Television in Chile: A History of Experiment and Reform

The unique features of the television system in the early 1970s—its mandate for social participation through representative governance and the mixed support of state and commercial advertising—were overtaken by a centralized and commercial system that is now being reevaluated in light of these original goals.     

Orientation and crystallinity in film casting of polypropylene

In the cast film process a polymer melt is extruded through a slit die, stretched in air, and cooled on a chill roll. During the path in air the melt cools while being stretched. Film casting experiments were carried out with an isotactic polypropylene resin. The temperature and width distributions were measured along the draw direction. Further, the crystallinity and Hermans orientation factor were measured on the final film. The process was described by a simple thermomechanical model derived elsewhere. The evolution of the molecular orientation parameters was calculated on the basis of a dumbbell model coupled with velocity and temperature distributions provided by the thermomechanical model. The experimental crystalline orientations of the final films collapsed into a single step‐shaped curve (from low to high orientation) if plotted versus the stress calculated by the model at the frozen line. The experimental values of the crystallinity and Hermans orientation factors are discussed on the basis of predictions of the dumbbell model for melt orientation at the frozen line and the crystallinity data obtained in quiescent conditions under the same cooling rate. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 1981–1992, 2002; DOI 10.1002/app.10422     

Comparative study of structural and optical properties of ZnO nanostructures prepared by three different aqueous solution methods

In the present work, zinc oxide (ZnO) nanoparticles with different morphologies and sizes were successfully synthesized via three different aqueous solution routes named proteic sol–gel, PVA-assisted sol–gel and microwave-assisted hydrothermal method. Sol–gel samples were crystallized into hexagonal structure after calcination at 350 °C, presenting uniform growth and predominantly spherical particles. On the other hand, the sample produced via hydrothermal method assumed nanorod morphology, probably due to the adsorption of ammonium on the surface of ZnO nuclei, which affect the growth orientation of the crystals. All the samples exhibited a sharp UV emission peak, related to excitonic recombination, and a broad emission band in the visible region, attributed to internal transitions in color centers. Sol–gel samples calcined at the lowest temperatures presented an UV emission intensity that was 44 and 89 times higher than the visible emission, which can be related to the passivation of the defects by hydrogen ions. As-prepared hydrothermal sample presented a broad emission band centered at approximately 596 nm, which is possibly related to OH groups adsorbed on the particle surfaces. Nevertheless, the emission band of samples calcined above 800 °C was shifted to 540 nm, which is probably related to oxygen vacancy according to the results from chemical analysis.     

Structure of Ego‐Alter Relationships of Politicians in Twitter

We analyze the ego‐alter Twitter networks of 300 Italian MPs and 18 European leaders, and of about 14,000 generic users. We find structural properties typical of social environments, meaning that Twitter activity is controlled by constraints that are similar to those shaping conventional social relationships. However, the evolution of ego‐alter ties is very dynamic, which suggests that they are not entirely used for social interaction, but for public signaling and self‐promotion. From this standpoint, the behavior of EU leaders is much more evident, while Italian MPs are in between them and generic users. We find that politicians – more than generic users – create relationships as a side effect of tweeting on discussion topics, rather than by contacting specific alters.     

Definition and Implementation of a SAML-XACML Profile for Authorization Interoperability Across Grid Middleware in OSG and EGEE

In order to ensure interoperability between middleware and authorization infrastructures used in the Open Science Grid (OSG) and the Enabling Grids for E-science (EGEE) projects, an Authorization Interoperability activity was initiated in 2006. The interoperability goal was met in two phases: firstly, agreeing on a common authorization query interface and protocol with an associated profile that ensures standardized use of attributes and obligations; and secondly implementing, testing, and deploying on OSG and EGEE, middleware that supports the interoperability protocol and profile. The activity has involved people from OSG, EGEE, the Globus Toolkit project, and the Condor project. This paper presents a summary of the agreed-upon protocol, profile and the software components involved.     

Streaming simplification of tetrahedral meshes

Unstructured tetrahedral meshes are commonly used in scientific computing to represent scalar, vector, and tensor fields in three dimensions. Visualization of these meshes can be difficult to perform interactively due to their size and complexity. By reducing the size of the data, we can accomplish real-time visualization necessary for scientific analysis. We propose a two-step approach for streaming simplification of large tetrahedral meshes. Our algorithm arranges the data on disk in a streaming, I/O-efficient format that allows coherent access to the tetrahedral cells. A quadric-based simplification is sequentially performed on small portions of the mesh in-core. Our output is a coherent streaming mesh which facilitates future processing. Our technique is fast, produces high quality approximations, and operates out-of-core to process meshes too large for main memory     

Injection molding of syndiotactic polystyrene/clay nanocomposites

This study aims at exploring the effect of a commercial organoclay montmorillonite (MMT) on the final properties of syndiotactic polystyrene (sPS) injection‐molded samples. To this goal, injection‐molded specimens made from neat sPS and commercial MMT modified with various organic compounds were prepared in different molding conditions. Dispersion of clay was attained via melt blending, directly in the injection chamber of the injection‐molding machine. The obtained specimens were analyzed by IR spectroscopy, X‐ray diffraction, thermogravimetry, and differential thermal analysis, with the aim of elucidating the effect of clay on the microstructures of the samples. Results clearly show that, depending on the organic modification, the presence of clay can induce strong effects on final crystallinity. This behavior can be attributed mainly to the role played by clay on the kinetics of the crystallization process. Eventually, it was found that the addition of a small percentage of clay (1%) in sPS can substantially widen the processing window of the material. POLYM. ENG. SCI. 46:1768–1777, 2006. © 2006 Society of Plastics Engineers.     

Putting value of information theory into practice: a methodology for building sequential decision support systems

Abstract: The paper presents a methodology for building sequential decision support systems based on decision theory using value of information (for short, DT‐VOI based SDSSs). DT‐VOI based SDSSs support decision‐makers in difficult problems of sequential decision‐making. In particular we consider the problem of building DT‐VOI based SDSSs which are capable of supporting decisions in critical situations where (1) making a decision entails knowing the states of some critical hypotheses, and such knowledge is acquired by performing suitable tests; (2) test outcomes are uncertain; (3) performing a test entails, in general, some drawbacks, so that a trade‐off exists between such drawbacks and the value of the information provided by the test; (4) performing a test has the side‐effect that it changes the expected benefit from performing other tests; (5) exceptional situations alter probability and utility default values.