In this study, multi-wall carbon nanotubes (MWCTs) is evaluated as a transducer, stabilizer and immobilization matrix for the construction of amperometric sensor based on iron-porphyrin. 5,10,15,20-Tetraphenyl-21H,23H-porphine iron(III) chloride (Fe(III)P) adsorbed on MWCNTs immobilized on the surface of glassy carbon electrode. Cyclic voltammograms of the Fe(III)P-incorporated-MWCNTs indicate a pair of well-defined and nearly reversible redox couple with surface confined characteristics at wide pH range (2-12). The surface coverage (Γ) and charge transfer rate constant (ks) of Fe(III)P immobilized on MWCNTs were 7.68 × 10−9 mol cm−2 and 1.8 s−1, respectively, indicating high loading ability of MWCNTs for Fe(III)P and great facilitation of the electron transfer between Fe(III)P and carbon nanotubes immobilized on the electrode surface. Modified electrodes exhibit excellent electrocatalytic activity toward reduction of ClO3−, IO3− and BrO3− in acidic solutions. The catalytic rate constants for catalytic reduction of bromate, chlorate and iodate were 6.8 × 103, 7.4 × 103 and 4.8 × 102 M−1 s−1, respectively. The hydrodynamic amperometry of rotating-modified electrode at constant potential versus reference electrode was used for detection of bromate, chlorate and iodate. The detection limit, linear calibration range and sensitivity for chlorate, bromate and iodate detections were 0.5 μM, 2 μM to 1 mM, 8.4 nA/μM, 0.6 μM, 2 μM to 0.15 mM, 11 nA/μM, and 2.5 μM, 10 μM to 4 mM and 1.5 nA/μM, respectively. Excellent electrochemical reversibility of the redox couple, good reproducibility, high stability, low detection limit, long life time, fast amperometric response time, wide linear concentration range, technical simplicity and possibility of rapid preparation are great advantages of this sensor. The obtained results show promising practical application of the Fe(III)P-MWCNTs-modified electrode as an amperometric sensor for chlorate, iodate and bromate detections. 相似文献
Multimedia Tools and Applications - Image retargeting is the task of making images capable of being displayed on screens with different sizes. This work should be done so that high-level visual... 相似文献
Maintaining a fluid and safe traffic is a major challenge for human societies because of its social and economic impacts. Various technologies have considerably paved the way for the elimination of traffic problems and have been able to effectively detect drivers’ violations. However, the high volume of the real-time data collected from surveillance cameras and traffic sensors along with the data obtained from individuals have made the use of traditional methods ineffective. Therefore, using Hadoop for processing large-scale structured and unstructured data as well as multimedia data can be of great help. In this paper, the TVD-MRDL system based on the MapReduce techniques and deep learning was employed to discover effective solutions. The Distributed Deep Learning System was implemented to analyze traffic big data and to detect driver violations in Hadoop. The results indicated that more accurate monitoring automatically creates the power of deterrence and behavior change in drivers and it prevents drivers from committing unusual behaviors in society. So, if the offending driver is identified quickly after committing the violation and is punished with the appropriate punishment and dealt with decisively and without negligence, we will surely see a decrease in violations at the community level. Also, the efficiency of the TVD-MRDL performance increased by more than 75% as the number of data nodes increased.
In this paper, after a brief review on the coherent states and squeezed states, we introduce two classes of entangled coherent-squeezed states. Next, in order to generate the introduced entangled states, we present a theoretical scheme based on the resonant atom-field interaction. In the proposed model, a \(\varLambda \)-type three-level atom interacts with a two-mode quantized field in the presence of two strong classical fields. Then, we study the amount of entanglement of the generated entangled states using the concurrence and linear entropy. Moreover, we evaluate a few of their nonclassical properties such as photon statistics, second-order correlation function, and quadrature squeezing and establish their nonclassicality features. 相似文献
Hubs are special facilities designed to act as switching, transshipment and sorting points in various distribution systems. Since hub facilities concentrate and consolidate flows, disruptions at hubs could have large effects on the performance of a hub network. In this paper, we have formulated the multiple allocation p-hub median problem under intentional disruptions as a bi-level game model. In this model, the follower’s objective is to identify those hubs the loss of which would most diminish service efficiency. Moreover, the leader’s objective is to identify the set of hubs to locate in order to minimize expected transportation cost while taking normal and failure conditions into account. We have applied two algorithms based on simulated annealing to solve the defined problem. In addition, the algorithms have been calibrated using the Taguchi method. Computational experiments on different instances indicate that the proposed algorithms would be efficient in practice. 相似文献
This paper proposes a new single-phase direct step-up ac–ac converter by modifying the p-type impedance source. It provides a high boost factor as well as high efficiency, while only six parts are required to design it, involving just two bidirectional power switches. A safe commutation method has been applied to power switches to make the converter snubber-free and high efficient. Input and output harmonic filters are no longer required since input and output currents variate continuously with small ripple and low total harmonic distortion (THD). The proposed topology only modulates the output voltage amplitude, not the phase and frequency, so the output frequency is identical to the input frequency and constant. Thus, it can be utilized in step-up conversion applications, like inductive power transmission from low ac voltage sources. Input and output have the same ground, which is a good protective feature. In this paper, the operating principle of the converter is demonstrated. Experimental results have been represented to evaluate the performance of the converter. For this purpose, an experimental prototype has been fabricated. Results are investigated and compared with other previous step-up ac–ac converters. Results confirm the theory, operating principle, and performance of the converter. 相似文献
A new method for robust fixed-order H∞ controller design by convex optimization for multivariable systems is investigated. Linear Time-Invariant Multi-Input Multi-Output (LTI-MIMO) systems represented by a set of complex values in the frequency domain are considered. It is shown that the Generalized Nyquist Stability criterion can be approximated by a set of convex constraints with respect to the parameters of a multivariable linearly parameterized controller in the Nyquist diagram. The diagonal elements of the controller are tuned to satisfy the desired performances, while simultaneously, the off-diagonal elements are designed to decouple the system. Multimodel uncertainty can be directly considered in the proposed approach by increasing the number of constraints. The simulation examples illustrate the effectiveness of the proposed approach. 相似文献
This paper presents a computational method of forecasting based on high-order fuzzy time series. The developed computational method provides a better approach to overcome the drawback of existing high-order fuzzy time series models. Its simplicity lies with the use of differences in consecutive values of various orders as forecasting parameter and a w-step fuzzy predictor in place of complicated computations of fuzzy logical relations. The objective of the present study is to examine the suitability of various high-order fuzzy time series models in forecasting. The general suitability of the developed method has been tested by implementing it in the forecasting of student enrollments of the University of Alabama and in the forecasting of crop (Lahi) production, a case of high uncertainty in time series data. The results obtained have been compared in terms of average error of forecast to show superiority of the proposed model. 相似文献