Influence of Compaction and Granulation Processes on the Properties of Soft Magnetic Ceramics

The granulation and compaction processes are investigated in relation to the influence they have on the magnetic permeability and electromagnetic power losses of conventionally prepared polycrystalline manganese-zinc ferrites. It appears that, during granulation by spray-drying, rapid evaporation conditions may be reached at the internal of the under drying droplets, giving rise to the formation of large void defects in the interior of the granulate. Those defects may resist compaction and also be present in the compacted specimens, eventually leading to large intragranular isolated pores and lower densities at the sintered material; the magnetic properties of the material are therefore negatively influenced. Compaction at high pressures (e.g., >500 kg cm⁻²) may compensate for the existence of inflation defects by causing their removal on compaction. The previous phenomenon is absent in granulates made by the roll granulation process that exhibit, in general, a better compaction, sintering, and magnetic behavior when compared to spray-drying granulates at conditions where void formation takes place.     

Proportional delay differentiation provision by bandwidth adaptation of class‐based queue scheduling

Supporting quality of service (QoS) over the Internet is a very important issue and many mechanisms have already been devised or are under way towards achieving this goal. One of the most important approaches is the so‐called Differentiated Services (DiffServ) architecture, which provides a scalable mechanism for QoS support in a TCP/IP network. The main concept underlying DiffServ is the aggregation of traffic flows at an ingress (or egress) point of a network and the marking of the IP packets of each traffic flow according to several classification criteria. Diffserv is classified under two taxonomies: the absolute and the relative. In absolute DiffServ architecture, an admission control scheme is utilized to provide QoS as absolute bounds of specific QoS parameters. The relative DiffServ model offers also QoS guarantees per class but in reference to the guarantees given to the other classes defined. In this paper, relative proportional delay differentiation is achieved based on class‐based queueing (CBQ) scheduler. Specifically, the service rates allocated to the classes of a CBQ scheduler are frequently adjusted in order to obtain relative delay spacing among them. The model presented can also be exploited in order to meet absolute delay constraints in conjunction with relative delay differentiation provision. Simulation experiments verify that our model can attain relative as well as absolute delay differentiation provided that the preconditions posed are satisfied. Copyright © 2004 John Wiley & Sons, Ltd.     

Design principles for spray-roasted iron oxides for the manufacturing of ferrites

A range of high purity iron oxides are prepared by varying basic operation parameters of an industrial spray roasting process. These iron oxides are investigated in relation to their morphology and subsequently evaluated as raw materials for MnZn-ferrite preparation. It appears that the most important morphological parameters for determining the reactivity (defined as firing shrinkage at equal compaction density) of the high purity iron oxide, and consequently the final density and magnetic properties of the ferrite specimens, are the primary particle size and the number of primary particles per aggregate. As found, the specific surface area of the iron oxide is of no predictive value for the behavior of the iron oxide in a MnZn-ferrite manufacturing process. A small primary particle size is important for a high reactivity; however, when particles are packed together in large aggregates, they are not available for the prefiring reactions. As a result, reactive sintering takes place leading to high porosity and bad microstructure. As found by the characterization methods employed in this article, the optimum iron oxides for MnZn-ferrite preparation should have a primary particle size between 0.45 and 0.55 μm with an aggregate size below 1.60 μm.     

Inequality path constraints in optimal control: a finite iteration -convergent scheme based on pointwise discretization

This paper presents a new result in the analysis and implementation of path constraints in optimal control problems (OCPs). The scheme uses the well-known concept of discretizing path constraints on a finite number of points, yielding a set of interior-time point constraints replacing the original path constraints. The approach replaces the original OCP by a sequence of OCPs which is shown to converge in a finite number of steps to the solution of the original path constrained problem with -accuracy. Numerical results, verifying the theoretical analysis, are presented. The method is shown to be effective and promising for future applications, particularly in control vector parameterization implementations.     

Processing and storage effects on the oxidative stability of hemp (Cannabis sativa L.) oil‐in‐water emulsions

Hempseed oil was used to form oil‐in‐water emulsions, and the effect of heating, storage and light on the oxidative stability of the dispersed phase was investigated. Lipid oxidation rate increased following thermal processing and light exposure, whereas oxidation markers remained relatively unaffected during emulsions storage at 4 °C for 10 days. Induction times of the emulsions were reduced up to 26% and the concentration of thiobarbituric acid reactive substances increased up to 4.5‐fold, depending on the processing conditions. Selected berries as potential sources of natural antioxidants were screened for polyphenol and anthocyanin content in order to investigate their ability to retard lipid oxidation in comparison with a commercially available synthetic counterpart. Raspberry powder extract significantly improved the oxidative stability of hemp‐based emulsion compared with the control and was even more effective compared to a synthetic antioxidant when samples were subjected to heat treatment.     

Properties and structure of dynamic robot models for control engineering applicationsStructure et proprietes des modeles dynamiques robotiques a appliquer au controle automatique

Controller design for robotic manipulators requires a fundamental physical understanding of the properties and structure of dynamic robot models. This paper focuses on the Lagrangian formulation which is attractive from both the dynamic modeling and control engineering points-of-view. Physical and mathematical properties and structural characteristics of the complete dynamic robot model are demonstrated. Implications of the model for control system analysis and design are then indicated. Physical interpretation leads naturally to the decomposition of the model into the positioning arm and end-effector subsystems and motivates the application of decentralized control to robotic manipulators. The authors then propose the application of control the positioning arm and artificial intelligence and intelligent sensors to control the end-effector.     

Water quality of Vistonis Lagoon, Northern Greece: seasonal variation and impact of bottom sediments

The aim of this study is to present the seasonal variation of nutrients in the water column and the bottom sediments of Vistonis Lagoon, a hypereutrophic Mediterranean coastal lagoon located in Northern Greece, and to estimate the impact of bottom sediments on the water quality of this lagoon. Nutrient concentrations in the water column and in bottom sediments were determined throughout seven seasonal sampling cruises from May 2003 to October 2004. Physicochemical parameters, such as transparency, temperature, salinity, pH and dissolved oxygen, were measured in situ in the water column using suitable equipment. Nutrient concentrations in bottom water were found generally higher than those in surface water. Nitrogen, mainly as nitrates, and phosphorus are released into the water column from the bottom sediments, especially during the summer period. Anoxia in the bottom water, as well as resuspension of the sediments are the main factors affecting nutrient internal loading in this lagoon. An approximate calculation showed that total phosphorus release was about 80 mg m⁻² d⁻¹ for the period March–August 2004. Vistonis Lagoon restoration will be possible only through the minimization or elimination of both external and internal nutrient loadings.     

Optical switching of electric charge transfer pathways in porphyrin: a light-controlled nanoscale current router

We introduce a novel molecular junction based on a thiol-functionalized porphyrin derivative with two almost energetically degenerate equilibrium configurations. We show that each equilibrium structure defines a pathway of maximal electric charge transfer through the molecular junction and that these two conduction pathways are spatially orthogonal. We further demonstrate computationally how to switch between the two equilibrium structures of the compound by coherent light. The optical switching mechanism is presented in the relevant configuration subspace of the compound, and the corresponding potential and electric dipole surfaces are obtained by ab initio methods. The laser-induced isomerization takes place in two steps in tandem, while each step is induced by a two-photon process. The effect of metallic electrodes on the electromagnetic irradiation driving the optical switching is also investigated. Our study demonstrates the potential for using thiol-functionalized porphyrin derivatives for the development of a light-controlled nanoscale current router.     

Multilevel converters for single-phase grid connected photovoltaic systems: an overview

Multilevel voltage source inverters offer several advantages compared to their conventional counterparts. By synthesising the AC output terminal voltage from several levels of DC voltages, staircase waveforms can be produced, which approach the sinusoidal waveform with low harmonic distortion, thus reducing filter requirements. The need of several sources on the DC side of the converter makes multilevel technology attractive for photovoltaic applications. This paper provides an overview on different multilevel topologies and investigates their suitability for single-phase grid connected photovoltaic systems. Several transformerless photovoltaic systems incorporating multilevel converters are compared regarding issues such as component count and stress, system power rating and the influence of the photovoltaic array earth capacitance.