Studies on chains of bubbles rising through quiescent liquid

The liquid velocity profile induced by a chain of bubbles is studied theoretically and a comparison with measurements is made. The wake velocity and the bubble shape involved in the theoretical development are considered based on the wake theory and the previous empirical relation for single bubbles, respectively. The shape and wake volume of chain bubbles can be treated in the same manner as those of single bubbles by using relative velocity. As a result, using the previous results of the drag coefficient and shape of single bubbles enables the prediction of the rising velocity of chain bubbles.     

FREE RADICALS FORMED IN HYDROTREATED COAL LIQUID AND INFLUENCE OF OXYGEN

The behavior of radicals formed in hydrotreated coal liquid with heat treatment and the influence of oxygen have been investigated by electron spin resonance (e.s.r.) spectroscopy. A set of e.s.r. spectral lines identified as phenalenyl radical appears from 50^°C as the oil is heated in argon atmosphere. The radical concentration is enhanced with temperature, reaches a maximum between 130 and 150^°C and then decreases at higher temperatures. The radical is very stable even at 200^°C for the sample hydrotreated under mild condition, whereas the radical in the sample treated under severe conditions disappears drastically from 150^°C. When oxygen is introduced in the oil, the radical is converted into semiquinone and/or aryloxy radicals and stable molecules. The treatment in the presence of oxygen at higher temperatures is considered to accompany the formation of other aryloxy radicals by the reaction of aromatic hydrocarbons and oxygen.     

Drug Release Properties of the Microcapsules of Adriamycin Hydrochloride with Ethylcellulose Prepared by a Phase Separation Technique

Adriamycin hydrochloride was microencapsulated with ethylcellulose by a phase separation method to develop a prolonged release dosage form. Polyisobutylene (PIB) was used as a coacervation-inducing agent to control the particle size and drug release rate of the resultant microcapsules. With increasing the concentration of PIB (1 to 3 %) the average diameter of the microcapsules decreased, due to the fact that the microcapsules were discreted to a single microcapsule. At low concentration of PIB, the resultant microcapsules were agglomerated, which resulted in increasing the size. The microcapsules prepared with PIB 2 % prolonged desirably the drug release from the microcapsules. A little size effects of the microcapsules on the drug release rate was found for the microcapsules with PIB 2 % and 3 %.     

Molecular orientation behaviour of uniaxially stretched poly(vinyl chloride) film: 1. Birefringence: effect of plasticizers and draw ratio above and below Tg

In order to investigate the orientation behaviour of a non-crystalline chain polymer, plasticized and unplasticized poly(vinyl chloride) films (PVC) are chosen for investigation. The following two orientation distribution functions are postulated to calculate the second moment of the molecular orientation: (a) for the unplasticized film drawn below the glass transition temperature the distribution function derived from an affine deformation mechanism is applied; (b) for the all plasticized films or for the films drawn above the glass transition temperature a compound distribution function derived from the affine deformation mechanism and that of a rubber-like chain (Langevin model) proposed by Roe et al is applied. The parameters which are included in the distribution function, viz. the ratio of the affine part to the Langevin part, the ratio of polyene to carbonyl in a heat treated film and the segment number of the Langevin chain, can be evaluated experimentally. The intrinsic birefringences of normal and heat treated unplasticized and plasticized films are estimated theoretically on the basis of additivity of band polarizabilities. The calculated birefringences and orientation distribution functions show good agreement with measured values.     

Nonlinear magnetic levitation control by four-point attraction

Rubber components of production equipment are a significant source of contamination in the fabrication of VLSI devices and other semiconductor products. One approach to solving this problem is to use a magnetic levitation system for noncontact transfer. The force nonlinearity of magnetic circuits presents a problem, particularly when the gap between the magnets and the levitated vehicle is small. Linearization methods that allow effective control do exist, but in this paper an alternative method not based on linearization is proposed. The design involves magnetic levitation control by 4-point attraction. The experimental results indicate that the idea is an effective one.     

Rheological properties of iron oxide particle suspensions

Viscosities of γ-Fe₂O₃ dispersions in epoxy resin, phenol resin, and polyvinyl butyral solutions are measured at shear rate D from 19.2 to 384 sec^?1. Volume fraction of γ-Fe₂O₃ in these dispersions ranges from about 0.002 to 0.03. The concentration dependence of relative viscosity η/η_s is closely represented by the Mooney equation. From this equation, intrinsic viscosity [η] of suspensions is found to decrease from 46.1 at D = 19.2sec^?1 to 14 at D = 384 sec^?1 for epoxy resin solution. The high [η] value indicates the existence of flocs containing immobilized liquid. By increasing the shear rate, the average floc size is reduced to point where at an infinite shear rate, only small clusters or possibly particles remain. Of the three polymers, the lowest [η] value is obtained in the dispersion of the phenol resin solution.     

Protein degradation by ERp72 from rat and mouse liver endoplasmic reticulum

The endoplasmic reticulum (ER) resident protein, ER60, is a member of the protein disulfide-isomerase family and contains two copies of the internal thioredoxin motif, CGHC. Previously, ER60 was identified as a cysteine protease and named ER-60 protease (Urade, R., Nasu, M., Moriyama, T., Wada, K., and Kito, M. (1992) J. Biol. Chem. 267, 15152-15159; Urade, R., and Kito, M. (1992) FEBS Lett. 312, 83-86). Here, ERp72, the other member of the protein disulfide-isomerase family containing three CGHC motifs, was isolated from ER of rat and mouse livers through four sequential chromatographies on DEAE-Toyopearl 650, AF-heparin Toyopearl 650M, and TSK gel G3000SW twice. The purified rat protein was found to be homogeneous on sodium dodecyl sulfate-polyacrylamide gel electrophoresis, not being contaminated by ER-60 protease, as judged on immunoblot analysis using an anti-ER-60 protease antibody. The partial amino acid sequence of rat ERp72 was 93% homologous to that of mouse ERp72. The purified rat ERp72 degraded other ER resident proteins such as protein disulfide-isomerase and calreticulin. The purified mouse ERp72 also degraded those proteins. Though rat ERp72 did not basically require Ca2+ for the reaction, the degradation of protein disulfide-isomerase was enhanced, but the degradation of calreticulin was inhibited in the presence of Ca2+. The proteolytic activity of rat ERp72 was inhibited by cysteine protease inhibitors. Its sensitivity to protease inhibitors was the same as that of ER-60 protease. In addition, the proteolytic activity of rat ERp72 was inhibited by acidic phospholipids, also similar to ER-60 protease. Therefore, we propose that ERp72 be named ER-72 protease.     

Piezoelectric ceramics of (Bi1/2Na1/2)TiO3-PbTiO3-BaTiO3 system

Piezoelectric and ferroelectric properties of bismuth sodium titanate, (Bi_1/2Na_1/2)TiO₃(BNT)-based solid solution, that is, (Bi_1/2Na_1/2)(_1-x)(Pb_a Ba_b)_xTiO₃(a + b = 1) [BNPB(100x-100a/100b)], are studied from the viewpoint of a new group of lead-free or low-lead content piezo-electric ceramics with a rhombohedral(F_a-tetragonal (F_β) morphotropic phase boundary (MPB). It is evident that the MPB seems to be remarkably efficacious in promoting piezoelectric and pyroelectric activities by electrical poling. X-ray diffraction data, dielectric properties and D-E hysteresis loops show that the MPB exist near (Bi_1/2Na_1/2)TiO₃[BNT] at x = 0.13–0.14, 0.08–0.09 and 0.06–0.07 in the case of b = 0, b = 0.5 and b = 1, respectively. BNPB ceramics are superior for piezoelectric ceramics in high-frequency ultrasonic uses, or special piezoelectric actuator materials with a lower free permittivity ε₃₃Tε₀, and a high electromechanical coupling factor k₃₃, along with a high mechanical strength.     

The vapour pressures and heats of sublimation of model disperse dyes

The vapour pressures and heats of sublimation of 23 model disperse dyes have been measured by the vapour saturation method (modified transpiration method). The data obtained were in good agreement with those produced by the other investigators using the effusion method. The heats of sublimation are discussed in terms of molecular structure.