Influence of deposited metal structures on the failure mechanisms of silicon-based components

Miniaturised silicon-based multilayer chips are nowadays widespread as semiconductor components for the mobile device technology. The use of special processing and integration procedures requires such materials to possess a definite mechanical strength to ensure the functionality of the entire device. The strength and mechanical reliability of such components can be described by the Weibull theory, and is highly influenced by the geometry of the metallisation and other near-surface functional layers. In this work, we attempt to clarify the mechanisms leading to the failure of the metallised side of Si-chip components. The combined use of Finite Elements (FE) and Focused Ion Beam (FIB) analyses allowed recognising that cracks are induced in the metal-oxide-silicon interfacial area well before complete failure of the component. Such cracks have a crucial role in the lower strength and higher Weibull modulus observed on the metallised side.     

Effect of Inclusion Size and Distribution on the Corrosion Behavior of Medical-Device Grade Nitinol Tubing

Nonmetallic inclusions in Nitinol, such as carbides (TiC) and intermetallic oxides (Ti₄Ni₂O _x ), are known to be triggers for fatigue failure of Nitinol medical devices. These mechanically brittle inclusions are introduced during the melting process. As a result of hot and cold working in the production of Nitinol tubing inclusions are fractionalized due to the mechanical deformation imposed. While the role of inclusions regarding Nitinol fatigue performance has been studied extensively in the past, their effect on Nitinol corrosion behavior was investigated in only a limited number of studies. The focus of the present work was to understand the effect of inclusion size and distribution on the corrosion behavior of medical-device grade Nitinol tubing made from three different ingot sources during different manufacturing stages: (i) for the initial stage (hollow: round bar with centric hole), (ii) after hot drawing, and (iii) after the final drawing step (final tubing dimensions: outer diameter 0.3 mm, wall thickness 0.1 mm). For one ingot source, two different material qualities were investigated. Potentiodynamic polarization tests were performed for electropolished samples of the above-mentioned stages. Results indicate that inclusion size rather than inclusion quantity affects the susceptibility of electropolished Nitinol to pitting corrosion.     

Non‐destructive detection of corrosion applied to steel and galvanized steel coated with organic paints by the pulsed phase thermography

Organic coatings in the automobile industry have to resist corrosion and mechanical damage from stone chipping. Currently, no tool is established in industrial non‐destructive applications for analyzing the damage of stone‐impacts and the following corrosion after accelerated corrosion tests. Measurement methods such as the scanning Kelvin probe can analyze the corrosion progress in a detailed manner, but with a long measurement time. The pulsed phase thermography (PPT) is a non‐destructive tool to analyze inhomogeneities and defects in materials, with a huge field of applications existing. The present work shows advances in using the PPT to detect propagation of corrosion under coatings. Physical principles of the mechanism of the corrosion detection under coatings are described. Results of measurements of organic coatings on carbon steel as well as of organic coated galvanized steel show the corrosion propagation. Influencing factors to the measurement such as the thickness of the coatings are investigated, but no significant effect on the quality of the analysis was found. The corrosion progress can be monitored by the PPT fast and reliably. The achieved results correlate with the theoretical basis and the test results after surface characterization and destructive analysis of samples.     

Analysis of New Nitinol Ingot Qualities

New ingot qualities, processed by optimized vacuum arc remelting (VAR), optimized vacuum induction melting followed by VAR and VAR followed by electron beam remelting, were compared with standard quality. Finished components as well as diamond-shaped samples representing a typical dimension of self-expanding stents were produced using Nitinol tubing drawn from the new ingot qualities. Metallographic longitudinal sections were prepared and analyzed to determine inclusion size and distributions of the various ingot qualities. Radial force and uniaxial tensile tests were used to determine the mechanical properties of fully processed material and tubing, respectively. Transformation temperatures of tubing as delivered from supplier and processed stents were measured by differential scanning calorimetry and deformation-and-free-recovery testing. Finally, fatigue tests were performed on diamond-shaped samples to evaluate the strain-life characteristics of the new ingot qualities. Results of this study are compared to ADMEDES historical data from standard Nitinol materials to gain an assessment of the new improved ingot qualities with regard to the production of Nitinol vascular implants. The latest developments in Nitinol ingot quality are highlighted and the results of the comparison from technical point of view are shown.     

Dauerhaftigkeit und mechanische Stabilität von Terrassendielen bei erhöhter Temperatur – Ein Werkstoffvergleich: WPC,thermisch modifiziertes Holz und Massivholz

This article deals with the differences in the long-term durability and thermal stability under load of terrace deckings from various materials. The tested materials were deckings made of wood, thermally modified timber (TMT), and wood–polymer–composites (WPC). For the determination of the test temperatures for component testing according to EN 310, the surface temperatures of the decks during a normal hot summer day were measured. A cyclic test according to EN 321 was applied to all decking materials. Afterwards the component testing was repeated. All wooden samples reveal considerable cracks, some were twisted, and few were even broken. In particular regarding the optical appearance, wood decks show advantages against the TMT decks. Some WPC decks show very fine cracks on the face, which were additionally analyzed by means of X-ray computed tomography (CT). Except for the WPC deck with higher wood content, no WPC deck revealed significant changes after the cyclic test. The CT analysis was also suitable to find cracks inside the materials and illustrate them. Thus, the whole damage inside a sample could be characterized by calculating a kind of error pattern. No considerable cracks or failures could be observed on the WPC decks.     

Study of Lewis acid catalyzed chemical bromination and bromoalkylation of multi-walled carbon nanotubes

Chemical functionalization of carbon nanotubes (CNT) with nucleophiles requires introduction of electrophilic reactive sites on the CNTs. This can, for instance, be accomplished by the chemical bromination procedure with elemental bromine and a set of Lewis acids (BBr₃, BF₃ × Et₂O, AlBr₃, FeBr₃, ZnBr₂, TiBr₄, SiBr₄, SnBr₄, VBr₃) or a radical starter like dibenzoylperoxide (DBPO) in appropriate solvents at varied temperature. The present approach to electrophilic sites relies on the well-known electrophilic aromatic substitution or addition of bromine with aromatic structural units. In addition to the use of bromine, the introduction of haloalkyl groups was also investigated here using bis-electrophiles or haloalcohols and Brønsted acids. The advantages and drawbacks of the studied reaction conditions, the obtained degree of bromination as analyzed by X-ray photoelectron spectroscopy (XPS) and the amount of introduced bromine that can be substituted by a nucleophile are presented and discussed.     

GMOfinder—A GMO Screening Database

The development and cultivation of genetically modified crops is still increasing globally. Food and feed imports from outside the European Union (EU) will subsequently require more effort from the responsible authorities in monitoring the compliance with effective labelling regulations. The aim of this study was the development of the GMOfinder, a database for collection and interpretation of information related to the screening for genetically modified organisms (GMOs). Different genetic elements (e.g. promoters, terminators, structural genes) are artificially introduced into plants to establish new genetic modifications. The introduced elements may vary between GMO events, depending on the intended trait(s). Screening for such inserted elements with (real-time) polymerase chain reaction is a common first step to analyse samples for the presence of any genetical modification. From the pattern of detectable and nondetectable elements, valuable conclusions about the identity of putative present GMO event(s) can be drawn with the GMOfinder. Information about selected genetic elements from the literature, applications for authorisation and other (web) sources were systematically integrated in a tabular matrix format. Special care was taken to additionally record the sources of the information, thus facilitating evaluation of screening results, and tracing of possible errors in the matrix. The GMOfinder accesses data from the element matrix with implemented algorithms and facilitates to interpret the outcome of screenings. Such a preselection helps to systematically narrow down the candidates for subsequent identification reactions. Optional display of events with potentially masked elements completes the included features.