Bioprocesses for the removal of nitrogen oxides from polluted air

Nitrogen oxides (NOx) of environmental concern are nitrogen monoxide (NO) and nitrogen dioxide (NO₂). They are hazardous air pollutants that lead to the formation of acid rain and tropospheric ozone. Both pollutants are usually present simultaneously and are, therefore, called NOx. Another compound is N₂O which is found in the stratosphere where it plays a role in the greenhouse effect. Concern for environmental and health issues coupled with stringent NOx emission standards generates a need for the development of efficient low‐cost NOx abatement technologies. Under such circumstances, it becomes mandatory for each NOx‐emitting industry or facility to opt for proper NOx control measures. Several techniques are available to control NOx emissions: selective catalytic reduction (SCR), selective non‐catalytic reduction (SNCR), adsorption, scrubbing, and biological methods. Each process offers specific advantages and limitations. Since bioprocesses present many advantages over conventional technologies for flue gas cleaning, a lot of interest has recently been shown for these processes. This article reviews the major characteristics of conventional non‐biological technologies and recent advances in the biological removal of NOx from flue gases based on the catalytic activity of either eucaryotes or procaryotes, ie nitrification, denitrification, the use of microalgae, and a combined physicochemical and biological process (BioDeNOx). Relatively uncomplicated design and simple operation and maintenance requirements make biological removal a good option for the control of NOx emissions in stationary sources. Copyright © 2005 Society of Chemical Industry     

Optimal error bounds for the MITC4 plate bending element

Abstract One of the most popular finite element method for Reissner-Mindlin plates is the so-called MITC4 method. Unfortunately, until recently, the best error estimate available in the literature for this element needs a non-optimal and generally unrealistic regularity for the solution. Here we derive optimal error estimates for this well-known low-order finite element method, which are valid for a general family of meshes. A similar result has recently been obtained elsewhere, with the same mesh restrictions. The exposition presented here is totally different.     

Defect pyrochlore structure A2B2X6: A general approach to the coordination polyhedra around the metal ions

On the basis of the distances A-X and B-X, in the defect pyrochlores A₂B₂O₆, a general approach to the coordination polyhedra around A and B metal ions is established. Results show that, depending on these distances, coordination of 3+3 and 3+3+3 around A ions can be found and that a region of low stability should exist.     

Compatibility studies between ibuprofen or ketoprofen with cellulose ether polymer mixtures using thermal analysis

Differential scanning calorimetry (DSC) was used to investigate and detect incompatibilities between drugs such as: ibuprofen (IBU) or ketoprofen (KETO) with cellulose ether derivatives, which are frequently applied on controlled release dosage forms. Binary mixtures concerning methylcellulose (MC25) or hydroxypropylcellulose (HPC) with hydroxypropylmethylcellulose (HPMC) K15M or K100M in different ratios were prepared and evaluated by the appearance, shift, or disappearance of peaks and/or variations in the corresponding ΔH values. According to the DSC results, binary mixtures between those polymers were found to be compatible, but their mixture with IBU or KETO, promotes a solid-solid interaction mainly with 1:1:1 (w/w) ratio (drug-excipient). However, when the drug:excipient interactions were detected, they were not found to affect the drug bioavailability. DSC was successfully employed to evaluate the compatibility of the drugs with the selected polymers.     

Hydrodynamic behaviour and comparison of technologies for the removal of excess biomass in gas-phase biofilters

The hydrodynamic behaviour of a biofilter fed toluene and packed with an inert carrier was evaluated on start-up and after long-term operation, using both methane and styrene as tracers in Residence Time Distribution experiments. Results indicated some deviation from ideal plug flow behaviour after 2-year operation. It was also observed that the retention time of VOCs gradually increased with time and was significantly longer than the average residence time of the bulk gas phase. Non-ideal hydrodynamic behaviour in packed beds may be due to excess biomass accumulation and affects both reactor modeling and performance. Therefore, several methods were studied for the removal of biomass after long-term biofilter operation: filling with water and draining, backwashing, and air sparging. Several flow rates and temperatures (20-60 degrees C) were applied using either water or different chemicals (NaOH, NaOCl, HTAB) in aqueous solution. Usually, higher flow rates and higher temperatures allowed the removal of more biomass, but the efficiency of biomass removal was highly dependent on the pressure drop reached before the treatment. The filling/draining method was the least efficient for biomass removal, although the treatment did basically not generate any biological inhibition. The efficiency of backwashing and air sparging was relatively similar and was more effective when adding chemicals. However, treatments with chemicals resulted in a significant decrease of the biofilter's performance immediately after applying the treatment, needing periods of several days to recover the original performance. The effect of manually mixing the packing material was also evaluated in duplicate experiments. Quite large amounts of biomass were removed but disruption of the filter bed was observed. Batch assays were performed simultaneously in order to support and quantify the observed inhibitory effects of the different chemicals and temperatures used during the treatments.     

Elasto-plastic analysis of bonded joints with macro-elements

The Finite Element (FE) method could be able to address the stress analysis of bonded joints. Nevertheless, analyses based on FE models are mainly computationally cost expensive and it would be profitable to develop simplified approaches, enabling extensive parametric studies. Firstly, a one-dimensional 1D-bar and 1D-beam simplified models for the bonded joint stress analysis, assuming a linear elastic adhesive material, are presented. These models derive from an approach, inspired by the FE method using a formulation based on a four-node macro-element, which is able to simulate an entire bonded overlap. Moreover, a linear shear stress variation in the adherend thickness is included in the formulation. Secondly, a numerical procedure is then presented to introduce into both models an elasto-plastic adhesive material behavior, while keeping the previous linear elastic formulation. Finally, assuming an elastic perfectly plastic adhesive material behavior, the results produced by simplified models are compared with the results predicted by FE using 1D-bar, plane stress, and three-dimensional (3D) models. Good agreements are shown.     

Risk factors in oil and gas industry returns: International evidence

The recent boom in oil prices has attracted many investors to oil companies in search of both returns and diversification benefits. This analysis of the risk factors of investing in the oil and gas industry in 34 countries finds evidence that oil price is a globally priced factor for the oil industry. The oil and gas sector in developed countries responds more strongly to oil price changes than in emerging markets. Oil and gas industry returns also respond asymmetrically to changes in oil prices; oil price rises have a greater impact than oil price drops. There is no parallel to the asymmetry of oil price changes in other industries related to commodities. If there is any asymmetry, it is in the opposite direction from oil. Negative commodity price changes have a greater impact than positive ones. The results seem to indicate that the oil and gas industry is distinguished by a pass-through effect.     

Extraction of carotenoids from Phaffia rhodozyma: A comparison between different techniques of cell disruption

The yeast Phaffia rhodozyma is known for producing carotenogenic pigments, commonly used in aquaculture feed formulation as well as in cosmetic, pharmaceutical, and food industries. Despite the high production of carotenoids from microorganisms by biotechnology, their use has limitation due to the cell wall resistance, which constitutes a barrier to the bioavailability of carotenoids. Therefore, there is a need to improve carotenoids recovering technique from microorganisms for the application of food industries. This study aimed to compare mechanical, chemical, and enzymatic techniques of cell disruption for extracting carotenoids produced by P. rhodozyma NRRL Y-17268. Among the techniques studied, the highest specific concentration of carotenoids (190.35 μg/g) resulted from the combined techniques of frozen biomass maceration using diatomaceous earth and enzymatic lysis at pH of the reaction medium of 4.5 at 55°C, with initial activity of β-1,3 glucanase of 0.6 U/mL for 30 min.     

The catalytic activity of the Pr2Zr2−xFexO7±δ system for the CO oxidation reaction

One of the alternatives to decrease the concentration of CO is its oxidation reaction to CO₂, which can be made more efficient using catalysts. In this work, it is shown that pyrochlore structures are a promising candidate to act as heterogeneous catalysts due to their chemical and physical properties. For use as a catalyst in this reaction, the Pr₂Zr_2−xFe_xO_7±δ (x = 0, 0.05, 0.10, and 0.15) system was synthesized by the solvothermal method, firing the powder obtained at temperatures of 1200 and 1400°C. The diffraction patterns confirmed the pyrochlore structure as the single phase in all the nominal compositions. The Brunauer–Emmett–Teller method and dynamic light-scattering analysis showed an increase in the particle size and a decrease in the specific surface area when increasing the iron concentration and increasing the calcination temperature. The compositions that presented the best catalytic activity were the samples with the highest iron concentration. Moreover, these samples were able to convert all the CO oxidation reactions in a narrower temperature range than a conventional CeO₂ sample. The presence of vacancies and the redox behavior of the elements present are the key factors for the catalysis of this system in the CO oxidation reaction.