Low-temperature thermionic emission from nitrogen-doped nanocrystalline diamond films on n-type Si grown by MPCVD

Temperature-dependent emission current–voltage measurements were carried out for nitrogen (N)-doped nanocrystalline diamond (NCD) films grown on n-type Si substrates by microwave plasma-assisted chemical vapor deposition (MP-CVD). Low threshold temperature (~ 260 °C) and low threshold electric field (~ 5 × 10^− 5 V/µm) were observed. Both the temperature dependence and the electric field dependence have shown that the obtained emission current was based on electron thermionic emission from N-doped NCD films. We have also studied the relation between nitrogen concentration and the saturation emission current. The saturation current obtained was as high as 1.4 mA at 5.6 × 10^− 3 V/µm at 670 °C when the nitrogen concentration was 2.4 × 10²⁰ cm^− 3. Low value of effective work function (1.99 eV) and relatively high value of Richardson constant (~ 70) were estimated by well fitting to Richardson–Dushman equation. The results of smaller φ and larger A′ suggest that N-doped NCD has great possibility of being a highly efficient thermionic emitter material.     

Process synthesis by task assignment

An approach by task assignment is presented to determine processing system structures in chemical process design. For given design conditions of major subsystems, which were specified by the results of basic or applied research, a basic flowsheet is determined by task assignments on energy recovery and material flow transportation. An illustrative example shows the usefulness of the present method.     

High-precision voltage-measuring method using fast sampled data for electric power systems

Control and protection equipment in power systems requires higher sensitivity and operational reliability to meet today's changing power system requirements. The voltage-measuring deviation requirement for advanced voltage and var control equipment is less than 0.1 percent under conditions of harmonic distortion in the voltage waveform and power-system frequency variation. Studies on digital signal processing suitable for electric power systems showed that these requirements are satisfied using fast sampling and very fast 32-bit floating point operations by a Digital Signal Processor (DSP). This paper describes the design philosophy of a high-precision power system voltage-measuring method using fast sampled data. In addition, total voltage-measuring deviation characteristics under a combination of the techniques are described along with digital filter characteristics, frequency-measuring deviation characteristics, frequency variation versus gain-compensation characteristics of a digital filter, and peak value operating principles.     

Anodic chlorination of aniline in N,N-dimethyl-formamide and N,N-dimethylacetamide

A pertinent electrochemical synthesis of 2,4,6-trichloroaniline (TCA) in anhydrous media was studied. The influence of the solvent, the chlorinating reagent, the electricity passed and the nature of the anode material, were investigated. TCA was produced in electrolytic solutions whose solvents were amides with strong nucleophilicity as N,N-dimethylformamide (DMF) and N,N-dimethylacetoamide (DMAc), and was obtained selectively by the controlled potential electrolysis of aniline in the solution containing LiCl. The definition of the experimental conditions corresponding to an optimum and selective electrolysis of TCA was described.     

Liquid film dryout in a boiling channel under flow oscillation conditions

A simple theory was developed to elucidate the influence of sinusoidal oscillation of the inlet flow rate on the occurrence of liquid film dryout in an annular two-phase flow regime in a boiling channel. The theory assumes that the critical heat flux (CHF) under an oscillatory condition can be calculated from values in steady states provided that the effect of axial mixing of the liquid film is appropriately considered. The trends of CHFs calculated using a one-dimensional three-fluid model and those experimentally measured under atmospheric pressure were in reasonable agreement with the proposed theory. However, the CHF values measured under oscillatory conditions were usually higher in the experiment than in the numerical simulation, which indicated that axial liquid transport induced by disturbance waves might enhance axial mixing of the liquid film.     

Direct contact melting of porous material

The direct contact melting of a porous material is investigated experimentally and analytically. The phase change material (PCM) is made of fine ice particles of a nearly uniform diameter, which is changed as a parameter. In the analysis, two models are proposed. One is calculated as the direct contact melting of a monolithic sample and another is treated as an assembly of the direct contact melting of the individual particles. As a result, it was found that the heat flux increased with the diameter, due to increase of permeability in a case of small diameter. But, in a case of large diameter, the heat flux decreased as the particle diameter increased because the direct contact melting occurred independently for the individual particles.