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71.
The electronic states of sodium ion (Na+) trapped on the model surfaces of amorphous carbon have been investigated by means of hybrid density functional theory (DFT) calculations to elucidate the nature of interaction between Na+/Na and the amorphous carbon surfaces. Also, direct molecular orbital-molecular dynamics (MO-MD) calculation [Tachikawa and Shimizu, J. Phys. Chem. B, 110 (2006) 20445] was applied to diffusion processes of the Na+ ion on the model surface of amorphous carbon. Seven models of graphene sheets (n = 7, 14, 19, 29, 37, 44 and 52, where n means numbers of rings in each carbon cluster) were considered in the present study. The B3LYP/LANL2MB calculations showed that the sodium ion is located at 2.24-2.26 Å from the graphene surfaces. The direct MO-MD calculations showed that the Na+ ion diffuses freely on the surface above 300 K. At higher temperature (1100 K), the Na+ ion moved from the center to edge region of the model surface. The nature of the interaction between Na+ and the amorphous carbon surfaces was discussed on the basis of theoretical results. 相似文献
72.
Antioxidants were extracted from Japanese pepper (Zanthoxylum piperitum DC.) fruit and characterized. The antioxidant activity of the methanol extract from Japanese pepper fruit was found to be equal to that of α-tocopherol and stable under heat treatment. The main compounds that gave a significant antioxidant activity from the methanol extract were identified to be hyperoside (quercetin-3-O-galactoside) and quercitrin (quercetin-3-O-rhamnoside) as determined by HPLC, mass spectrometry, UV/Vis spectroscopy, and TLC. Radical-scavenging activities of hyperoside and quercitrin from Japanese pepper fruit were evaluated using the 1,1-diphenyl-2-picrylhydrazyl (DPPH) method. As a result, hyperoside and quercitrin scavenged DPPH radical strongly with IC50 values of 16 and 18 μM, respectively. These observations show the presence of strong antioxidants, namely hyperoside and quercitrin in Japanese pepper fruit. 相似文献
73.
The presence of multiple microcracks in a structural component causes material degradation such as reduction in the stiffness or reduction in the fracture toughness of the component. In this paper, the homogenization method is used to evaluate mechanical properties of the damaged material. The adaptation of the superposition method to the homogenization method is also presented. The proposed method makes use of the finite element solution of uncracked solid and the analytical solution. The effective elastic moduli of damaged materials containing lattice-distribution microcracks are estimated by the proposed method. Furthermore, the stress fields and the stress intensity factors of the elliptical microcracks in the damaged material at a micro-mechanics scale are evaluated to illustrate microscopic behavior such as crack interaction. 相似文献
74.
This paper deals with an optimal part selection problem tominimize the expected cost, in an automated manufacturing system in which a flexible manufacturing cell produces different parts for several production lines. The optimal control problem is formulated as an undiscounted semi-Markov decision process. Properties of the optimal policy are analyzed. Moreover, sufficiency conditions are derived for the optimal policy to be of control iimit type. 相似文献
75.
Postdetection selection diversity reception for Nyquist pulse shaped quadrature differential PSK (QDPSK) signal transmissions is addressed. Average bit error rate (BER) performance with differential and coherent demodulation is analysed for multiple-branch diversity reception under slow multipath Rayleigh fading. Diversity effects in real fading environments are verified by 8 and 16 kbit/s transmissions at 1.45 GHz carrier frequency.<> 相似文献
76.
This work is concerned with the application of H/sub /spl infin// control with the generalized hold function (GHF) to track-following control of hard disk drives (HDDs). In HDDs, the sampling frequency is limited primarily by the fact that a high sampling frequency tends to decrease the available data storage capacity of the devices, since the position error signal (PES) must be stored on the disk. Under such conditions, GHF provides a possible way to enhance servo performance without requiring more PES data. We investigate its possibility, comparing the results with other conventional H/sub /spl infin// control design results, including continuous/discrete-time and single/multirate control. Our results show that this controller has better performance due to the nature of the control input of the GHF. 相似文献
77.
Two-dimensional device simulations that confirm that the side-gating effect in GaAs MESFETs occurs on semi-insulating substrates containing hole traps are discussed. A negative voltage applied on a side gate, a separate n-type doped region, causes an increase in the thickness of the negatively charged layer at the FET channel interface in the substrate, through hole emission from hole traps. The FET channel current is modulated by the electron depletion of the n-type channel, which results from the compensation for the extension of the negatively charged layer at the n-i interface into the i-substrate containing hole traps. The magnitude of the drain current reduction is determined by the total acceptor concentration in the substrate and the donor concentration of the channel. However, the magnitude is independent of the side-gate distances 相似文献
78.
M Utsumi K Moriguchi H Takahashi C Kinoshita A Togari M Mizutani N Ohno 《Journal of electron microscopy》1999,48(2):139-145
The ultrastructure of the parathyroid gland (PTG) of the UM-X7.1 cardiomyopathic hamster (the UM-X7.1) was qualitatively and quantitatively compared with that of the normal hamster. In the UM-X7.1, the Golgi apparatus and rER were well developed compared with those of the control hamster. Morphometric analysis revealed that the mean values of the Golgi apparatus, rER and large vacuolar bodies were significantly greater in the UM-X7.1 than in the normal hamster and the mean value of lipid droplets was significantly less in the UM-X7.1 than in the normal hamster. Ultrastructurally, we consider that in the UM-X7.1, the synthesis and release of the parathyroid hormone may be activated by an excessive amount of circulating catecholamine, and the functional activity of the PTG may be higher than that in the normal hamster. 相似文献
79.
Kunio Matsui Jun Kikuma Masamichi Tsunashima Tetsuji Ishikawa Shin-ya Matsuno Akihiro Ogawa Masugu Sato 《Cement and Concrete Research》2011,(5):510-519
The hydrothermal formation of tobermorite during the processing of autoclaved aerated concrete was investigated by in situ X-ray diffraction (XRD) analysis. High-energy X-rays from a synchrotron radiation source in combination with a newly developed autoclave cell and a photon-counting pixel array detector were used.To investigate the effects of the silica source, reactive quartz from chert and less-reactive quartz from quartz sand were used as starting materials. The effect of Al addition on tobermorite formation was also studied. In all cases, C-S-H, hydroxylellestadite and katoite were clearly observed as intermediates.Acceleration of tobermorite formation by Al addition was clearly observed. However, Al addition did not affect the dissolution rate of quartz. Two pathways, via C-S-H and katoite, were also observed in the Al-containing system. These results suggest that the structure of initially formed C-S-H is important for the subsequent tobermorite formation reactions. 相似文献
80.