Study of contact angle, wettability and water vapor permeability in carboxymethylcellulose (CMC) based film with murta leaves (Ugni molinae Turcz) extract

Edible films have been extensively studied with the aim to find an adequate formulation that allows improving food quality and safety. Both wettability and water-barrier properties are two important parameters that must be considered for an adequate design of edible coatings. The aim of this work was to measure the contact-angle of film solution based on carboxymethylcellulose (CMC) with murta leaf (Ugni molinae Turcz) extract to estimate the wettability on apple and quince skins and measure the water vapor permeability (WVP) of films. The results show that murta leaves extract did not affect the contact angle and wettability measured on the fruits surface. However, differences were obtained between apple and quince skin which can be explained because the dispersive component of surface tension of quince skin was lower than apple skin. The WVP was not affected by murta leaves extract incorporation. This allows concluding that the film properties assayed were not modified by the incorporation of murta leaves extract ecotype 14-4.     

Efficient implementation of pseudochaotic piecewise linear maps with high digitization accuracies

In this paper we discuss the efficient implementation of pseudochaotic piecewise linear maps with high digitization accuracies, taking the R'enyi chaotic map as a reference. The proposed digital architectures are based on a novel algorithmic approach that uses carry save adders for the nonlinear arithmetic modular calculations arising when computing piecewise linear maps with a finite precision. As a result, the system can be implemented by digital circuits obtaining high throughputs, which are not dependent on the digital resolution while involving a hardware complexity linearly proportional to the number of bits used for representing the discretized state. The proposed solutions result to be particularly suitable for the implementation of pseudorandom number generators based on pseudochaos, or for the definition of efficient digital blocks that can be integrated in most of the pseudochaotic cyphers proposed in the literature. Copyright © 2010 John Wiley & Sons, Ltd.     

Graphical method to select vegetable oils as potential feedstock for biodiesel production

Chemical compositions of 80 vegetable oils were collected from literature and the properties of the obtainable biodiesel (methyl esters) have been predicted by empirical relationships. The purpose has been to check the viability of predicting if a biodiesel could meet the EN 14214 standards knowing only the fatty acid profile (FAP) of the parent oil. Two parameters were used in this investigation: (i) average number of carbon atoms in the fatty acid chains, (ii) average number of double bonds (C?C) per molecule. Two new empirical relationships have been proposed to predict the viscosity and the cetane number of biodiesel from the two parameters. The range of values of the two parameters leading to biodiesel meeting the EN 14214 standard for viscosity, cetane number, iodine value, and cold filter plugging point have been graphically obtained by overlapping the corresponding level surfaces. Practical applications: This work provides biodiesel producers with indications of the quality of biodiesel without the need for analytical testing of the product (indeed, of the product itself). Only the fatty acid profile of the starting vegetable oil is required. The quality of biodiesel can be estimated by using a chart developed in this work, allowing to estimate, e.g. if the biodiesel meets the European standards. The work can be useful to rapidly screen oil seed crops in studies of genetic engineering that require high throughput.     

Diagnostic expert systems: a method for engineering knowledge used in sequential diagnosis

The paper presents a method for helping knowledge engineers in modelling the knowledge involved in sequential diagnosis. In particular, we consider sequential diagnosis as a process which occurs in the following type of scenario: (1) there exist some candidate hypotheses which are to be pursued; (2) for each hypothesis there are some alternative tests which might be executed to pursue it; (3) the available knowledge about the world precludes projecting into the future (in other words, the available knowledge about the world does not afford the information needed for planning sequences of tests, i.e. for projecting the consequences of possible sequences of actions and picking the best sequence); (4) the choice of the next test (or tests) is made on the basis of the current state of knowledge; (5) the outcome of a test execution is affected by uncertainty. The suggested method addresses the problem of engineering the knowledge experts use for making decisions under uncertainty. A practical example of the method is also presented: at any time of the diagnostic process the expert is provided with a dynamically updated list of suggested tests in order to support him or her in the decision-making problem about which test to execute next.     

Structure and morphology of solution blended poly(vinylidene fluoride)/montmorillonite nanocomposites

Nanocomposites based on poly(vinylidene fluoride) were prepared with montmorillonite by solution blending. The samples were characterized by small angle X‐ray scattering, wide angle X‐ray diffraction, Fourier transform infrared spectroscopy, and differential scanning calorimetry. Different crystallization conditions, that is, evaporation of the solvent and coprecipitation with two different antisolvents, H₂O or supercritical CO₂ (scCO₂), were tested and their influence on the resulting structure and morphology of the samples were studied. Coprecipitation with scCO₂ induced an ordinate crystalline framework and an intercalated morphology of clay, with a consequent large improvement in modulus. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Sustainability assessment of hydrogen production by steam reforming

A specific methodology was applied to investigate the expected impact on sustainability of processes for hydrogen production by steam reforming of natural gas. Reference process schemes based on the current industrial state-of-the-art and on innovative steam reforming technologies were defined and assessed. The methodology allowed the calculation of a sustainability “fingerprint” of the reference schemes, based on sustainability key performance indicators. The results obtained evidenced the potential advantages of innovative processes, based on integrated conversion and internal membrane separation reactors. However, the valorization of the by-product streams is an essential requirement to reduce the impact on sustainability of these processes. Besides the improvement of the reaction section, the optimization of the overall separation efficiency and of energy requirement emerged as the key elements that control the overall sustainability performance of these processes.     

Autosomal Dominant Gyrate Atrophy-Like Choroidal Dystrophy Revisited: 45 Years Follow-Up and Association with a Novel C1QTNF5 Missense Variant

We present a long-term follow-up in autosomal dominant gyrate atrophy-like choroidal dystrophy (adGALCD) and propose a possible genotype/phenotype correlation. Ophthalmic examination of six patients from two families revealed confluent areas of choroidal atrophy resembling gyrate atrophy, starting in the second decade of life. Progression continued centrally, reaching the fovea at about 60 years of age. Subretinal deposits, retinal pigmentation or choroidal neovascularization as seen in late-onset retinal degeneration (LORD) were not observed. Whole genome sequencing revealed a novel missense variant in the C1QTNF5 gene (p.(Q180E)) which was found in heterozygous state in all affected subjects. Haplotype analysis showed that this variant found in both families is identical by descent. Three-dimensional modeling of the possible supramolecular assemblies of C1QTNF5 revealed that the p.(Q180E) variant led to the destabilization of protein tertiary and quaternary structures, affecting both the stability of the single protomer and the entire globular head, thus exerting detrimental effects on the formation of C1QTNF5 trimeric globular domains and their interaction. In conclusion, we propose that the p.(Q180E) variant causes a specific phenotype, adGALCD, that differs in multiple clinical aspects from LORD. Disruption of optimal cell-adhesion mechanisms is expected when analyzing the effects of the point mutation at the protein level.     

Biodiesel from fried vegetable oils via transesterification by heterogeneous catalysis

Three solid catalysts have been tested in the transesterification of fried oils: CaO, SrO, K₃PO₄. For CaO and SrO the different efficiency, between their use as powder or granules, has been examined. Another investigated aspect has been the catalytic activity at different catalyst loadings and recycles. At the end granules have been employed in a catalytic bed reactor, comparing results with batch systems. Results have shown that using catalyst as granule does not affect the yields after 3 h of reaction. The use of the catalytic bed reactor has given the possibility to perform the transesterification maintaining the catalyst separated from the reactants, without loss of efficiency; in fact the comparison between trials in batch reactor and in catalytic bed system has not shown differences in yields. After 3 h of reaction, at 65 °C, 5 wt% of catalyst, we have had the following FAME yields: 92% for CaO, 86% for SrO, 78% for K₃PO₄. The transesterification reaction has shown a sensitive influence respect to K₃PO₄ granules amount used; in fact the yield has reached the 85% using 10 wt% of catalyst. The reutilization of the catalyst, without regeneration, has shown a loss of efficiency of about 10-20% in decreasing yield.     

CFD modeling of LPG vessels under fire exposure conditions

Fire exposure of tanks used for the storage and transportation of liquefied gases under pressure may cause complex heat‐ and mass‐transfer phenomena that may contribute to compromise the integrity of the vessels in accident scenarios. Heat transfer through vessel lading results in the heat‐up of the internal fluid and the increase of vessel internal pressure. However, local temperature gradients in the liquid phase cause liquid stratification phenomena that result in a more rapid vaporization and pressure build‐up in the liquid phase. These fundamental phenomena were analyzed by a computational fluid dynamic model. The model was specifically focused on the early steps of vessel heat‐up, when liquid stratification plays a relevant role in determining the vessel internal pressure. A two‐dimensional transient simulation was set up using ANSYS FLUENT in order to predict the evolution of the liquid and vapor phases during the tank heat up. The model was validated against large scale experimental data available for liquefied petroleum gas vessels exposed to hydrocarbon fires, and was applied to case studies derived from recent accidental events in order to assess the expected time of pressure build‐up in different fire scenarios. © 2014 American Institute of Chemical Engineers AIChE J 60: 4292–4305, 2014     

Land-sea mercury transport through a modified watershed, SE Brazil

River management has altered the land-sea transport of water, sediments, and chemical compounds with profound impacts on the structure of continental and costal ecosystems. Understanding riverine transport across modified watersheds allow for better assessment of the influence of river management on material fluxes to coastal waters. Here, we assess the quantitative and qualitative aspects of mercury (Hg) transport across a modified watershed by diversion of Paraíba do Sul River waters into Sepetiba Bay, Brazil. We measured concentrations and speciation of Hg in water samples collected at sites within the modified watershed. These data, together with water discharge and sediment load from numerical models and measurements were used to estimate mass balances. In the Sepetiba watershed, mercury is mainly associated with suspended sediments (90%) and therefore Hg flux displayed the characteristic trend of downstream reduction due to trapping efficiency of particulate load by successive reservoirs. The mass balance suggests that the major source of mercury to Sepetiba Bay is the erosion of soil-derived particles from the drainage basin rather than mercury diverted from Paraíba do Sul River watershed.