An investigation into surface energetics of rice hull ash particles using Inverse Gas Chromatography (IGC)

Silanol groups that are present on the surface of rice hull ash or silica ash fillers can positively influence the reinforcing character of the filler. However, being hydrophilic, they present the problem of aggregation and moisture absorption. Physicochemical contributions to reinforcement, provided by silanol groups, influence the filler-polymer and filler-filler interactions. In this study, we investigated the surface energetics of silica ash particles and the effect of chemical surface modification on the free surface energy of silica ash particles was studied.Inverse Gas Chromatography (IGC), a successful evaluation technique for the surface energy of solids, has been used at infinite dilution to determine the nature of surface interaction of various probes with a silica ash surface. The Gibbs free energies and enthalpies of specific interactions were also determined to estimate the acid-base characteristics of the surface of silica ash particles. The influence of heat treatment and surface modification upon the physicochemical parameters was also investigated. It was found that the silica ash surface is acidic in nature. Modification of the surface, by hydrophobization using silane agents, reduces the specific component of surface energy and could be expected to positively affect the reinforcing character. Surface modification reduced the specific component of surface energy by 80% and positively affects the filler-matrix interaction.     

Assessment of sperm count in rural population of central India

26 clinician trainees' recollections of experiences in a diagnostic preschool program were analyzed in terms of strength and weaknesses of the program.     

Transient Turbulent Flow in a Liquid-Metal Model of Continuous Casting,Including Comparison of Six Different Methods

Computational modeling is an important tool to understand and stabilize transient turbulent fluid flow in the continuous casting of steel to minimize defects. The current work combines the predictions of two steady Reynolds-averaged Navier–Stokes (RANS) models, a “filtered” unsteady RANS model, and two large eddy simulation (LES) models with ultrasonic Doppler velocimetry (UDV) measurements in a small-scale liquid GaInSn model of the continuous casting mold region fed by a bifurcated well-bottom nozzle with horizontal ports. Both mean and transient features of the turbulent flow are investigated. LES outperformed all models while matching the measurements, except in locations where measurement problems are suspected. The LES model also captured high-frequency fluctuations, which the measurements could not detect. Steady RANS models were the least accurate methods. Turbulent velocity variation frequencies and energies decreased with distance from the nozzle port regions. Proper orthogonal decomposition analysis, instantaneous velocity patterns, and Reynolds stresses reveal that velocity fluctuations and flow structures associated with the alternating-direction swirl in the nozzle bottom lead to a wobbling jet exiting the ports into the mold. These turbulent flow structures are responsible for patterns observed in both the time average flow and the statistics of their fluctuations.     

Surfactant assisted synthesis and spectroscopic characterization of selenium nanoparticles in ambient conditions

In this work, an attempt has been made to synthesize well-distributed stable selenium (Se) particles of nanosize dimensions via an aqueous micellar solution by the assistance of surfactants of two different polarities (anionic, sodium bis(2-ethylhexyl)sulfosuccinate (AOT) and cationic, hexadecyltrimethylammonium bromide (CTAB)). The morphology of the particles was examined with transmission electron microscopy (TEM). X-ray analysis reveals that the particles have a monoclinic structure. The band gap of the particles was determined from UV-visible optical spectroscopic results. The size variation was estimated by employing a quantum confinement effect equation. The evolution of the selenium nanoparticles in AOT and CTAB micellar media was corroborated with the time-dependent absorption spectra. The influence of hydrazine hydrate concentrations on the formation kinetics of Se nanoparticles was also investigated. The capping ability of the surfactants has been quantitatively evaluated from Fourier transform infrared (FTIR) studies.     

Kinetics and mechanism of corrosion of laboratory hot briquetted iron

While considerable work has been reported in the literature on the corrosion behavior and products of direct reduced iron and sponge iron, very little has been published on hot briquetted iron (HBI). The present article reports the kinetics and mechanism of HBI corrosion. As corrosion is an electrochemical process, measurements using electrochemical techniques have been made and these are compared to data gained by measuring mass changes in the briquettes over time. Similar trends were seen in data from both techniques, and the corrosion extent predicted by electrochemical measurements in saline solution was very close to the mass gain result obtained. Kinetic analysis of the data from mass gain over time trials was conducted. The activation energy for corrosion at temperatures between 25 °C and 80 °C has been calculated. The values of activation energy obtained indicate that corrosion was predominantly controlled by diffusion of oxygen in the liquid state. The internal structure of the briquettes was observed by microscopy both before and after corrosion in distilled water.     

Sex Differences and Individual Differences in Cognitive Performance and Their Relationship to Endogenous Gonadal Hormones and Gonadotropins.

Sexually dimorphic cognitive performance in men (n=42) and women (n=42) was related to testosterone, estradiol, progesterone, luteinizing hormone, follicle-stimulating hormone, and sex hormone binding globulin, measured in 10-ml blood samples collected between 0900 and 1030 and, among women, during the follicular phase of the menstrual cycle. Significant sex differences favored men on spatial tasks (Mental Rotation and Judgment of Line Orientation) and on an inhibition task and favored women on a verbal task (category fluency). However, there were no significant relationships between any of the hormones and cognitive performance, suggesting that there are few, if any, consistent, substantial relationships between endogenous, nonfluctuating levels of gonadal hormones or gonadotropins and these cognitive abilities in men or women. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Effect of Electromagnetic Ruler Braking (EMBr) on Transient Turbulent Flow in Continuous Slab Casting using Large Eddy Simulations

Static electromagnetic braking (EMBr) fields affect greatly the turbulent flow pattern in steel continuous casting, which leads to potential benefits such as decreasing flow instability, surface defects, and inclusion entrapment if applied correctly. To gain a fundamental understanding of how EMBr affects transient turbulent flow, the current work applies large eddy simulations (LES) to investigate the effect of three EMBr ruler brake configurations on transient turbulent flow through the bifurcated nozzle and mold of a liquid-metal GaInSn model of a typical steel slab-casting process, but with deep nozzle submergence and insulated walls with no solidifying shell. The LES calculations are performed using an in-house graphic-processing-unit-based computational-fluid-dynamics code (LES-CU-FLOW) on a mesh of ~7?million brick cells. The LES model is validated first via ultrasonic velocimetry measurements in this system. It is then applied to quantify the mean and instantaneous flow structures, Reynolds stresses, turbulent kinetic energy and its budgets, and proper orthogonal modes of four cases. Positioning the strongest part of the ruler magnetic field over the nozzle bottom suppresses turbulence in this region, thus reducing nozzle well swirl and its alternation. This process leads to strong and focused jets entering the mold cavity making large-scale and low-frequency (<0.02?Hz) flow variations in the mold with detrimental surface velocity variations. Lowering the ruler below nozzle deflects the jets upward, leading to faster surface velocities than the other cases. The double-ruler and no-EMBr cases have the most stable flow. The magnetic field generates large-scale vortical structures tending toward two-dimensional (2-D) turbulence. To avoid detrimental large-scale, low-frequency flow variations, it is recommended to avoid strong magnetic fields across the nozzle well and port regions.     

Temperature-dependent formation of a conjugate between tris(hydroxymethyl)aminomethane buffer and the malondialdehyde-DNA adduct pyrimidopurinone

OBJECTIVE: To examine the effects of cardiopulmonary bypass (CPB) on total and unbound plasma concentrations of propofol and midazolam when administered by continuous infusion during cardiac surgery. DESIGN: Prospective clinical study. SETTING: University hospital. PARTICIPANTS: Twenty-four adult patients undergoing cardiac surgery. INTERVENTIONS: Patients received either propofol or midazolam to supplement fentanyl anesthesia. Twelve patients received a propofol bolus (1 mg/kg) followed by an infusion of 3 mg/kg/hr. A second group received midazolam, 0.2 mg/kg bolus, followed by an infusion of 0.07 mg/kg/hr. MEASUREMENTS AND MAIN RESULTS: Blood sample were collected from the radial artery cannula at 0, 2, 4, 8, 8, 10, 15, 20 minutes and then every 10 minutes before CPB, at 1, 2, 3, 4, 6, 10, 15, 20 minutes and then each 10 minutes during CPB. On weaning from CPB samples were collected at 0, 5, 10 and 20 minutes. Plasma binding, total and unbound propofol and midazolam concentrations were determined by ultrafiltration and high-pressure liquid chromatography (HPLC). CPB resulted in a fall in total propofol and midazolam plasma concentrations, but the unbound concentrations remained stable. The propofol unbound fraction increased from 0.22 +/- 0.06% to 0.41 +/- 0.17%. The midazolam unbound fraction increased from 5.6 +/- 1.0% to 11.2 +/- 2.1%. CONCLUSIONS: Unbound concentrations of propofol and midazolam are not affected by cardiopulmonary bypass. Total intravenous anesthesia algorithms do not need to be changed to achieve stable unbound plasma concentrations when initiating CPB.     

Sexual orientation-related differences in prepulse inhibition of the human startle response.

Prepulse inhibition (PPI) refers to a reduction in the startle response to a strong sensory stimulus when this stimulus is preceded by a weaker stimulus--the prepulse. PPI reflects a nonlearned sensorimotor gating mechanism and also shows a robust gender difference, with women exhibiting lower PPI than men. The present study examined the eyeblink startle responses to acoustic stimuli of 59 healthy heterosexual and homosexual men and women. Homosexual women showed significantly masculinized PPI compared with heterosexual women, whereas no difference was observed in PPI between homosexual and heterosexual men. These data provide the first evidence for within-gender differences in basic sensorimotor gating mechanisms and implicate the known neural substrates of PPI in human sexual orientation. (PsycINFO Database Record (c) 2010 APA, all rights reserved)