Asymmetric membrane fiber-based carbon dioxide removal devices for ion chromatography

The application of hollow and filament-filled single asymmetric membrane fibers, consisting of a thin silicone layer on a tubular microporous support, for removing CO(2) in suppressed ion chromatography effluents is described. With appropriate choice of the removal device and operating conditions, the CO(2) can be essentially quantitatively (99+%) removed. For carbonate-based eluents, the use of such devices greatly reduces or eliminates the water dip, permitting better quantitation of poorly retained anions that elute close to the dip, allows practical gradient chromatography, and improves noise levels and attainable detection limits. In hydroxide eluent chromatography, the device largely removes the response from CO(2) present in the samples; this greatly aids atmospheric trace gas analysis by IC. Device dimensions are such that the dispersion introduced by the device is small.     

Gel permeation chromatography for characterization of graft copolymer

Summary The present paper describes the grafting of vinyl monomers onto cellulose nitrate in non-aqueous medium using benzoyl peroxide as a catalyst. The complete separation of the homopolymers and graft copolymer was carried out by selective solvent extraction. The graft copolymer was characterized by IR spectra. The GPC was used as a technique to differentiate between homopolymer, polymer mixture, polyblend, and graft copolymer.     

Transforming Binary Uncertainties for Robust Speech Recognition

Recently, several algorithms have been proposed to enhance noisy speech by estimating a binary mask that can be used to select those time-frequency regions of a noisy speech signal that contain more speech energy than noise energy. This binary mask encodes the uncertainty associated with enhanced speech in the linear spectral domain. The use of the cepstral transformation smears the information from the noise dominant time-frequency regions across all the cepstral features. We propose a supervised approach using regression trees to learn the nonlinear transformation of the uncertainty from the linear spectral domain to the cepstral domain. This uncertainty is used by a decoder that exploits the variance associated with the enhanced cepstral features to improve robust speech recognition. Systematic evaluations on a subset of the Aurora4 task using the estimated uncertainty show substantial improvement over the baseline performance across various noise conditions.     

Influence of Die Angle on Containerless Extrusion of Commercially Pure Titanium Tubes

Containerless tube extrusion has been investigated with commerically pure titanium at room temperature and a strain rate of 0.07 s^-1 using 20 conical dies of five different strains and four different angles with MoS₂ lubricant. Theoretical punch pressures have been calculated using appropriate equations from slab analysis of the process and compared with experimentally determined punch pressures. It is found that there exists an optimum angle at which the punch pressure is the least at a given strain.     

Evaluating different NDVI composite techniques using NOAA-14 AVHRR data

Normalized Difference Vegetation Index (NDVI) data derived from Advanced Very High Resolution Radiometer (AVHRR) data are influenced by cloud contamination, which is common in individual AVHRR scenes. Maximum value compositing (MVC) of NDVI data has been employed to minimize cloud contamination. Two types of weekly NDVI composites were built for crop seasons in summer: one from all available AVHRR data (named the traditional NDVI composite) and the other from solely cloud-free AVHRR data (named the conditional NDVI composite). The MVC method was applied to both composites. The main objective of this study was to compare the two types of NDVI composites using Texas data. The NDVI seasonal profiles produced from the conditional NDVI composites agreed with the field measured leaf area index (LAI) data, reaching maximum values at similar times. However, the traditional NDVI composites showed irregular patterns, primarily due to cloud contamination. These study results suggest that cloud detection for individual AVHRR scenes should be strongly recommended before producing weekly NDVI composites. Appropriate AVHRR data pre-processing is important for composite products to be used for short-term vegetation condition and biomass studies, where the traditional NDVI composite data do not eliminate cloud-contaminated pixels. In addition, this study showed that atmosphere composition affected near-infrared reflectance more than visible reflectance. The near-infrared reflectance was increasingly adjusted through atmospheric correction.     

Land Surface Water Index (LSWI) response to rainfall and NDVI using the MODIS Vegetation Index product

For more than 20 years the Normalized Difference Vegetation Index (NDVI) has been widely used to monitor vegetation stress. It takes advantage of the differential reflection of green vegetation in the visible and near-infrared (NIR) portions of the spectrum and provides information on the vegetation condition. The Land Surface Water Index (LSWI) uses the shortwave infrared (SWIR) and the NIR regions of the electromagnetic spectrum. There is strong light absorption by liquid water in the SWIR, and the LSWI is known to be sensitive to the total amount of liquid water in vegetation and its soil background. In this study we investigated the LSWI characteristics relative to conventional NDVI-based drought assessment, particularly in the early crop season. The area chosen for the study was the state of Andhra Pradesh located in the Indian peninsular. The Moderate Resolution Imaging Spectroradiometer (MODIS) Vegetation Index (VI) product from the Aqua satellite was used in the study. The analysis was carried out for the years 2002 (deficit year) and 2005 (normal year) using the NDVI from the MODIS VI product and deriving the LSWI using the NIR and SWIR reflectance available with the MODIS VI product. The response of LSWI to rainfall, observed in the rate of increase in LSWI in the subsequent fortnights, shows that this index could be used to monitor the increase in soil and vegetation liquid water content, especially during the early part of the season. The relationship between the cumulative rainfall and the current fortnight LSWI is stronger in the low rainfall region (<500 mm), while the one-fortnight lagged LSWI had a stronger relationship in the high rainfall region (>500 mm). The relationship between LSWI and the cumulative rainfall for the entire state was mixed in 2002 and 2005. The strength of the relationship was weak in the high rainfall region. When LSWI was regressed directly with NDVI for three LSWI ranges, it was observed that the NDVI with the one-fortnight lag had a strong relationship with the LSWI in most of the categories.     

Contribution of organomodified clay on hybrid microstructures and properties of epoxidized natural rubber‐based nanocomposites

Influence of organic modifying agent of clay on dispersion, distribution, hybrid microstructure formation, and associated performance properties of epoxidized natural rubber‐based composites was evaluated. Binary and ternary composites of carbon black (CB) and two organomodified layered silicates (i.e., nanomer I30E and Cloisite 30B) were prepared and characterized based on small angle X‐ray scattering, transmission electron microscopy, hydrodynamic swelling, tensile measurement, and dynamic mechanical analyses. Greater extent of exfoliation and “nanounit” formation was noted in ternary composites containing nanomer I30E, which was reflected in higher interfacial roughness (d_s = 2.82) and lower radius of gyration (R_g = 205 Å). Morphological observations suggested higher nanomer I30E–CB interactions than that of Cloisite 30B–CB. The interplatelet distance in Cloisite 30B (d = 1.83 nm) stacks was lower than that of nanomer I30E (d = 2.26 nm). These two factors jointly contributed in higher breakdown of nanomer I30E stacks by CB than that of Cloisite 30B stacks. Greater exfoliation and nanounit formation in I30E–CB‐filled nanocomposite was also reflected in increased degree of crosslinking (n = 20 × 10^?5%), tensile modulus/strength, half height width of damping peak (20.3°C), and filler effectiveness (C = 0.33). POLYM. ENG. SCI., 2013. © 2012 Society of Plastics Engineers