生物气候型建筑的目的,就是要以产生尽可能少的能量消耗并充分考虑环境因素的条件在建筑物内部创造最大程度的舒适度。因此,在建筑工程项目的每一阶段内,都最大程度地减少能量消耗是非常必要的。     

Localized Ligand Induced Electroless Plating (LIEP) Process for the Fabrication of Copper Patterns Onto Flexible Polymer Substrates

The “ligand induced electroless plating (LIEP) process” is a simple process to obtain localized metal plating onto flexible polymers such as poly(ethylene terephtalate) and polyvinylidene fluoride sheets. This generic and cost‐effective process, efficient on any common polymer surface, is based on the covalent grafting by the GraftFast process of a thin chelating polymer film, such as poly(acrylic acid), which can complex copper ions. The entrapped copper ions are then chemically reduced in situ and the resulting Cu⁰ species act as a seed layer for the electroless copper growth which, thus, starts inside the host polymer. The present work focuses on the application of the LIEP process to the patterning of localized metallic tracks via two simple lithographic methods. The first is based on a standard photolithography process using a positive photoresist masking to prevent the covalent grafting of PAA in designated areas of the polymer substrate. In the second, the patterning is performed by direct printing of the mask with a commercial laser printer. In both cases, the mask was lifted off before the copper electroless plating step, which provides ecological benefits, since only the amount of copper necessary for the metallic patterning is used.     

Scheduling links for heavy traffic on interfering routes in wireless mesh networks

We consider wireless mesh networks and the problem of scheduling the links of a given set of routes under the assumption of a heavy-traffic pattern. We assume some TDMA protocol provides a background of synchronized time slots and seek to schedule the routes’ links to maximize the number of packets that get delivered to their destinations per time slot. Our approach is to construct an undirected graph G and to heuristically obtain node multicolorings for G that can be turned into efficient link schedules. In G each node represents a link to be scheduled and the edges are set up to represent every possible interference for any given set of interference assumptions. We present two multicoloring-based heuristics and study their performance through extensive simulations. One of the two heuristics is based on relaxing the notion of a node multicoloring by dynamically exploiting the availability of communication opportunities that would otherwise be wasted. We have found that, as a consequence, its performance is significantly superior to the other’s.     

Theoretical study of a novel solar trigeneration system based on metal hydrides

In order to utilize the low grade heat energy efficiently, the preliminary scheme of a metal hydride based Combined Cooling, Heating and Power (CCHP) system driven by solar energy and industrial waste heat was proposed, in which both refrigeration and power generation are achieved. Following a step-by-step procedure recently developed by the authors, two pairs of metal hydrides were selected for the CCHP system. The working principle of the system was discussed in detail and further design of the configuration for CCHP was conducted. Based on the cycle mentioned above, the models of energy conversion and exergy analysis were set up. The multi-element valued method was used to assess the performance of the CCHP system in a whole sense, thus the analysis of influence factors on the system performance can be carried out. The typical climate conditions of Xi’an in 2005 were taken for discussion, and the results showed that the system performance is mainly affected by the quantity of solar radiation energy. The objective of the system’s optimization is to increase the exergy efficiency of the metal hydride heat pump, based on the quantity of solar radiation energy. The comparison with two different traditional types of CCHP systems proved that the novel CCHP system is superior to the traditional CCHP systems concerning the integrated performance.     

The Hybrid Finite Element Mixing Cell Method: A New Flexible Method for Modelling Mine Ground Water Problems

Dewatering operations often stop at mine closure. The ground water rebound can have undesirable consequences, which numerical models can help one understand and manage. However, classical modelling techniques are relatively unsuitable to these contexts. While spatially distributed and physically based models suffer difficulties due to the lack of data and the complexity of geological and hydrogeological conditions, black-box models are too simple to deal with the problems effectively. A new modelling method is proposed to simulate ground water environments in which water flows through mined (exploited) and unmined (unexploited) areas. Exploited zones are simulated using a group of mixing cells possibly interconnected by pipes. Unexploited zones are simultaneously simulated using classical finite elements. This combined approach allows explicit calculation of ground water flows around the mine and mean water levels in the exploited zones. Water exchanges between exploited zones and unexploited zones are simulated in the model using specifically defined internal boundary conditions. The method is tested on synthetic cases of increasing complexity, and first results from a real case study are presented.     

90° SOI optical hybrid for Radio-over-fibre links

Radio-over- fibre (RoF) technology is receiving large attention due to its ability to provide simple antenna front ends, increased capacity and increased wireless access coverage. Coherently detected RoF systems would enable the information to be carried in both the amplitude and phase or in different states of the polarisation of the optical field. Additionally, the selectivity of coherent receiver is very well suited for access networks. We present a 90° optical hybrid built on a silicon-on-insulator planar light-wave circuit, which can be used as the optical front end of the digital coherent receiver in a digitised RoF link and will lead to reduced receiver footprint and cost. The optical hybrid circuit includes 2?×?2 and 4?×?4 multimode interference (MMI) splitters, in a polarisation diversity configuration. The simulation results at vacuum wavelength 1,550 nm show polarisation independence and phase errors between the ports of less than 0.03°. The properties of the prototyped 4?×?4 MMI were measured over a wide range of wavelengths. The 2?×?2 and 4?×?4 MMI showed nearly equal splitting ratios. Measurements of the relative phase relationship between the ports for Transverse Electric mode polarisation are shown to match the simulation results.