Structural characteriztion of Nd-doped in silica host matrix prepared by net chemical process

Silica host matrix containing neodymium which is potentially important for the formation of nanocrystalline metal oxides was prepared by solgel method, using tetra-ethoxysilane and Nd(NO3)3 as precursor materials. The prepared samples were changed from amorphous to nanocrystallites phase at sintered temperature 550℃ (4 h), 750℃ (8 h) and 950 ℃ (12 h). The thermally treated sample microstructures were investigated using X-ray diffraction (XRD), Fourier transformation infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). While a further increase of the temperature at 750 ℃ and annealing time (8 h) resulted in the formation of cubic and hexagonal Nd2O3 nanocrystallites. At constant sintering temperature 950℃ for 12 h, the samples showed sharper and intense peaks. The sizes of Nd2O3 nanocrystallites were characterized by XRD with average size～46 nm.     

Dielectric relaxation and conduction mechanism of complex perovskite Ca0.90Sr0.10Cu3Ti3.95Zn0.05O12 ceramic

In this work, Sr and Zn co-doped calcium copper titanate having nominal formula Ca_0.90Sr_0.10Cu₃Ti_3.95Zn_0.05O₁₂ has been synthesized and systematically studied for structure, dielectric and electrical properties. The phase purity of the prepared composition has been confirmed by X-ray diffraction (XRD) pattern and various structural parameters are presented here with Rietveld refinement data. The Scanning electron microscopy (SEM) image revealed the presence of homogeneous fine-grained microstructure investigated in the prepared ceramic. The impedance data well fitted with 2 R-CPE model confirmed the non-ideality of the system. Dielectric studies have shown the existence of two relaxation processes in low and high frequency domains. Low frequency dielectric response proposed as a combination of Maxwell-Wagner relaxation and intrinsic defect (V_o⁺⁺) while high frequency behavior has been interpreted in terms of polaronic relaxation caused by hopping process of an electron between Ti³⁺ and Ti⁴⁺ states. The frequency dependent behavior of conductivity has been well fitted to Dong’s model and interpreted in term of Overlapping Large Polaron Tunneling (OLPT) mechanism. The various parameters; relaxation angular frequency (ω₁) of Debye process, ionic hopping frequency (ω₂₎, dc conductivity (σ_o), cole- cole parameter (α) and frequency exponent (s) have been determined by Dong’s Model fitting.     

The case for technology in developing regions

Alongside good governance, technology is considered among the greatest enablers for improved quality of life. However, the majority of its benefits have been concentrated in industrialized nations and therefore limited to a fraction of the world's population. We believe that technology has a large role to play in developing regions, that "First World" technology to date has been a poor fit in these areas, and that there is thus a need for technology research for developing regions. Despite the relative infancy of technology studies in developing regions, anecdotal evidence suggests that access to technology has a beneficial economic impact. Cellular telephony is probably the most visible application, but there are many others, some of which we cover in this article. The World Bank's infoDev site catalogs hundreds of information and communications technologies (ICT) projects, albeit not all successful. Most of these projects use existing off-the-shelf technology designed for the industrialized world. Although it is clear that there are large differences in assumptions related to cost, power, and usage, there has been little work on how technology needs in developing regions differ from those of industrialized nations. We argue that Western market forces continue to meet the needs of developing regions accidentally at best.     

Microscopic Theory of Organic Superconductors

A microscopic theory of organic superconductors based on the concept of partial electron dielectrization is developed from first principles. Self-consistent equations for the superconducting order parameter () and insulating order parameter (D) are derived using a Green's function technique and equation of motion method. The theory is applied to explain the experimental results in the two-dimensional organic superconductor k-(BEDT-TTF)₂ Cu(NCS)₂. The present model explains coexistence of spin density wave (SDW) state and superconductivity state in the system. The behavior of superconducting order parameter (), insulating order parameter (D), specific heat, density of state, free energy, and critical field is also studied for the system k-(BEDT-TTF)₂ Cu(NCS)₂.     

An improved algorithm for connectivity analysis of distribution networks

In the present paper, an efficient algorithm for connectivity analysis of moderately sized distribution networks has been suggested. Algorithm is based on generation of all possible minimal system cutsets. The algorithm is efficient as it identifies only the necessary and sufficient conditions of system failure conditions in n-out-of-n type of distribution networks. The proposed algorithm is demonstrated with the help of saturated and unsaturated distribution networks. The computational efficiency of the algorithm is justified by comparing the computational efforts with the previously suggested appended spanning tree (AST) algorithm. The proposed technique has the added advantage as it can be utilized for generation of system inequalities which is useful in reliability estimation of capacitated networks.     

k‐version of finite element method in gas dynamics: higher‐order global differentiability numerical solutions

In this paper, we consider and examine alternate finite element computational strategies for time‐dependent Navier–Stokes equations describing high‐speed compressible flows with shocks in a viscous and conducting medium, with the ultimate objective of establishing the desired features of a general mathematical and computational framework for such initial value problems (IVP) in which: (a) the numerically computed solutions are in agreement with the physics of evolution described by the governing differential equations (GDEs) i.e. the IVP, (b) the solutions are admissible in the non‐discretized form of the GDEs in the pointwise sense (i.e. anywhere and everywhere) in the entire space–time domain, and hence in the integrated sense as well, (c) the numerical approximations progressively approach the same global differentiability in space and time as the theoretical solutions, (d) it is possible to time march the solutions (this is essential for efficiency as well as ensuring desired accuracy of the computed solution for the current increment of time, i.e. to minimize the error build up in the time marching process), (e) the computational process is unconditionally stable and non‐degenerate regardless of the choice of discretization, nature of approximations and their global differentiability and the dimensionless parameters influencing the physics of the process, (f) there are no issues of stability, CFL number limitations and (g) the mathematical and computational methodology is independent of the nature of the space–time differential operators. We consider one‐dimensional compressible flow in a viscous and conducting medium with shocks as model problems to illustrate various features of the general mathematical and computational framework used here and to demonstrate that the proposed framework is general and is applicable to all IVP. The Riemann shock tube with a single diaphragm serves as a model problem. The specific details presented in the paper discuss: (1) Choice of the form of the GDEs, i.e. strong form or weak form. (2) Various choices of variables. The paper establishes and considers density, velocity and temperature as variables of choice. (3) Details of the space–time least squares (LS) integral forms (meritorious over all others in all aspects) are presented and choice of approximation spaces are discussed. (4) In all numerical studies we consider a viscous and conducting medium with ideal gas law, however results are also presented for non‐conducting medium. Extension of this work to real gas models will be presented in a separate paper. It is worth noting that when the medium is viscous and conducting, the solutions of gas dynamics equations are analytic. (5) It is also significant to note that upwinding methods based on addition of artificial diffusion such as SUPG, SUPG/DC, SUPG/DC/LS and their many variations are neither needed nor used in this present work. (6) Numerical studies are aimed at resolving the localized details of the shock structure, i.e. shock relations, shock width, shock speed, etc. as well as the over all global behaviour of the solution in the entire space–time domain. (7) Numerical studies are presented for Riemann shock tube for high Mach number flows with special emphasis also on time accuracy of the evolution which is ensured by requiring that the approximations for each increment of time satisfy non‐discretized form of the GDEs in the pointwise sense, and hence in the integrated sense as well. (8) Comparisons are made with published results as well as theoretical solutions (when possible). It is established that space–time least squares processes are the only processes that yield variationally consistent space–time integral forms, and hence unconditionally non‐degenerate space–time computational processes, which when considered in higher‐order scalar product spaces provide the desired mathematical framework in which progressively higher‐order global differentiability solutions in space and time yield the same characteristics as the theoretical solutions of the IVP in all aspects. Copyright © 2006 John Wiley & Sons, Ltd.     

Effect of vacancy de-excitation parameters on L X-rays of Pb using H+ beam

The collision progression including ionization of an inner-shell by an energetic proton and decay of vacancy is a motivating theme in ion-beam analysis. To explore measured vacancy de-excitation parameters for Pb, intensity ratios are experimentally determined from L X-rays with proton impact in the energy range 225–400 keV. Predictions of UAECPSSR theory are employed for ionization cross-sections. For atomic parameters such as transition rates, fluorescence, Auger and Coster–Kronig (CK) yields, various databases are used. In this paper, significance of these features and current progress are discussed.     

Deploying a Rural Wireless Telemedicine System: Experiences in Sustainability

A novel ICT project in rural India uses long-distance Wi-Fi networking to enable high-quality videoconferencing between eye hospitals and remote village clinics. The project highlights the importance of sustainability as a first-class goal for systems research.     

Phytic acid and extractable phosphorus of pearl millet flour as affected by natural lactic acid fermentation

Lactic acid fermentation of pearl millet flour decreased its phytic acid content and increased extractable phosphorus. Fermentation at 40 and 50°C for 72 h or longer eliminated phytic acid almost completely; extractable phosphorus was more than doubled. Lower temperatures (20 and 30°C) were less effective. The changes in concentration of phytic acid and extractable phosphorus may be attributed partly to phytase activity inherent in pearl millet flour.     

Production and properties of crude enterotoxin of Pseudomonas aeruginosa

Pseudomonas aeruginosa CTM-3 was found to be the most potentially enteroxigenic strain out of the 12 isolates recovered from milk, as a high fluid length ratio, i.e. F/L (1.1) in rabbit gut and a strong permeability response in rabbit skin (38.5 mm² necrotic zone) was obtained with this culture. No clear-cut relationship between the two tests was observed. Six of the ethidium bromide (300 μg/ml) cured variants of this culture completely lost their ability to produce enterotoxin indicating the possible involvement of a plasmid in enterotoxin synthesis. The crude enterotoxin from P. aeruginosa CTM-3 was completely inactivated in 15 s at 72°C. However, it was fairly stable at pH values in the range 4.5–7.5. Both pepsin and trypsin inactivated the enterotoxin activity at a concentration of 40 μg/ml. Organic acids, formalin and hydrogen peroxide had no significant effect on the enterotoxin activity. The need for further investigations with purified preparations is emphasized.