Recent developments in aerosol measurement techniques and the metrological issues

A small error in the aerosol measurements can lead to a considerable influence on our understanding towards its impact on climate. To better simulate aerosol effects on the earth’s radiation budget, the chemical and physical characterizations of aerosol particles with accurate measurements have been a key interest in the aerosol research for last several decades. Recent advances in the chemical characterization of aerosols at bulk and molecular levels, and their physical characterization, such as size distribution, hygroscopicity, and cloud condensation nuclei (CCN) activity have improved our knowledge to better understand the aerosol sources, concentration distributions, atmospheric processing and their potential climate impacts. Apart from the complexity of atmospheric aerosols, because of the limited availability of aerosol certified reference materials, traceability data and measurement protocols, it is still a challenging task to measure the aerosol properties with reduced uncertainty. The recent developments on aerosol analytical techniques (on-line and off-line), which include gas chromatography/flame ionization detector (GC/FID)/mass spectrometry (MS)/isotope ratio mass spectrometry (irMS), ion chromatography (IC), organic carbon/elemental carbon (OC/EC) and water-soluble organic carbon (WSOC) analyzers, and physical measurements using scanning mobility particle sizer (SMPS), hygroscopicity tandem differential mobility analyzer (HTDMA) and cloud condensation nuclei-counter (CCN-C) are discussed with the metrological issues in the measurements. The importance of aerosol metrology is highlighted giving the data obtained from the laboratory studies and aerosol field campaigns.     

Prediction of burning rate of coal in fluidized-bed combustion

A theory has been proposed to evaluate the burning rate of a single carbon particle in a continuously operated coal-fired fluidized bed. Experimental verification was carried out in a laboratory scale 200 mm × 200 mm combustor. The burning rate increases with the increase of the fluidization velocity and the size of the bed material. The predicted data on burning rate agree fairly well with the experimental values. The gas concentration in the bed and freeboard has also been measured and it is seen that the consumption of oxygen mostly takes place in the bed.     

Synthesis of Mixed Refrigerant Cascade Cycles

This paper considers the synthesis of refrigeration systems with refrigerant mixtures as working fluids. The employed refrigeration topology encompasses features from industrial liquefaction of natural gas (LNG) systems. This configuration consists of a combination of horizontal and vertical cascades generalizing the vertical cascade of pure refrigerant systems. The key features of mixtures exploited here are their ability to evaporate/condense over a temperature range and their potential to generate streams with different compositions through partial condensation. The synthesis problem is formulated and solved as a nonlinear program. The proposed methodology is illustrated using an example of cooling a methane-rich stream.     

Residence time distribution and oxygen transfer in a novel constructed soil filter

BACKGROUND: The constructed soil filter (CSF), also known as soil biotechnology is a system for water renovation, which makes use of formulated media, culture of soil micro‐ and macro‐organisms, additives and plantation to purify water and wastewater. The process gives benefits in terms of applicability across very small to large scale, natural aeration, absence of moving parts, no biological sludge generation, odor free green aesthetic ambience. RESULTS: Residence time distribution (RTD) studies were carried out using laboratory scale CSF. Pulse potassium bromide tracer tests were carried out to determine RTD, and the Peclet number found to be 9–13 for a 2 m bed, and 2–3 for a 0.30 m bed with oxygen transfer of 0.08 h^?1. CONCLUSION: The two‐channel dispersion model for flow behavior shows a good fit to the experimental data, indicating a reactor Peclet number 9–13 for a 2 m bed and 2–3 for a 0.3m bed. Oxygen transfer studies carried out using various methods gave an oxygen transfer coefficient of about 0.08 h^?1. Wastewater purification studies indicate overall COD removal rate of around 50 mg L^?1 h^?1, suggesting that highly aerobic conditions are prevalent in the CSF system. Copyright © 2009 Society of Chemical Industry     

Gas-Sensing Properties of Zinc Ferrite Nanoparticles Synthesized by the Molten-Salt Route

Zinc ferrite (ZnFe₂O₄) nanoparticles have been synthesized at 700°C using sodium chloride as a growth inhibitor. Single-phase formation of spinel zinc ferrite having crystallite size in the range of 15–20 nm was observed by XRD and confirmed by TEM. In the present work, the gas-sensing properties of these zinc ferrite nanoparticles toward ethanol, LPG, H₂, NO _x . SO _x , and H₂S have been studied. It was found that they exhibit excellent selective sensitivity toward 200 ppm of H₂S at the operating temperature of 250°C, and thus this nanosized ferrite is expected to be useful in an industrial application as a potential H₂S gas sensor.     

An improved vertical-axis water-current turbine incorporating a channelling device

Water-Current Turbines (WCTs) are non-polluting electricity generation plants that harness the kinetic energy of natural water courses, using several kinds of rotors. At the School of Engineering of the University of Buenos Aires, researchers are developing a WCT whose particular characteristics improve technical and economic performance. A channelling device, integrated into the flotation system, is used to modify flow conditions in the neighbourhood of the rotor. This system was developed from theoretical modelling and small-scale model testing in a hydrodynamic test canal. The principal advantages of this kind of machine include reduced need for fixed civil works, ease of transport and relocation and autonomous, self-regulated operation, and it is expected to be a low-cost and long-lifetime system.     

EMA-PRBDS: efficient multi-attribute packet rank based data scheduling in wireless sensor networks for real-time monitoring systems

ABSTRACT

In recent years, Wireless Sensor Networks (WSNs) are widely placed in real-time monitoring systems like environmental, structural, patient monitoring, etc. The major criterion for WSN includes energy efficiency and network lifetime. Scheduling is used as a large number of data packets focus on the same queue at the same time. Only limited data scheduling schemes have been implemented in WSN to enhance the performance. The existing First Come First Serve (FCFS) and Dynamic Multilevel Priority (DMP) have some technical challenges like delay, packet drop and high energy consumption due to starvation and deadlock. In this paper, we proposed a new algorithm to optimise and rank the incoming data packets based on multi-attributes decision-making methodology named as Packet Rank Based Data Scheduling (PRBDS), the algorithm selects packet priority, deadline, and size as the metrics to rank the incoming data packets. A simulation result shows when compared with existing scheduling, PRBDS not only provides less energy consumption, also significantly reduces the packet drop and increases the lifetime. Thus, the proposed algorithm is most suitable for real-time monitoring system since it combines data ranking method with scheduling algorithm to create accurate and reliable results to evaluate the incoming data packets.     

Virus removal by iron coagulation-microfiltration

This study was undertaken to determine virus removal efficiency by iron coagulation followed by microfiltration (MF) in water treatment using the MS2 bacteriophage (25 nm diameter) as a tracer virus. Results from these bench-scale studies were used to propose a mechanism for virus removal by iron coagulation–MF. Ferric chloride was used as coagulant, and the dosages were 0, 2, 5, and 10 mg/L as Fe(III) with pH adjusted during mixing to 6.3, 7.3 and 8.3. In the absence of iron-coagulation and with less than 2 mg/L Fe, MF alone achieved less than a 0.5 log removal of MS2 virus. However, iron-coagulation pretreatment dramatically improved virus removal, especially in the 5–10 mg/L Fe dose range, ultimately achieving more than 4-log removal at pH 6.3 with 10-mg/L Fe dose. For the 5 and 10 mg/L Fe dosages, decreasing pH in the 8.3–6.3 range resulted in significantly greater virus removal. For 0 and 2 mg/L iron dosages, decreasing pH in the 8.3–6.3 range also improved virus removal, but to a lesser extent. The experimental data indicates negatively charged MS2 viruses first adsorbed onto the positively charged iron oxyhydroxide floc particles before being removed by MF. MS2 viruses were not inactivated in iron or aluminum coagulation as evidenced by the fact that their concentrations before and after coagulation, settling, and re-suspension of the coagulated sludge were not statistically different.