A Quaternary van der Waals Ferromagnetic Semiconductor AgVP2Se6

The recent realization of 2D magnetism in van der Waals (vdWs) magnets holds promise for future information technology. However, the vdWs semiconducting ferromagnets, which remain rare, are especially important in developing 2D magnetic devices with new functionalities due to the possibility of simultaneous control of the carrier charge and spin. Metal thiophosphate (MTP), a multifunctional vdWs material system that combines the sought‐after properties of complex oxides, is a promising vdWs magnet system. Here, single crystals of a novel vdWs ferromagnetic semiconductor MTP AgVP₂Se₆ with a room‐temperature resistivity of 1 Ω m are successfully synthesized. Due to the nature of vdWs bonding along the c‐axis, the magnetic properties of the few‐layer AgVP₂Se₆ with different thicknesses are characterized on the exfoliated samples. The AgVP₂Se₆ flakes exhibit significant thickness‐dependent magnetic properties, and a rectangular hysteresis loop with a large coercive field of 750 Oe at 2 K and an undiminished Curie temperature of 19 K are observed in the 6.7 nm AgVP₂Se₆ flake. The discovered vdWs ferromagnet AgVP₂Se₆ with semiconducting behavior will provide alternative platforms for exploring 2D magnetism and potential applications in spintronic devices.     

Explanation of impact load curve in ball impact test in relation to thermal aging

Solder joints are required to have high impact strength for use in portable electronic products. To make solder joints with high impact strength, qualitative evaluation methods of impact strength are required. Ball impact tests have been widely adopted in evaluating the impact strength of solder joints because of their easy implementation. Impact load curves obtained from ball impact tests are used as an evaluation indicator of impact strength of solder joint. However, a relation between fracture behavior and impact load curve has not yet been clarified, and an explanation of the impact load curve has not yet been provided in detail. In addition to this, detailed study about the relation between IMC layer thickness and impact strength has not been performed, although the IMC layer thickness formed at the interface would significantly affect the impact strength of the solder joint. This study aimed to explain the impact load curve in the ball impact test and to reveal the effect of the IMC layer thickness on the impact strength of the solder joint. Sn–3.0Ag–0.5Cu solder was reflowed on an electroless Ni–P plated Cu substrate (Ni–P), and a ball impact test was then carried out to evaluate the impact strength. This study found that the ball impact test is effective to evaluate the interfacial strength of solder joints. In the impact load curve, it is estimated that the solder bump keeps deforming until the interfacial crack initiates (maximum load), and the interfacial crack initiates after the maximum load and propagates along the interface between the solder and Ni–P. The suitable evaluation of impact strength became possible by measuring the correspondence relation between the deformation distance of the solder bump after fracture and the energy until maximum load and the relation between the area fraction of the residual solder on the fractured pad and the energy after maximum load. And, it is proved that the impact strength decreased with increasing aging time because the growth of the IMC layer remarkably degraded the interfacial strength of the solder joint.     

中国充电器标准化带来的变化

中国政府率先开始了手机充电器的标准化,其目的是让用户更换手机终端后可继续使用原来的充电器,从而通过削减废弃物达到保护环境的目的。     

Design strategy and development of spherical silicon solar cell with semi-concentration reflector system

Structural and economical merits of a spherical silicon solar cell with semi-concentration reflector system have been discussed. The roles of the reflector system have been clarified; the reflector improves short-circuit current density and also open-circuit voltage by 4–6 times concentration to make a light irradiation area comparable to a p–n junction area. We have theoretically demonstrated that the spherical Si solar cell with semi-concentration reflector system can realize a performance comparable to that of conventional Si solar cells, with less amount of silicon material use.     

An evaluation method of the fluctuation characteristics of photovoltaic systems by using frequency analysis

Short-time fluctuations in solar irradiance will become an important issue with regard to future embedded photovoltaic (PV) systems. However, when PV systems are intensively installed, fluctuation of total output in clustered PV systems is not remarkable because there is the smoothing effect of irradiance in certain areas. In this paper, a new estimation method of irradiance fluctuation, which is based on the combination of the Fourier transform and the wavelet transform methods, is described.     

Photovoltaic characteristics of phosphorus-doped amorphous carbon films grown by r.f. plasma-enhanced CVD

The phosphorus-doped amorphous carbon (n-C:P) films were grown by r.f. power-assisted plasma-enhanced chemical vapor deposition at room temperature using solid phosphorus target. The influence of phosphorus doping on material properties of n-C:P based on the results of simultaneous characterization are reported. Moreover, the solar cell properties such as series resistance, short circuit current density (J_sc), open circuit current voltage (V_oc), fill factor (FF) and conversion efficiency (η) along with the spectral response are reported for the fabricated carbon based n-C:P/p-Si heterojunction solar cell were measured by standard measurement technique. The cells performances have been given in the dark I–V rectifying curve and I–V working curve under illumination when exposed to AM 1.5 illumination condition (100 mW/cm², 25 °C). The maximum of V_oc and J_sc for the cells are observed to be approximately 236 V and 7.34 mA/cm², respectively for the n-C:P/p-Si cell grown at lower r.f. power of 100 W. The highest η and FF were found to be approximately 0.84% and 49%, respectively. We have observed the rectifying nature of the heterojunction structures is due to the nature of n-C:P films.     

Selective sorption of heavy metal thiocyanate complexes on crown ether resin

The sorption behavior of heavy metal thiocyanate complexes was investigated for dibenzo-18-crown-6 (DB18C6) resin and bis[2-(o-methoxyphenoxy)ethyl]ether (BMPE) resin. The DB18C6 resin showed a high sorption ability and the degree of zinc sorption increased significantly with thiocyanate concentration. This behavior was not observed for BMPE resin. The sorption behavior was influenced by the countercation species, and the degree of sorption of zinc ions showed the maximum when the potassium thiocyanate was used as a complexing salt. The sorbed species appear to be KZn(SCN)₃, K₂Zn(SCN)₄ in the potassium thiocyanate system, and Zn(SCN)₂ in the lithium thiocyanate system, respectively, according to analysis of the sorption equilibrium. Sodium and ammonium thiocyanate systems show an intermediate behavior of the two. The sorption selectivity for DB18C6 resin depended not only on the hydrophobic nature of heavy metal thiocyanate complexes but also on the stabilization of counter cation species with crown ether matrix, and the sorption selectively was found to be effectively controlled by countercation species according to the cation-chelation mechanism.     

Detection and Quantitation of Left-to-Right Shunts from Radionuclide Angiocardiography Using the Homomorphic Deconvolution Technique

The homomorphic filtering method is described for the detection and quantitation of left-to-right shunts from radionuclide angiocardiography. First, the method is investigated theoreticatly and numerically using a realistic model with systemic recirculation. It is demonstrated that even in a noisy situation the shunt flow fraction can be relatively well estimated, if only the characteristics of the fiters used are suitable. Second, the method is applied to real data, i.e., the pulmonary time-activity curves from radionucUde anglocardiography. The presence or absence of a left-to-right shunt is determined using the ratio AT/MTT. The pulmonary-to-systemic flow ratios calculated from the areas of the two decomposed curves are compared with those from oximetry at cardiac catheterization. Good agreement between the Qp/Qs ratios calculated by oximetry and radionucUide angiocardiography is obtained.     

Liver phosphatidylcholine hydroperoxidation provoked by ethionine-containing choline-deficient diet in mice

It is shown that peroxidation of phosphatidylcholine (PC) is enhanced in liver of mice fed a hepatocarcinogenic choline-deficient diet containing 0.1% w/w ethionine. Mice were divided into 4 groups and fed for 3 weeks one of the following diets: choline-supplemented; choline-supplemented containing ethionine; choline-deficient; and choline-deficient containing ethionine. Phosphatidylcholine hydroperoxide (PCOOH) of liver lipids was measured by high performance liquid chromatography using a chemiluminescence detector. Mice fed a choline-deficient diet containing ethionine showed 6-fold higher PCOOH levels than the choline-supplemented control mice: the PCOOH/PC molar ratios of liver lipids were 32.3×10⁻⁵ and 5.6×10⁻⁵, respectively. In addition to this remarkable degree of lipid peroxidation in liver of mice fed the choline-deficient diet containing ethionine, we also observed a significant liver fatty infiltration, a decrease in plasma and liver α-tocopherol, and an increase in liver injury-indicative enzyme activities. Also, marker enzymes for hepatocarcinogenesis, glucose-6-phosphatase and γ-glutamyl transpeptidase were affected. These data suggest that enhanced hydroperoxidation of phosphatidylcholine may participate in hepatocarcinogenesis provoked by choline deficiency in the presence of ethionine.