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排序方式: 共有412条查询结果,搜索用时 7 毫秒
101.
Development of novel Ru catalyst of preferential CO oxidation for residential polymer electrolyte fuel cell systems 总被引:2,自引:0,他引:2
CO preferential oxidation on a novel Ru catalyst greatly improved in activity and selectivity over a wide temperature range by the pre-treatment of H2 reduction was characterized. The high performance was obtained by increasing the population of surface Ru(0) which improved O2 activation at low temperatures. Methanation of CO on the catalyst can also contribute to the final CO clean-up from ca. 100 to <1 ppm at low temperatures where the influence of CO2 methanation can be ignored. 相似文献
102.
Processing, Mechanical Properties, and Oxidation Behavior of Silicon Oxynitride Ceramics 总被引:2,自引:0,他引:2
Masayoshi Ohashi Shuzo Kanzaki Hideyo Tabata 《Journal of the American Ceramic Society》1991,74(1):109-114
Silicon oxynitride ceramics were prepared by hot-pressing an equimolar Si3 N4 + SiO2 mixture with 3 mol% CeO2 . The Ce2 O3 /SiO2 ratio of intergranular phase (liquid phase) increased as the formation of Si2 N2 O proceeded. The intergranular liquid remained as a glass on cooling until the Ce2 O3 /SiO2 ratio exceeded a certain value, at which point the liquid crystallized. There were great differences in thermal and mechanical properties and oxideation behavior between the specimen containing intergranular glassy phase and the one containing intergranular crystalline phase (Ce5 (SiO4 )3 N–Ce4.67 (SiO4 )3 O). The specimen containing the intergranular glassy phase showed excellent hightemperature strength and oxidation resistance. 相似文献
103.
Takahide Nomura Masakatsu Tachibana Hiroko Nomura Masaru Chihara Yasumichi Hagino 《Lipids》1987,22(7):474-479
Studies were conducted to compare the metabolic effects of vasopressin, 4β-phorbol-12-myristate-13-acetate (PMA) and A23187
on ketogenesis and oleate metabolism in isolated hepatocytes from fed rats. Vasopressin inhibited the formation of acid-soluble
products from [1-14C]oleate (0.25 mM, 0.5 mM and 1 mM), the inhibition being most marked at low (0.25 mM) concentration of oleate. Conversion
of [1-14C]oleate into14CO2 and esterified products was stimulated by vasopressin. The stimulatory effect of this hormone on14CO2 production was most marked at high (1 mM) concentration of oleate, whereas that on [1-14C]-oleate esterification was most marked at low (0.25 mM) concentration of oleate. These vasopressin actions were abolished
when hepatocytes were incubated in the absence of calcium in the medium. Our results strongly suggest that both increase in
esterification and increase in oxidation to CO2 contribute to the anti-ketogenic action of vasopressin when oleate is added as substrate, although the relative extent of
their contribution varies according to the oleate concentration. The anti-ketogenic action of vasopressin was mimicked by
PMA but not by A23187. PMA also caused a stimulation of [1-14C]oleate esterification although the effect was diminished at 1 mM [1-14C]oleate. A23187 failed to affect [1-14C]oleate esterification. The metabolic effects of PMA were elicited in the absence of extracellular calcium, too. Conversion
of [1-14C]oleate into14CO2 was only slightly increased by both PMA and A23187 when 1 mM [1-14C]oleate was added as substrate. The marked stimulatory effect of vasopressin on14CO2 production from [1-14C]oleate was not reproduced even by the combination of PMA and A23187. The possible involvement of protein kinase C and calcium
mobilization in the regulation of oleate metabolism is discussed. 相似文献
104.
Takashi Yoshida Kenichi Nishizawa Masahiro Tabata Hiroshi Abe Tatsuya Kodama Masamichi Tsuji Yutaka Tamaura 《Journal of Materials Science》1993,28(5):1220-1226
The methanation reaction of CO2 was studied with H2-reduced magnetite. A high conversion ratio of about 0.9 (in 30 min of the reaction time) with a selectivity of nearly 100% was obtained at 300°C and at 0.1 MPa for H2-reduced magnetite which had been prepared by passing H2 gas for 1–5 h at 300°C. From the results of X-ray diffractometry and Mössbauer spectroscopy, and from chemical analysis of the deposited carbon, H2-reduced magnetite is considered to decompose adsorbed CO2 into carbon, and to incorporate the oxygen of the CO2 into the spinel-type structure of the magnetite, associated with oxidation of the Fe2+ ion into Fe3+ ion in the magnetite. The high conversion ratio in the methanation reaction is considered to come from a higher reactivity of the elementary carbon deposited on the surface of the H2-reduced magnetite. 相似文献
105.
Selective catalytic reduction of NOx by propane was investigated on Co-Beta to clarify the loaded states of cobalt and their
role in catalytic activity. At low ion exchange levels less than 100%, loaded cobalt is highly dispersed, which has a high
selectivity for NOx reduction. At ion exchange levels much higher than 100%, Co3O4 appears as identified by Raman spectroscopy, and it contributes to propane oxidation by oxygen and lowers the selectivity
especially at high temperatures.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
106.
N Fukuda T Oki A Iuchi T Tabata K Manabe Y Kageji M Sasaki H Yamada S Ito 《Canadian Metallurgical Quarterly》1995,76(7):503-507
To elucidate predisposing factors for severe mitral regurgitation (MR) in idiopathic mitral valve prolapse (MVP), 124 MVP patients were classified into the following categories: 55 with isolated clicks (click group), 35 with a late-systolic murmur (late-SM group), and 34 with a holosystolic murmur (holo-SM group). Their clinical and echocardiographic findings were compared with those of 26 patients with spontaneous chordal rupture (rupture group). In 22 patients in the click group, 24 in the late-SM group, and 22 in the holo-SM group, follow-up studies were performed for a mean of 4.5 years (range 1 to 13.5). The mean age was youngest in the click group and oldest in the rupture group. The click and late-SM groups showed a female predominance, but the holo-SM and rupture groups showed a male predominance. There was no difference in the incidence of systemic hypertension among the 4 groups. Most patients in the click and late-SM groups had anterior leaflet prolapse. In the holo-SM and rupture groups, however, the incidence of posterior leaflet involvement was significantly increased. The incidence of thickened mitral valve increased in order of the click (8%), late-SM (21%), holo-SM (38%), and rupture (50%) groups. Six patients in the holo-SM group developed chordal rupture with severe MR during the follow-up period. In the click and late-SM groups, however, there were no complications and no development into a holo-SM. Thus, aging, male sex, posterior leaflet prolapse, thickened mitral valve, and holo-SM were found to be important predisposing factors for severe MR in idiopathic MVP. 相似文献
107.
N Tabata 《Canadian Metallurgical Quarterly》1998,96(2-3):197-214
Cervical muscles of 15 cases of compression of the neck and the other traumatized skeletal muscles from 54 autopsy cases were examined histologically and immunohistochemically. Round and thick fibers, that is, opaque fibers were observed in the muscles beneath the compression marks on the neck, whereas in areas where no force had been applied, such fibers did not exist. Furthermore, opaque changes appeared around cavities, which formed within severely compressed injured muscle tissue. The pattern of appearance of opaque fibers in the cases of compression of the neck were mainly divided into two types, 'diffuse' pattern and 'focal' pattern. In both blunt and sharp force injuries, the production of opaque fibers were common in the area directly where damage had been inflicted. In stab wounds especially, the appearance of opaque fibers and wavelike fibers, which fanned out and showed a different color from the other areas, was limited to the marginal zone. These results suggest that there is a close relationship between opaque changes and force. Opaque fibers are probably produced by damage to muscles due to extremely applied force. The high incidence of opaque fibers beneath compression marks on the neck should be regarded as a useful indication of strangulation and/or hanging. Furthermore, the distribution and direction of force to the neck might be presumed by the pattern of opaque fibers in cervical muscles, to a certain extent. 相似文献
108.
109.
The distillation test plant operated since April 14, 1972 during 94.2% of the work day has the capacity to treat 1,000 cu. meter/day of sea water, to produce 850t of fresh water of excellent quality, leaving 150t of concentrated brine containing 20% solid matter. Raw sea water was pretreated to prevent scale formation and corrosion of materials in distillation. Patents have been granted in Japan, USA, United Kingdom, West Germany, France, Italy, etc. (1).This method enables use of a base metal such as common steel for construction with the following advantages:Capital investment is cheaper.No galvanic corrosion arises.Mechanical structure is rigid.Contamination of poisonous heavy metals is avoidable.Upper limit of temperature is higher.Amount of raw sea water is smaller.Amount of exhaust brine is smaller. 相似文献
110.
An analysis of ring compression of porous metals was made on the basis of the plasticity theory for porous metals previously proposed by the authors. The change in geometry of rings with various porosities was obtained for various coefficients of friction. Experiments on ring compression were carried out using sintered copper powder metals. The coefficient of friction was determined for various lubricants and a proper lubricant for forging of porous metals was found. 相似文献