Design and optimization of radioisotope sources for betavoltaic batteries

A Monte Carlo source model using PENELOPE was developed to investigate different tritiated metals in order to design a better radioisotope source for betavoltaic batteries. The source model takes into account the self‐absorption of beta particles in the source which is a major factor for an efficient source design. The average beta energy, beta flux, source power output, and source efficiency were estimated for various source thicknesses. The simulated results for titanium tritide with 0° and 90° angular distributions of beta particles were validated with experimental results. The importance of the backscattering effect due to isotropic particle emission was analyzed. The results showed that the normalized average beta energy increases with the source thickness, and it reaches peak energy depending on the density and the specific activity of the source. The beta flux and power output also increase with increasing source thickness. However, the incremental increase in beta flux and power output becomes minimal for higher thicknesses, as the source efficiency decreases significantly at higher thicknesses due to the self‐absorption effect. Thus, a saturation threshold is reached. A low‐density source material such as beryllium tritide provided a higher power output with higher efficiency. A maximum power output of approximately 4 mW/cm³ was obtained for beryllium tritide with SiC. A form factor approach was used to estimate the optimum source thickness. The optimum source thickness was found near the thickness where the peak beta particle average energy occurs.     

Wrinkle free plaited knitted fabrics without pre-heat setting

Wrinkle free fabric at low cost is always a desirable aesthetic property. Different type of resins/finishes and pre-heat setting prior to processing are applied to avoid wrinkles in woven and hosiery, respectively. Current study is proposed to produce wrinkle free circular plaited knitted fabric by the elimination of a pre-boarding step. In this achievement, yarn covering parameters and compatibility of yarns with knitting machines are examined. Sock samples were analyzed for improved physical appearance (wrinkles) after various processes (pre-tumbling, dyeing, bleaching, and washing). Yarn specifications (sheath yarn fineness, sheath yarn texture i.e. shrink/un-shrink, covering air-knots) impact on socks physical appearance were also analyzed. The results clearly showed that by decreasing number of yarn covering air knots and sheath yarn fineness leads to prevention of wrinkle formation. The results also prove to be supportive for cost effectiveness by eliminating the pre-setting stage.     

Numerical simulation of mixed convective 3D flow of a chemically reactive nanofluid subject to convective Nield's conditions with a nonuniform heat source/sink

The present investigation aims to explore the influence of a mixed convection and nonuniform heat source/sink on unsteady flow of a chemically reactive nanofluid driven by a bidirectionally expandable surface. Convective heat transport phenomenon is used to maintain the temperature of the surface. Moreover, zero mass flux is also accounted at the surface such that the fraction of nanomaterial maintains itself on strong retardation. The governing nonlinear set of partial differential equations is transformed into a set of ordinary differential equations via a suitable combination of variables. The Keller‐Box scheme has been incorporated to make a numerical inspection of the transformed problem. The spectacular impacts of the pertinent constraints on thermal and concentration distributions are elucidated through various plots. Graphical outcomes indicate that the thermal state of nanomaterial and nanoparticles concentration are escalated for elevated amounts of Biot number, porosity parameter and nonuniform heat source/sink constraints. Furthermore, it is also seen that escalating amounts of unsteady parameter, temperature controlling indices, Prandtl number, and expansion ratio parameter reduce the thermal and concentration distributions. Numerical results for the rate of heat transference have been reported in tabular form. The grid independence approach is used to verify the convergence of the numerical solution and the CPU run time is also obtained to check the efficiency of the numerical scheme adopted for finding the solution.     

Thermodynamic screening of suitable oxygen carriers for a three reactor chemical looping reforming system

Hydrogen (H₂) production by using a three reactor chemical looping reforming (TRCLR) technology is an innovative process which utilizes fossil fuels as feed stocks. This process occurs in three steps by employing an oxygen carrier (OC), which is generally a transition metal. As the OC plays an important role, its selection should be done after carefully considering the chemical and physical properties of the material. In this study, various candidate materials for use in a TRCLR process, with methane (CH₄) as a fuel stock, were investigated. The results show that the iron (Fe)- and molybdenum (Mo)-based OCs oxidize CH₄ completely in the FR at low temperatures. In terms of H₂ yield, tungsten (W)-based OCs produce the highest yield, ～3.9 mol-H₂/mol-CH₄. The equilibrium oxygen partial pressures and the solid circulation rates are the highest for Fe-based OCs. The oxygen carrying capacity of Fe-based OCs is relatively high while its price is low. Therefore, among the OCs investigated, Fe-based OCs were identified as the preferred OC option for a TRCLR process.     

Effects of rarefaction,viscous dissipation and rotation mode on the first and second law analyses of rarefied gaseous slip flows confined between a rotating shaft and its concentric housing

A parametric analytical study is carried out to scrutinize the mechanism of fluid flow, heat transfer and entropy generation in a low-speed rarefied gaseous flow confined between a shaft and its concentric housing, i.e., the cylindrical Couette flow. In the first law analysis, closed form solutions for the radial temperature profiles are obtained by incorporating the calculated velocity distribution into the energy equation. The derivations for three thermal cases, which are founded on imposing different thermal conditions, namely, the Uniform Heat Flux (UHF) and the Constant Wall Temperature (CWT) boundary conditions, are presented. In the second law analysis, the contributions of thermal diffusion and fluid friction irreversibility to the total entropy generation in the micro domain are illustrated, and the relevant expressions for the Bejan number and the entropy generation number as well as the average entropy generation rate are derived. Finally, the variations of major variables with influential parameters such as the Knudsen number, the Brinkman number and rotation mode are investigated to elucidate the associated effects of rarefaction phenomenon, viscous dissipation and geometric condition on the characteristics of the flow.     

A newly synthesized single crystal zinc complex as molecular electrocatalyst for efficient hydrogen generation from neutral aqueous solutions

A new chlorobis(2-aminomethylbenzimidazole)zinc(II) perchlorate complex [Zn(AMB)₂Cl](ClO₄) 1 has been synthesized and characterized. Spectral and X-ray structural features led to the conclusion that the zinc(II) complex has a square-pyramidal environment around zinc(II) center with coordination chromophore ZnN₄Cl. Different amounts of complex 1 were supported on glassy carbon (GC) electrode yielding three GC-supported complex 1 electrodes with different loading densities (0.2, 0.4, and 0.8 mg cm^?2). These electrodes were tested as molecular electrocatalysts for the hydrogen evolution reaction (HER) in phosphate buffer aqueous solutions (pH 7), employing linear sweep voltammetry (LSV) and electrochemical impedance spectroscopy (EIS). Results showed that GC-complex 1 catalysts are highly active for the HER, and this catalytic activity enhances with the loading density. The one with the highest loading density (0.8 mg cm^?2) exhibited high HER catalytic activity with low onset potential of ?140 mV vs. RHE and a high exchange current density of 0.22 mA cm^?2. It required an overpotential of 240 mV to achieve a current density of 10 mA cm^?2. It also recorded a turnover frequency (TOF) of 1722 mol of hydrogen per mole of catalyst per hour at overpotential 500 mV, which is comparable with the most active molecular electrocatalysts reported in the literature for H₂ generation from aqueous neutral solutions. A catalytic cycle is proposed for the generation of hydrogen by complex 1 and the mechanism of the HER is discussed based on the measured Tafel slope (140 mV dec^?1).     

Second law analysis of forced convection in a circular duct for non-Newtonian fluids

The second law characteristics of fluid flow and heat transfer inside a circular duct under fully developed forced convection for non-Newtonian fluids are presented. Heat flux is kept constant at the duct wall. Analytical expressions for dimensionless entropy generation number (_NS$N_{\mathrm{S}}$), irreversibility distribution ratio (Φ  ), and Bejan number (Be$\mathit{Be}$) are obtained as functions of dimensionless radius (R$R$), Peclet number (Pe$\mathit{Pe}$), modified Eckert number (Ec$\mathit{Ec}$), Prandtl number (Pr), dimensionless temperature difference (Ω  ), and fluid index (m$m$ or n$n$). Spatial distributions of local and average entropy generation number, irreversibility ratio, and Bejan number are presented graphically. For a particular value of fluid index, n=1$n=1$ (or m=2$m=2$), the general entropy generation number expression for a non-Newtonian power-law fluid reduces to the expression for Newtonian fluid as expected. Furthermore, entropy generation minimization is applied to calculate an optimum fluid index (_nEGM$n_{\mathrm{EGM}}$). A correlation is proposed that calculates _nEGM$n_{\mathrm{EGM}}$as a function of group parameter (Ec×Pr/Ω$\mathit{Ec}\times \mathit{Pr}/\Omega$) and Peclet number (Pe$\mathit{Pe}$) within ±5% accuracy. Finally, for some selected fluid indices, the governing equations are solved numerically in order to obtain Nusselt number. It is observed that the numerically obtained asymptotic Nusselt number shows excellent agreement with the analytically obtained Nusselt number.     

Indirect evaporative cooling: Past,present and future potentials

This paper reported a review based study into the Indirect Evaporative Cooling (IEC) technology, which was undertaken from a variety of aspects including background, history, current status, concept, standardisation, system configuration, operational mode, research and industrialisation, market prospect and barriers, as well as the future focuses on R&D and commercialisation. This review work indicated that the IEC technology has potential to be an alternative to conventional mechanical vapour compression refrigeration systems to take up the air conditioning duty for buildings. Owing to the continuous progress in technology innovation, particularly the M-cycle development and associated heat and mass transfer and material optimisation, the IEC systems have obtained significantly enhanced cooling performance over those the decade ago, with the wet-bulb effectiveness of greater than 90% and energy efficiency ratio (EER) up to 80. Structure of the IEC heat and mass exchanger varied from flat-plate-stack, tube, heat pipe and potentially wave-form. Materials used for making the exchanger elements (plate/tube) included fibre sheet with the single side water proofing, aluminium plate/tube with single side wicked setting (grooved, meshed, toughed etc), and ceramic plate/tube with single side water proofing. Counter-current water flow relevant to the primary air is considered the favourite choice; good distribution of the water stream across the wet surface of the exchanger plate (tube) and adequate (matching up the evaporation) control of the water flow rate are critical to achieving the expected system performance. It was noticed that the IEC devices were always in combined operation with other cooling measures and the commonly available IEC related operational modes are (1) IEC/DEC system; (2) IEC/DEC/mechanical vapour compression system; (3) IEC/desiccant system; (4) IEC/chilled water system; and (5) IEC/heat pipe system. The future potential operational modes may also cover the IEC-inclusive fan coil units, air handle units, cooling towers, solar driven desiccant cycle, and Rankine cycle based power generation system etc. Future works on the IEC technology may focus on (1) heat exchanger structure and material; (2) water flowing, distribution and treatment; (3) incorporation of the IEC components into conventional air conditioning products to enable combined operation between the IEC and other cooling devices; (4) economic, environment and social impacts; (5) standardisation and legislation; (6) public awareness and other dissemination measures; and (7) manufacturing and commercialisation. All above addressed efforts may help increase the market ratio of the IEC to around 20% in the next 20 years, which will lead to significant saving of fossil fuel consumption and cut of carbon emission related to buildings.