熔加色素法搪瓷色釉结构的研究

用ＳＥＭ、ＷＤＳ、ＩＲＲＳ、ＸＰＳ和ＡＳＳ对搪瓷色釉结构进行了研究熔加法的搪瓷色釉具有均匀分布的小尺寸、数量小的气孔。分析了搪瓷色釉的Ｏ１ｓ谱，并分解了成桥氧、非桥氧、及自由氧。熔加法的桥氧浓度远大于磨加法，而熔加法的非桥氧的浓度远低于磨加法，这表明熔加法的搪瓷色釉的结构强度高于磨加法。     

聚酯型超分散剂对聚丙烯/无机填料复合材料力学性能的影响

合成了以聚己内酯为溶剂化链,以四乙烯五胺或多乙烯多胺为锚固基团的“梳形”超分散剂t-ZTPCL和p- ZTPCL,并将其用于聚丙烯／高岭土填料复合材料,研究了分散剂对复合体系力学性能的分散和增强效果。结果表明: ZTPCL对聚丙烯／高岭土复合材料具有明显的增强效果和分散作用。t-ZTPCL质量分数为0．5％～1．0％或p-ZTPCL质量分数为0．5％-2．5％时,复合材料的拉伸强度明显高于未加分散剂的复合材料,部分材料的拉伸强度超过纯PP。摩尔质量为2 000g/mol的p-ZTPCL对复合材料拉伸强度的提高尤为显著,质量分数为2．0％时,复合材料的拉伸强度较纯 PP的提高7．4％,比未加分散剂的提高22．8％。     

煤制合成气低温甲醇洗配管总结

本文根据以煤为原料的合成氨工艺装置中低温甲醇洗涤净化系统的特点，对其配管在工程设计时的一些特殊要求进行总结，供工程设计人员参考。     

H∞ filtering for discrete-time systems subject to stochastic missing measurements: a decomposition approach

This paper deals with the problem of H_∞ filtering for discrete-time systems with stochastic missing measurements. A new missing measurement model is developed by decomposing the interval of the missing rate into several segments. The probability of the missing rate in each subsegment is governed by its corresponding random variables. We aim to design a linear full-order filter such that the estimation error converges to zero exponentially in the mean square with a less conservatism while the disturbance rejection attenuation is constrained to a given level by means of an H_∞ performance index. Based on Lyapunov theory, the reliable filter parameters are characterised in terms of the feasibility of a set of linear matrix inequalities. Finally, a numerical example is provided to demonstrate the effectiveness and applicability of the proposed design approach.     

Relationship between chemical degradation and thickness loss of an amine-cured epoxy coating exposed to different UV environments

The relationship between chemical degradation and thickness loss of an unpigmented, non UV-stabilized, crosslinked amine-cured epoxy coating exposed to three UV conditions was investigated. Spin-coated samples having a thickness of approximately 7 μm on an Si substrate were prepared from a stochiometric mixture of a bisphenol A epoxy resin and a tetra-functional amine curing agent. Samples were exposed outdoors and to two accelerated laboratory UV environments. Chemical degradation and thickness loss were measured by transmission Fourier transform infrared spectroscopy (FTIRS) and laser scanning confocal microscopy (LSCM), respectively. In addition, surface roughness and morphological changes were measured by atomic forcemicrosocopy (AFM) and LSCM. Substantial chemical degradation, thickness loss, and morpholocal changes occurred in the exposed films, and the rate of chemical degradation was greater than that due to the thickness loss. This additional chemical loss was attributed to an inhomogeneous degradation process in which nanoscale localized depressions initiate at certain sites on the surface, which then enlarge and deepen with exposure time. The results of this study provide a better understanding of the degradation mechanism and should lead to the development of scientific-based models for predicting the service life of crosslinked amine-cured epoxy coatings. Presented at the 82nd Annual Meeting of the Federation of Societies for Coatings Technology, October 27–29, 2004, in Chicago, IL     

拟稳态法测定气相扩散系数

根据拟稳态一维扩散原理,建立了气相扩散系数的测定装置。在该装置上,测定了8个体系的气相扩散系数,其中CH_2Cl_2-空气,CH_2Cl_2-H_2,CH_3CH_2Br-空气,CH_3Cl_2Br-H_2,CHCl_3-H_2等5个体系的气相扩散系数实验值,迄今尚未见文献报道。实验结果表明,本测试装置稳定性好,实验误差小,实验装置体积小,测试过程较为简便。     

Hydrogen and Oxygen Bubble Attachment to a Bitumen Drop

Air bubble – bitumen attachment is a critical step in the flotation of bitumen from mined oil sand. In this study, single bubble – bitumen drop attachment was observed directly using a novel experimental technique. Induction time is determined and used as an indication of bubble‐bitumen attachment potency for both hydrogen and oxygen bubbles. The attachment tests were conducted in deaerated municipal water (City of Edmonton tap water) at temperatures ranging from 22–50°C. Induction times measured for hydrogen bubble attachment were shorter than those for oxygen bubbles. Coalescence tests were also conducted in the absence of bitumen, and showed that hydrogen bubbles coalesced more rapidly than oxygen bubbles in both deaerated municipal water and clear (solids‐free) process water.     

New polyimide–silica organic–inorganic hybrids

A series of polyimide–silica hybrid films with silica contents up to 30 wt % were successfully prepared by the sol‐gel reaction of tetraethoxysiliane in the presence of poly(amic acid) containing pendent hydroxyl groups. The films were yellow and transparent when the silica content was less than 11 wt %. The chemical structure of the films was characterized by Fourier transform infrared spectroscopy, and the morphology of the films was investigated by scanning electronic microscopy and atomic force microscopy. Thermogravimetric analysis, differential scanning calorimetry, and stress–strain tests were used to measure the performance of the films. The results indicate that the glass‐transition temperatures and decomposition temperatures of the hybrid films increased with increasing silica content, whereas the tensile strength had a maximum with the variety of silica contents. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 2210–2214, 2003     

Pb(Mg_(1+x)/3Nb_(2-x)/3)O_3铁电材料中有序-无序相变的理论研究

基于Kikuchi自洽迭代方法,利用有序-无序相变理论,并取最近邻相互作用近似,研究了Pb(Mg_((1+x)/2)Nb_((2-x)/2)O_3晶粒中在x=0.5时有序区形成的原因,提出Mg~(2+)∶Nb~(5+)=1∶1(离子数比)时,形成B位有序排列最为有利,并且弱的空间电荷场不影响这种有序排列的形成,同时给出了温度-组份的有序-无序相图。     

明胶和胶囊生产干燥新工艺的研究

本文介绍了氯化锂液体除湿的工作原 理,并深入分析了其除湿工艺、主要特点和在 明胶与胶囊干燥方面的研究和应用。