Comparison of total ozone column observations from space-borne Ozone Monitoring Instrument with ground-based Dobson Ozone Spectrophotometer measurements at an urban location in Indo-Gangetic Basin

This article presents a comparison analysis of OMIT (Ozone Monitoring Instrument retrieved overpass total ozone column (TOC)), and DOST (Dobson Ozone Spectrophotometer observed TOC) over Delhi during a period from October 2004 to June 2011. Megacity Delhi, located in Indo-Gangetic Basin, is an important site for comparison of ground-based and satellite retrieved TOCs due to significant anthropogenic emissions of ozone precursors, large shift in seasons, and large-scale crop residue burning in the region. DOST and OMIT data show an overall bias of 3.07% and significant correlation with coefficient of determination R² = 0.73. Large seasonal fluctuations in the biases and correlations have been observed ranging from 2.46% (winter) to 3.82% (spring), and R² = 0.84 (winter) to R² = 0.09 (summer), respectively. The large biases are attributed to changes in temperature, cloud cover, pollutants emissions from urban area, and crop-residue burning events. We also find notable variations in correlations between the datasets due to the varying burden of absorbing aerosols from open field crop-residue burning. The R² has changed from 0.67 (for aerosol optical depth, AOD 1.5–3.5) to 0.77 (for AOD 0–0.99). The dependence of the bias on solar zenith angle, cloud fraction, and satellite distance is also discussed. A simple linear regression analysis is applied to check the linkage between DOST and OMIT. The influence of atmospheric air temperature and relative humidity on OMIT at different pressure levels between 1000 and 20 hPa has been discussed.     

Aluminum‐Tailored Energy Level and Morphology of Co3−xAlxO4 Porous Nanosheets toward Highly Efficient Electrocatalysts for Water Oxidation

Tuning energy levels plays a crucial role in developing cost‐effective, earth‐abundant, and highly active oxygen evolution catalysts. However, to date, little attention has been paid to the effect of using heteroatom‐occupied lattice sites on the energy level to engineer electrocatalytic activity. In order to explore heteroatom‐engineered energy levels of spinel Co₃O₄ for highly‐effective oxygen electrocatalysts, herein Al atoms are directly introduced into the crystal lattice by occupying the Co²⁺ ions in the tetrahedral sites and Co³⁺ ions in the octahedral sites (denoted as Co²⁺_Td and Co³⁺_Oh, respectively). Experimental and theoretical simulations demonstrate that Al³⁺ ions substituting Co²⁺_Td and Co³⁺_Oh active sites, especially Al³⁺ ions occupying the Co²⁺_Td sites, optimizes the adsorption, activation, and desorption features of intermediate species during oxygen evolution reaction (OER) processes. As a result, the optimized Co_1.75Al_1.25O₄ nanosheet exhibit unprecedented OER activity with an ultralow overpotential of 248 mV to deliver a current of 10 mA cm^–2, among the best Co‐based OER electrocatalysts. This work should not only provide fundamental understanding of the effect of Al‐occupied different Co sites in Co_3–xAl_xO₄ composites on OER performance, but also inspire the design of low‐cost, earth‐abundant, and high‐active electrocatalysts toward water oxidation.     

A First-Principles Calculation of Electronic Structure and dHvA Simulation of the Novel Superconductor Re<Subscript>6</Subscript>Hf

In this paper, we performed a density functional theory calculation study on the newly discovered superconductor Re₆Hf containing anti-symmetric spin-orbit coupling (ASOC) properties. The calculated densities of electronic states demonstrate that the d–d interaction of Re₆Hf is much stronger than that in Re₆Zr. A fully relativistic DFT study shows a special performance of densities of states for the spin-up and spin-down electrons. Band structure calculations indicate that the lifting at several high symmetric k points and plenty of splits in band structures yield significant topological transitions in the Fermi surfaces of Re₆Hf. The energy splitting of bands caused by ASOC are estimated to be 34 and 44 meV, respectively. The de Hass-van Alphen effect simulation is demonstrated and analyzed.     

Predicting Drying Performance of Osmotically Treated Heat Sensitive Products Using Artificial Intelligence

The main goal of this research is to develop and apply a robust Artificial Neural Networks (ANNs) model for predicting the characteristics of the osmotically drying treated potato and apple samples as a model heat-sensitive product in vacuum contact dryer. Concentrated salt and sugar solutions were used as the osmotic solutions at 27C. Series of experiments were performed at various temperatures of 35C, 40C, and 55C for conduction heat input under vacuum ( −760 mm Hg) condition. Some experiments were also performed in a pure vacuum without heat addition. Dimensionless moisture content (DMC), effective moisture diffusivity, and mass flux were considered as the performance parameters in this study. Results revealed that the osmotic dehydration using a concentrated sugar solution shows a higher reduction in the initial moisture loss of 19.87% compared to 5.3% in the salt solution. Furthermore, a significant enhancement of drying performance of about 27% in DMC was observed for both samples at vacuum and 40C compared to pure vacuum drying conditions. Using the experimental data, a robust artificial neural network (ANN) was proposed to describe the osmotic dehydration’s behavior on the drying process. The ANN model outputs are the dimensionless moisture contents (DMC), the diffusivity, and the mass flux. Whereas the ANN inputs were the drying time, the percent of sugar solution, and the percent of salt solution. For the ANN apple’s model, the minimum root mean square error (RMSE) values were 0.0261, 0.0349 and 0.0406, for DMC, diffusivity, and mass flux, respectively. Whereas the best correlation coefficients of the above three parameters’ determination values were 0.9909, 0.9867 and 0.9744, respectively. For the ANN potato’s model, the minimum RMSE values were 0.0124, 0.0140 and 0.0333, for DMC, diffusivity, and mass flux, respectively. And the best correlation coefficients of the parameters’ values were found 0.9969, 0.9968 and 0.9736, respectively. Accordingly, the ANN model’s prediction has a perfect agreement with the experimental dataset, which confirmed the ANN model’s accuracy.     

Blockchain-Enabled EHR Framework for Internet of Medical Things

The Internet of Medical Things (IoMT) offers an infrastructure made of smart medical equipment and software applications for healthcare services. Through the internet, the IoMT is capable of providing remote medical diagnosis and timely health services. The patients can use their smart devices to create, store and share their electronic health records (EHR) with a variety of medical personnel including medical doctors and nurses. However, unless the underlying commination within IoMT is secured, malicious users can intercept, modify and even delete the sensitive EHR data of patients. Patients also lose full control of their EHR since most healthcare services within IoMT are constructed under a centralized platform outsourced in the cloud. Therefore, it is appealing to design a decentralized, auditable and secure EHR system that guarantees absolute access control for the patients while ensuring privacy and security. Using the features of blockchain including decentralization, auditability and immutability, we propose a secure EHR framework which is mainly maintained by the medical centers. In this framework, the patients’ EHR data are encrypted and stored in the servers of medical institutions while the corresponding hash values are kept on the blockchain. We make use of security primitives to offer authentication, integrity and confidentiality of EHR data while access control and immutability is guaranteed by the blockchain technology. The security analysis and performance evaluation of the proposed framework confirms its efficiency.     

Profiling Casualty Severity Levels of Road Accident Using Weighted Majority Voting

To determine the individual circumstances that account for a road traffic accident, it is crucial to consider the unplanned connections amongst various factors related to a crash that results in high casualty levels. Analysis of the road accident data concentrated mainly on categorizing accidents into different types using individually built classification methods which limit the prediction accuracy and fitness of the model. In this article, we proposed a multi-model hybrid framework of the weighted majority voting (WMV) scheme with parallel structure, which is designed by integrating individually implemented multinomial logistic regression (MLR) and multilayer perceptron (MLP) classifiers using three different accident datasets i.e., IRTAD, NCDB, and FARS. The proposed WMV hybrid scheme overtook individual classifiers in terms of modern evaluation measures like ROC, RMSE, Kappa rate, classification accuracy, and performs better than state-of-the-art approaches for the prediction of casualty severity level. Moreover, the proposed WMV hybrid scheme adds up to accident severity analysis through knowledge representation by revealing the role of different accident-related factors which expand the risk of casualty in a road crash. Critical aspects related to casualty severity recognized by the proposed WMV hybrid approach can surely support the traffic enforcement agencies to develop better road safety plans and ultimately save lives.     

Deep Learning and Machine Learning for Early Detection of Stroke and Haemorrhage

Stroke and cerebral haemorrhage are the second leading causes of death in the world after ischaemic heart disease. In this work, a dataset containing medical, physiological and environmental tests for stroke was used to evaluate the efficacy of machine learning, deep learning and a hybrid technique between deep learning and machine learning on the Magnetic Resonance Imaging (MRI) dataset for cerebral haemorrhage. In the first dataset (medical records), two features, namely, diabetes and obesity, were created on the basis of the values of the corresponding features. The t-Distributed Stochastic Neighbour Embedding algorithm was applied to represent the high-dimensional dataset in a low-dimensional data space. Meanwhile,the Recursive Feature Elimination algorithm (RFE) was applied to rank the features according to priority and their correlation to the target feature and to remove the unimportant features. The features are fed into the various classification algorithms, namely, Support Vector Machine (SVM), K Nearest Neighbours (KNN), Decision Tree, Random Forest, and Multilayer Perceptron. All algorithms achieved superior results. The Random Forest algorithm achieved the best performance amongst the algorithms; it reached an overall accuracy of 99%. This algorithm classified stroke cases with Precision, Recall and F1 score of 98%, 100% and 99%, respectively. In the second dataset, the MRI image dataset was evaluated by using the AlexNet model and AlexNet + SVM hybrid technique. The hybrid model AlexNet + SVM performed is better than the AlexNet model; it reached accuracy, sensitivity, specificity and Area Under the Curve (AUC) of 99.9%, 100%, 99.80% and 99.86%, respectively.     

Local-Tetra-Patterns for Face Recognition Encoded on Spatial Pyramid Matching

Face recognition is a big challenge in the research field with a lot of problems like misalignment, illumination changes, pose variations, occlusion, and expressions. Providing a single solution to solve all these problems at a time is a challenging task. We have put some effort to provide a solution to solving all these issues by introducing a face recognition model based on local tetra patterns and spatial pyramid matching. The technique is based on a procedure where the input image is passed through an algorithm that extracts local features by using spatial pyramid matching and max-pooling. Finally, the input image is recognized using a robust kernel representation method using extracted features. The qualitative and quantitative analysis of the proposed method is carried on benchmark image datasets. Experimental results showed that the proposed method performs better in terms of standard performance evaluation parameters as compared to state-of-the-art methods on AR, ORL, LFW, and FERET face recognition datasets.     

Diffusion Based Channel Gains Estimation in WSN Using Fractional Order Strategies

In this study, it is proposed that the diffusion least mean square (LMS) algorithm can be improved by applying the fractional order signal processing methodologies. Application of Caputo’s fractional derivatives are considered in the optimization of cost function. It is suggested to derive a fractional order variant of the diffusion LMS algorithm. The applicability is tested for the estimation of channel parameters in a distributed environment consisting of randomly distributed sensors communicating through wireless medium. The topology of the network is selected such that a smaller number of nodes are informed. In the network, a random sleep strategy is followed to conserve the transmission power at the nodes. The proposed fractional order modified diffusion LMS algorithms are applied in the two configurations of combine-then-adapt and adapt-then-combine. The average squared error performance of the proposed algorithms along with its traditional counterparts are evaluated for the estimation of the Rayleigh channel parameters. A mathematical proof of convergence is provided showing that the addition of the nonlinear term resulting from fractional derivatives helps adjusts the autocorrelation matrix in such a way that the spread of its eigenvalues decreases. This increases the convergence as well as the steady state response even for the larger step sizes. Experimental results are shown for different number of nodes and fractional orders. The simulation results establish that the accuracy of the proposed scheme is far better than its classical counterparts, therefore, helps better solves the channel gains estimation problem in a distributed wireless environment. The algorithm has the potential to be applied in other applications related to learning and adaptation.