全文获取类型
收费全文 | 288篇 |
免费 | 29篇 |
专业分类
电工技术 | 7篇 |
综合类 | 2篇 |
化学工业 | 92篇 |
金属工艺 | 5篇 |
机械仪表 | 14篇 |
建筑科学 | 9篇 |
能源动力 | 23篇 |
轻工业 | 14篇 |
水利工程 | 9篇 |
无线电 | 31篇 |
一般工业技术 | 62篇 |
冶金工业 | 13篇 |
原子能技术 | 3篇 |
自动化技术 | 33篇 |
出版年
2024年 | 1篇 |
2023年 | 16篇 |
2022年 | 16篇 |
2021年 | 24篇 |
2020年 | 21篇 |
2019年 | 17篇 |
2018年 | 22篇 |
2017年 | 21篇 |
2016年 | 28篇 |
2015年 | 20篇 |
2014年 | 19篇 |
2013年 | 25篇 |
2012年 | 18篇 |
2011年 | 12篇 |
2010年 | 8篇 |
2009年 | 12篇 |
2008年 | 6篇 |
2007年 | 8篇 |
2006年 | 2篇 |
2005年 | 3篇 |
2003年 | 1篇 |
2002年 | 2篇 |
2000年 | 2篇 |
1998年 | 2篇 |
1997年 | 2篇 |
1995年 | 1篇 |
1994年 | 2篇 |
1993年 | 1篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1980年 | 1篇 |
1977年 | 1篇 |
1976年 | 1篇 |
排序方式: 共有317条查询结果,搜索用时 15 毫秒
31.
Ali Shokuhi Rad Mehri Esfahanian Sina Maleki Gelare Gharati 《Journal of Sulfur Chemistry》2016,37(2):176-188
We studied the adsorption of SOx (x?=?2,3) molecules on the surface of pristine graphene (PG) and N-doped graphene (NDG) by density functional theory (DFT) calculations at the B3LYP/6-31G(d) level. We used Mulliken and NBO charge analysis to calculate the net charge transfer of adsorbed SOx on pristine and defected graphene systems. Our calculations reveal much higher adsorption energy and higher net charge transfer by using NDG instead of pristine graphene. Furthermore, the density of state (DOS) graphs point to major orbital hybridization between the SOx and NDG, while there is no evidence of hybridization by using pristine graphene. Based on our results, it is found that SO2 and SO3 molecules can be adsorbed on the surface of NDG physically and chemically with adsorption energies (Eads) of ?27.5 and 65.2?kJ?mol?1 (19.6 and 51.4?kJ?mol?1 BSSE), respectively, while low adsorption energies were calculated in the case of using pristine graphene. So we introduced NDG as a sensitive adsorbent/sensor for detection of SO2 and SO3. 相似文献
32.
Mohammad Ali Faramarzi Nadia Zolfaghary Mojtaba Tabatabaei Yazdi Sina Adrangi Hossein Rastegar Mohsen Amini Mohsen Badiee 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2009,84(7):1021-1025
BACKGROUND: A large number of bacterial, fungal and microalgal species are able to bio‐transform steroid compounds. Among them, fungi from the Mucor genus have been shown to mediate hydroxylation, oxidation, and desaturation by the double bond formation and epoxidation of various steroid substances. Mucor racemocus has not been studied for its ability to modify androst‐1,4‐dien‐3,17‐dione, a pharmaceutically important steroid precursor. RESULTS: The filamentous fungus M. racemosus was applied for bioconversion of androst‐1,4‐dien‐3,17‐dione (ADD, I ) in a 5‐day fermentation. Microbial metabolites were purified chromatographically and identified on the basis of their spectral data as 17β‐hydroxyandrost‐1,4‐dien‐3‐one ( II ), 14α‐hydroxyandrost‐1,4‐dien‐3,17‐dione ( III ), 15α‐hydroxyandrost‐1,4‐dien‐3,17‐dione ( IV ), 15α,17β‐dihydroxyandrost‐1,4‐dien‐3‐one ( V ), 14α,17β‐dihydroxyandrost‐1,4‐dien‐3‐one ( VI ), and 6β,17β‐dihydroxyandrost‐1,4‐dien‐3‐one ( VII ). CONCLUSION: Observed modifications included hydroxylation at C‐6β, C‐14α, C‐15α positions and 17‐carbonyl reduction. The best fermentation conditions for production of hydroxysteroid‐1,4‐dien‐3‐one derivatives were found to be 25 °C at 150 rpm for 5 days with a substrate concentration of 0.5 g L?1. Copyright © 2009 Society of Chemical Industry 相似文献
33.
34.
Alireza Ahmadiparidari Robert E. Warburton Leily Majidi Mohammad Asadi Amir Chamaani Jacob R. Jokisaari Sina Rastegar Zahra Hemmat Baharak Sayahpour Rajeev S. Assary Badri Narayanan Pedram Abbasi Paul C. Redfern Anh Ngo Mrton Vrs Jeffrey Greeley Robert Klie Larry A. Curtiss Amin Salehi‐Khojin 《Advanced materials (Deerfield Beach, Fla.)》2019,31(40)
Lithium–CO2 batteries are attractive energy‐storage systems for fulfilling the demand of future large‐scale applications such as electric vehicles due to their high specific energy density. However, a major challenge with Li–CO2 batteries is to attain reversible formation and decomposition of the Li2CO3 and carbon discharge products. A fully reversible Li–CO2 battery is developed with overall carbon neutrality using MoS2 nanoflakes as a cathode catalyst combined with an ionic liquid/dimethyl sulfoxide electrolyte. This combination of materials produces a multicomponent composite (Li2CO3/C) product. The battery shows a superior long cycle life of 500 for a fixed 500 mAh g?1 capacity per cycle, far exceeding the best cycling stability reported in Li–CO2 batteries. The long cycle life demonstrates that chemical transformations, making and breaking covalent C? O bonds can be used in energy‐storage systems. Theoretical calculations are used to deduce a mechanism for the reversible discharge/charge processes and explain how the carbon interface with Li2CO3 provides the electronic conduction needed for the oxidation of Li2CO3 and carbon to generate the CO2 on charge. This achievement paves the way for the use of CO2 in advanced energy‐storage systems. 相似文献
35.
Fars province is a large populated large province located in the southwest of Iran. This work presents a study of natural and radioactivity levels in soil samples of this province. For this purpose, 126 samples were gathered from different regions of the province and analysed by gamma spectroscopy to quantify radioactivity concentrations of radionuclides using a high-purity germanium detector and spectroscopy system. The results of this investigation show the average concentrations of 271 ± 28 Bq kg(-1), 6.37 ± 0.5 Bq kg(-1), 14.9 ± 0.9 Bq kg(-1) and 26.3 ± 1.9 Bq kg(-1) for (40)K, (137)Cs, (232)Th and (238)U in soil, respectively. Finally, baseline maps were established for the concentrations of each of the radionuclides in different regions. The absorbed dose rate and the annual effective dose (AED) were also calculated for the radionuclides according to the guidelines of UNSCEAR 2000. The average AED from the radioactivity content of soil in this province was found to be 39.9 ± 1.8 μSv. 相似文献
36.
Theresa Aliwarga Jean C. Dinh Scott Heyward Bhagwat Prasad Sina A. Gharib Rozenn N. Lemaitre Nona Sotoodehnia Rheem A. Totah 《International journal of molecular sciences》2022,23(20)
CYP2J2 is the main epoxygenase in the heart that is responsible for oxidizing arachidonic acid to cis-epoxyeicosatrienoic acids (EETs). Once formed, EETs can then be hydrolyzed by soluble epoxide hydrolase (sEH, encoded by EPHX2) or re-esterified back to the membrane. EETs have several cardioprotective properties and higher levels are usually associated with better cardiac outcomes/prognosis. This study investigates how cardiovascular disease (CVD) can influence total EET levels by altering protein expression and activity of enzymes involved in their biosynthesis and degradation. Diseased ventricular cardiac tissues were collected from patients receiving Left Ventricular Assist Device (LVAD) or heart transplants and compared to ventricular tissue from controls free of CVD. EETs, and enzymes involved in EETs biosynthesis and degradation, were measured using mass spectrometric assays. Terfenadine hydroxylation was used to probe CYP2J2 activity. Significantly higher cis- and trans-EET levels were observed in control cardiac tissue (n = 17) relative to diseased tissue (n = 24). Control cardiac tissue had higher CYP2J2 protein levels, which resulted in higher rate of terfenadine hydroxylation, compared to diseased cardiac tissues. In addition, levels of both NADPH-Cytochrome P450 oxidoreductase (POR) and sEH proteins were significantly higher in control versus diseased cardiac tissue. Overall, alterations in protein and activity of enzymes involved in the biosynthesis and degradation of EETs provide a mechanistic understanding for decreased EET levels in diseased tissues. 相似文献
37.
Eukaryotic elongation factor 2 (eEF-2) can undergo ADP-ribosylation in the absence of diphtheria toxin. The binding of free ADP-ribose and endogenous transferase-dependent ADP-ribosylation were distinct reactions for eEF-2, as indicated by different findings. Incubation of eEF-2 tryptic fragment 32/33 kDa (32F) with NAD was ADP-ribosylated and gave rise to the covalent binding of ADP-ribose to eEF-2. 32F was revealed to be at the C-terminal by Edman degradation sequence analysis. In our study, the elution of 32F from SDS-PAGE was ADP-ribosylated both in the presence and absence of diphtheria toxin. These results suggest that endogenous ADP-ribosylation of 32F might be related to protein synthesis. This modification appears to be important for the cell function. 相似文献
38.
Angiosarcoma with initial involvement of the scalp is a rare, malignant neoplasm. We present the case of a 77-year-old woman in whom extensive scarring alopecia developed that was proved histologically to be due to angiosarcoma. She had a good initial response to treatment with electron-beam therapy, but after seven months, extensive nodules and indurated areas on the face beyond the borders of the radiation field developed. Subsequently, massive cervical adenopathy and metastases to the lungs, liver, and spleen developed. Angiosarcoma must be differentiated from other malignant blood vessel tumors and should be considered in the differential diagnosis of scarring alopecia of the scalp in elderly patients. 相似文献
39.
Using a novel concept, the present study experimentally investigates underlying physics pertaining to statistics of the flame front position and the flame front velocity in turbulent premixed V-shaped flames. The concept is associated with characteristics of the reactants velocity at the vicinity of the flame front, referred to as the edge velocity. The experiments are performed using simultaneous Mie scattering and Particle Image Velocimetry techniques. Three mean streamwise exit velocities of: 4.0, 6.2, and 8.6 m/s along with three fuel–air equivalence ratios of: 0.7, 0.8, and 0.9 are examined. The results show that fluctuations of the flame front position and the flame front velocity are induced by the fluctuations of the component of the edge velocity transverse to the mean flow direction. Analysis of the results show that the mean of the flame front velocity in the normal direction to the flame front is significantly dependent on the vertical distance from the flame-holder. Relatively close to the flame-holder, the mean of the flame front velocity in the direction normal to the flame front is about zero; however, it increases to values several times larger than the laminar flame speed by increasing the vertical distance from the flame-holder. 相似文献
40.
Cork taint is mainly due to 2,4,6-trichloroanisole (TCA) produced through the activity of undesirable fungal strains. We observed that CFU mould number in TCA-containing stoppers was not quantitatively different to that of the stoppers not containing TCA (ca. 10(5)CFU/g). In contrast more fungi diversity was observed in TCA-containing stoppers. Penicillium spp (Penicillium chrysogenum, Penicillium glabrum), Aspergillus spp (Aspergillus niger and Aspergillus oryzae), Chrysonilia sitophila, Mucor racemosus, Paecilomyces sp. and Trichoderma viride were found in TCA-containing stoppers, while C. sitophila and Penicillium sp. were the main fungi in the stoppers devoid of TCA. Conidia were numerous close to the lenticels and present from the lateral surface through to the centre of the stoppers. Strains of Aspergillus, Mucor, Paecilomyces, Penicillium and Trichoderma isolated from TCA-containing stoppers were able to convert 2,4,6-trichlorophenol (TCP) in TCA in resting cell or growing conditions. The best yields of conversion were obtained by green fungi Paecilomyces sp. and P. chrysogenum, 17% and 20%, respectively. Chysonilia sitophila and Penicillium sp. did not produce TCA from TCP in our conditions. 相似文献