Output tracking of continuous bioreactors through recirculation and by-pass

In this paper, we propose to regulate the output of an auto-catalytic bioprocess (a biological process associated with a growth of a micro-organism) by means of a recirculation loop and by-pass. We give conditions on the volume of the reactor and the kinetic function for which it is possible to stabilize the output concentration under a constant or disturbed unmeasured input flow. Furthermore, we obtain convergence of the output variable in finite time with a Lipschitz continuous feedback.     

Dynamic analysis of a rigid rotor supported by three-pad hydrostatic squeeze film damper lubricated with ferrofluid

This work describes an analytical study on the dynamic behaviour of a three-pad hydrostatic journal bearing lubricated with ferrofluids. Each pad is fed with an external pressure through a capillary restrictor-type hydraulic resistance. Ferrofluid or magnetic fluid is a colloidal dispersion of magnetic nano-particles in a carrier liquid. In this study, a non-linear method was performed using Jenkins model in order to investigate the effect of ferrofluids lubrication on the vibrations amplitude and the transmitted forces of hydrostatic squeeze film dampers. The results presented in this paper showed that the ferrofluid lubrication is useful in controlling the bearing vibrations and transmitted forces. The results illustrated in this work are expected to be quite useful to the bearing designers.     

AlGaAs/GaAs bipolar transistors with a modulation-doped superlattice emitter

A new emitter-base concept for heterojunction bipolar transistors is proposed and demonstrated. The abrupt or graded emitter-base heterojunction drawbacks are circumvented by means of a modulation-doped stack of ternary compound alternating with binary compound layers. This stack provides efficient barriers to the hole current while preserving good diode characteristics. These concepts are demonstrated by experimental results on small-area devices with a common-emitter gain of ~40 and a collector-emitter voltage offset of ~80mV.     

Software sensors for highly uncertain WWTPs: a new approach based on interval observers

This paper presents the practical implementation of a new robust interval observer on a 1 m3 continuous fixed bed anaerobic reactor used for the treatment of industrial wine distillery wastewater. This interval observer is able to generate guaranteed intervals for the unmeasured variables (i.e. acidogenic and methanogenic bacteria, alkalinity and chemical oxygen demand) from few on-line measurements (i.e. input liquid flow rate, CO2 gaseous flow rate, volatile fatty acids and total inorganic carbon). The main advantage of this approach is its independance with respect to disturbances and uncertainty in the initial conditions, in the kinetics and, last but not least, in the process inputs.     

Ion exchanges in apatites for biomedical application

The modification of the composition of apatite materials can be made by several processes corresponding to ion exchange reactions which can conveniently be adapted to current coatings and ceramics and are an alternative to setting up of new synthesis methods. In addition to high temperature thermal treatments, which can partly or almost totally replace the monovalent OH^– anion of stoichiometric hydroxyapatite by any halogen ion or carbonate, aqueous processes corresponding to dissolution-reprecipitation reactions have also been proposed and used. However, the most interesting possibilities are provided by aqueous ion exchange reactions involving nanocrystalline apatites. These apatites are characterised by the existence on the crystal surface of a hydrated layer of loosely bound mineral ions which can be easily exchanged in solution. This layer offers a possibility to trap mineral ions and possibly active molecules which can modify the apatite properties. Such processes are involved in mineralised tissues and could be used in biomaterials for the release of active mineral species.     

High repetition rate laser produced soft x-ray source for ultrafast x-ray absorption near edge structure measurements

Recent progress in high intensity ultrafast laser systems provides the opportunity to produce laser plasma x-ray sources exhibiting broad spectrum and high average x-ray flux that are well adapted to x-ray absorption measurements. In this paper, the development of a laser based x-ray absorption near edge structure (XANES) beamline exhibiting high repetition rate by using the Advanced Laser Light Source (ALLS) facility 100 Hz laser system (100 mJ, 35 fs at 800 nm) is presented. This system is based on a broadband tantalum solid target soft x-ray source and a grazing incidence grating spectrometer in the 1-5 nm wavelength range. To demonstrate the high potential of this laser based XANES technique in condensed matter physics, material science, or biology, measurements realized with several samples are presented: VO2 vanadium L edge, Si3N4 nitrogen K edge, and BPDA/PPD polyimide carbon K edge. The characteristics of this laser based beamline are discussed in terms of brightness, signal to noise ratio, and compared to conventional synchrotron broadband x-ray sources which allow achieving similar measurements. Apart from the very compact size and the relative low cost, the main advantages of such a laser based soft x-ray source are the picosecond pulse duration and the perfect synchronization between this x-ray probe and a laser pulse excitation which open the way to the realization of time resolved x-ray absorption measurements with picosecond range time resolution to study the dynamics of ultrafast processes and phase transition.     

The role of surface diffusion of adatoms in the formation of nanowire crystals

A model of the formation of nanowire crystals on surfaces activated by droplets of the catalyst of growth is developed. In the model, the diffusion of adatoms from the surface of the substrate to the lateral surface of the crystals is taken into account. The exact solution of the diffusion problem for the flow of adatoms from the surface to the nanowire crystals is obtained, and the particular cases of the solution for the short and long diffusion lengths of adatoms, λ_s, are analyzed. A general expression for the length of the nanowire crystals, L, in relation to their radius R and to the conditions of growth is derived. The expression is applicable to a large variety of technologies of growth. The theoretical results are compared with the experimental dependences L(R) in the range of R = 20–250 nm for GaAs nanowire crystals grown by molecular-beam epitaxy on the GaAs (111) V Ga surface activated by Au. It is shown that, in some range of the parameters, the dependence L(R) follows the function 1/R ²ln(λ_s/R), which is radically different from the classical diffusion dependence 1/R.     

Interaction of uranium with in situ anoxically generated magnetite on steel

In the high level nuclear waste repository concept, spent nuclear fuel is designed to be encapsulated in steel canisters. Thus, it is necessary to study the influence of the steel and/or its corrosion products on the behaviour of the radionuclides released from the fuel. In this sense, the main objective of this work is to contribute to the knowledge of the influence of the steel and/or its corrosion products on the uranium(VI) retention. To this aim, magnetite (Fe(3)O(4)) has been generated by anaerobic steel corrosion in an autoclave reactor at an overpressure of 8atm of H(2)(g). After characterisation by X-ray diffraction (XRD), the obtained corroded steel coupons were contacted, at two different H(2)(g) pressures (1atm and 7.6atm), with a U(VI) solution. The evolution of the uranium concentration in solution is determined and a study of the composition of the coupons at the end of the experiments is carried out. The main conclusion obtained from this work is that magnetite generated on a steel coupon is able not only to retain uranium via sorption, but also to reduce hexavalent to tetravalent uranium in a higher extent than commercial magnetite, thus, providing an effective retardation path to the migration of uranium (and, potentially, other actinides) out of the repository.     

Wurtzite to zinc blende phase transition in GaAs nanowires induced by epitaxial burying

We bury vertical free-standing core-shell GaAs/AlGaAs nanowires by a planar GaAs overgrowth. As the nanowires get buried, their crystalline structure progressively transforms: whereas the upper emerging part retains its initial wurtzite structure, the buried part adopts the zinc blende structure of the burying layer. The burying process also suppresses all the stacking faults that existed in the wurtzite nanowires. We consider two possible mechanisms for the structural transition upon burying, examine how they can be discriminated from each other, and explain why the transition is favorable.     

Effect of Operating Parameters on the Heat Transfer and Liquid Film Thickness of Revolving Heat Pipe

This paper presents a study on the effects of operating parameters on the liquid film thickness and heat transfer of revolving heat pipe. The effects of speed, radius of rotation, evaporator and condenser temperatures, and mass of the working fluid are considered. Also, the effects of these parameters on the maximum heat transfer and minimum mass of the working fluid supplied to the heat pipe are considered. A simplified theoretical model is presented to estimate the heat transfer and the liquid film thickness. The theoretical model is used to determine the driven forces on the control volume. The system of equations associated with the heat pipe model is solved using the fourth-order Runge–Kutta method through a numerical code written in MATLAB. The results show that the heat transfer increases by decreasing the mass of the working fluid and increasing the temperature difference through the heat pipe. They also show that the liquid film thickness increases with the decrease in temperature difference and with increase in the mass of fluid. The maximum heat transfer increases with the increase in the rotation speed. The minimum mass of the working fluid supplied to the heat pipe increases with the increase in temperature difference and with the decrease in the rotation speed.