Efficient electrochemomechanical energy conversion in nanochannels grafted with polyelectrolyte layers with pH-dependent charge density

Nanochannels, functionalized by grafting with a layer of charged polyelectrolyte (PE), have been employed for a large number of applications such as flow control, ion sensing, ion manipulation, current rectification and nanoionic diode fabrication. Recently, we established that such PE-grafted nanochannels, often denoted as “soft” nanochannels, can be employed for highly efficient, streaming-current-induced electrochemomechanical energy conversion in the presence of a background pressure-driven transport. In this paper, we extend our calculation for the practically realizable situation when the PE layer demonstrates a pH-dependent charge density. Consideration of such pH dependence necessitates consideration of hydrogen and hydroxyl ions in the electric double layer charge distribution, cubic distribution of the monomer profile, and a PE layer-induced drag force that accounts for this given distribution of the monomer profile. Our results express a hitherto unknown dependence of the streaming electric field (or the streaming potential) and the efficiency of the resultant energy conversion on parameters such as the pH of the surrounding electrolyte and the \(\hbox {pK}_{\mathrm{a}}\) of the ionizable group that ionizes to produce the PE charge—we demonstrate that increase in the pH and the PE layer thickness and decrease in the \(\hbox {pK}_{\mathrm{a}}\) and the ion concentration substantially enhance the energy conversion efficiency.     

Non-equilibrium Thermodynamics of Rayleigh–Taylor Instability

Here, the fundamental problem of Rayleigh–Taylor instability (RTI) is studied by direct numerical simulation (DNS), where the two air masses at different temperatures, kept apart initially by a non-conducting horizontal interface in a 2D box, are allowed to mix. Upon removal of the partition, mixing is controlled by RTI, apart from mutual mass, momentum, and energy transfer. To accentuate the instability, the top chamber is filled with the heavier (lower temperature) air, which rests atop the chamber containing lighter air. The partition is positioned initially at mid-height of the box. As the fluid dynamical system considered is completely isolated from outside, the DNS results obtained without using Boussinesq approximation will enable one to study non-equilibrium thermodynamics of a finite reservoir undergoing strong irreversible processes. The barrier is removed impulsively, triggering baroclinic instability by non-alignment of density, and pressure gradient by ambient disturbances via the sharp discontinuity at the interface. Adopted DNS method has dispersion relation preservation properties with neutral stability and does not require any external initial perturbations. The complete inhomogeneous problem with non-periodic, no-slip boundary conditions is studied by solving compressible Navier–Stokes equation, without the Boussinesq approximation. This is important as the temperature difference between the two air masses considered is high enough (\(\Delta T = 70\) K) to invalidate Boussinesq approximation. We discuss non-equilibrium thermodynamical aspects of RTI with the help of numerical results for density, vorticity, entropy, energy, and enstrophy.     

A Formal Methodology for Detecting Managerial Vulnerabilities and Threats in an Enterprise Information System

From information security point of view, an enterprise is considered as a collection of assets and their interrelationships. These interrelationships may be built into the enterprise information infrastructure, as in the case of connection of hardware elements in network architecture, or in the installation of software or in the information assets. As a result, access to one element may enable access to another if they are connected. An enterprise may specify conditions on the access of certain assets in certain mode (read, write etc.) as policies. The interconnection of assets, along with specified policies, may lead to managerial vulnerabilities in the enterprise information system. These vulnerabilities, if exploited by threats, may cause disruption to the normal functioning of information systems. This paper presents a formal methodology for detection of managerial vulnerabilities of, and threats to, enterprise information systems in linear time.     

A recursive maximum a posteriori estimator

Kalman Filter (KF) is the optimal state estimator for linear dynamical systems in the presence of zero mean white Gaussian noise. It is a minimum mean square error (MMSE) estimator. In the present work a recursive maximum a posteriori estimator (RMAPE) has been developed from basic principles of estimation. This estimator may be used for realtime state estimation of linear dynamical systems in presence of zero mean white Gaussian noise. It is further shown here that the KF can be derived from this RMAPE algorithm, i.e. this work shows an alternative method way to derive the KF. Copyright © 2010 John Wiley and Sons Asia Pte Ltd and Chinese Automatic Control Society     

Fairness of Transitions in Diagnosability of Discrete Event Systems

Failure diagnosability has been widely studied for discrete event system (DES) models because of modeling simplicity and computational efficiency due to abstraction. In the literature it is often held that for diagnosability, such models can be used not only for systems that fall naturally in the class of DES but also for the ones traditionally treated as continuous variable dynamic systems. A class of algorithms for failure diagnosability of DES models has been successfully developed for systems where fairness is not a part of the model. These algorithms are based on detecting cycles in the normal and the failure model that look identical. However, there exist systems with all transitions fair where the diagnosability condition that hinges upon this feature renders many failures non-diagnosable although they may actually be diagnosable by transitions out of a cycle. Hence, the diagnosability conditions based on cycle detection need to be modified to hold for many real-world systems where all transitions are fair. In this work, however, it is shown by means of an example that a system may have some transitions fair and some unfair. A new failure diagnosability mechanism is proposed for DES models with both fair and unfair transitions. Time complexity for deciding diagnosability of DES models with fair and unfair transitions is analyzed and compared with the time complexities of other DES diagnosability analysis methods reported in the literature.     

Hadamard quantum broadcast channels

We consider three different communication tasks for quantum broadcast channels, and we determine the capacity region of a Hadamard broadcast channel for these various tasks. We define a Hadamard broadcast channel to be such that the channel from the sender to one of the receivers is entanglement-breaking and the channel from the sender to the other receiver is complementary to this one. As such, this channel is a quantum generalization of a degraded broadcast channel, which is well known in classical information theory. The first communication task we consider is classical communication to both receivers, the second is quantum communication to the stronger receiver and classical communication to other, and the third is entanglement-assisted classical communication to the stronger receiver and unassisted classical communication to the other. The structure of a Hadamard broadcast channel plays a critical role in our analysis: The channel to the weaker receiver can be simulated by performing a measurement channel on the stronger receiver’s system, followed by a preparation channel. As such, we can incorporate the classical output of the measurement channel as an auxiliary variable and solve all three of the above capacities for Hadamard broadcast channels, in this way avoiding known difficulties associated with quantum auxiliary variables.     

Universal instability modes in internal and external flows

Two prototypical external and internal flows have been studied which display linear temporal instability followed by nonlinear saturation taking the flows to a new equilibrium state. Direct simulation results are obtained using a specific formulation and numerical methods with very high accuracy. These results are analyzed via proper orthogonal decomposition (POD), which reveal similar modes for flow past a circular cylinder and flow inside a lid-driven cavity, indicating universality of such modes. Unlike many other efforts on reduced order modeling via POD, here the emphasis has been on understanding the physical aspect of the flow instability which requires very high accuracy of the simulation. Then, the obtained POD modes are related to the instability modes (in the classical sense of defining the latter) and new generic types of instability modes are identified in the studied external and internal flows. These new modes have been reported for flow past a circular cylinder [Sengupta TK, Singh N, Suman VK. Dynamical system approach to instability of flow past a circular cylinder. J Fluid Mech 2010;656:82–115] which help one in understanding the instability sequence and the relative importance of these modes in the flow evolution starting from an impulsive start. Present comparative study, furthermore, reveals universality of such instability modes by showing their presence for the flow inside a lid-driven cavity as well. Despite seeming dissimilarities between these two flows, similarities between the instability portrait of these two flows suggest universality of such modes. From the equilibrium amplitude of vorticity time-series, we establish the presence of multiple modes and multiple bifurcation sequences for these flows in parameter space. Existing theory due to Landau and Stuart that considers only a single dominant mode and its self-interaction does not explain all these features. We invoke a multi-modal interaction model in the cited reference above, termed as Landau–Stuart–Eckhaus (LSE) equation in recognition of Eckhaus’ work in modifying the classical Stuart–Landau equation. We also show that the new instability modes do not follow either the classical Stuart–Landau or the newly proposed LSE model equations and for this reason we call these as anomalous modes. Two specific classes of anomalous modes are identified and classified in the present work. Empirical expressions for the evolution of these anomalous modes are presented and their unambiguous role during instabilities is discussed.     

33.7 MHz heavy-ion radio frequency quadrupole linac at VECC Kolkata

A 33.7 MHz heavy-ion radio frequency quadrupole (RFQ) linear accelerator has been designed, built, and tested. It is a four-rod-type RFQ designed for acceleration of 1.38 keVu, qA> or =116 ions to about 29 keVu. Transmission efficiencies of about 85% and 80% have been measured for the unanalyzed and analyzed beams, respectively, of oxygen ((16)O(2+), (16)O(3+), (16)O(4+)), nitrogen ((14)N(3+), (14)N(4+)), and argon ((40)Ar(4+)). The system design and measurements along with results of beam acceleration test will be presented.     

Triglyceride composition of chrysalis oil,an insect lipid

Chrysalis oil, an insect fat obtained from the spent silk worm pupae, Bombyx mori, is a by-product of sericultural industry and represents a potential source of 1750 tons of linolenic-rich oil per annum for India. Fatty acid and triglyceride compositions of chrysalis oil have been determined by the combination of the techniques of lower temperature segregation, lipolysis, thin layer and gas liquid chromatography. Percentage contents of the component acids are: C_14:0, 0.6; C_16:0, 19.3; C_18:0 3.9; C_18:1, 17.7; C_18:2, 9.8, and C_18:3, 48.7. Major component triglycerides are, LLnLn, 5.2%; PLnO, 6.4%;OLnLn, 9.6%; LnLnLn, 10.5% and PLnLn, 14.0% (P, palmitic; O, oleic; L, linoleic and Ln, linolenic acids. On low temperature crystallization, Chrysalis oil yielded two fractions amounting together to 40% of the total with composition quite similar to that of linseed oil.     

Polyaniline as a Gas-Sensor Material

Polyaniline (PANI) was synthesized by oxidative polymerization of aniline using ammonium persulfate in an acid medium. The polyaniline salt was converted to base form by treatment with ammonium hydroxide. The polyaniline base was dissolved in N-methyl pyrrolidone (NMP) for film casting. The cast film was doped with HCl for obtaining higher conductivity. Both doped and undoped PANI films were characterized by UV-visible, FTIR, and XRD analyses. The electrical conductivity of the PANI film was studied by a four-point probe method at room temperature. Finally, ammonia gas-sensing characteristics of the prepared polyaniline film were studied by measuring the change in electrical conductivity on exposure to ammonia gas at different concentrations. The influence of concentration of acid during polymerization of aniline and dopant concentration on the gas sensing characteristics of PANI film are reported in this paper.