Synthesis and properties of novel amphiphilic sulfated ionomers by the ring‐opening reaction of an epoxidized styrene–butadiene–styrene triblock copolymer

A method for the synthesis of novel sulfated ionomer of styrene–butadiene–styrene triblock copolymer (SBS) was developed. SBS was first epoxidized by performic acid in the presence of a phase‐transfer catalyst; this was followed by a ring‐opening reaction with an aqueous solution of alkali salt of bisulfate. The optimum conditions for the ring‐opening reaction of the epoxidized SBS with an aqueous solution of KHSO₄ were studied. During the ring‐opening reaction, both phase‐transfer catalyst and ring‐opening catalyst were necessary to enhance the conversion of epoxy groups to ionic groups. The products were characterized with Fourier transform infrared spectrophotometry and transmission electron microscopy (TEM). After the potassium ions of the ionomer were substituted with lead ions, the lead sulfated ionomer exhibited dark spots under TEM. Some properties of the sulfated ionomer were studied. With increasing ionic groups or ionic potential of the cations, the water absorbency and emulsifying volume of the ionomer and the intrinsic viscosity of the ionomer solution increased, whereas the oil absorbency decreased. The sulfated ionomer possessed excellent emulsifying properties compared with the sulfonated SBS ionomer. The sodium sulfated ionomers in the presence of 10% zinc stearate showed better mechanical properties than the original SBS. When the ionomer was blended with crystalline polypropylene, a synergistic effect occurred with respect to the tensile strength. The ionomer behaved as a compatibilizer for blending equal amounts of SBS and oil‐resistant chlorohydrin rubber. In the presence of 3% ionomer, the blend exhibited much better mechanical properties and solvent resistance than the blend without the ionomer. SEM photographs indicated improved compatibility between the two components of the blend in the presence of the ionomer. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

导向剂加入方式对Y型沸石合成的影响

以煤系高岭土为原料,采用液态补硅手段调节体系SiO2/Al2O3、导向剂两步加入法合成了Y型沸石.考察了导向剂不同加入方式对Y型沸石合成的影响.采用合理的导向剂两步加入法,特别是通过控制导向剂第二步加入的时间,可明显缩短Y型沸石的晶化时间,并有效地减少P型沸石的生成.     

关于传统与现代设计理念的思考

中国传统的思维方式深深地影响了中国传统陶瓷艺术设计，中国传统陶瓷艺术设计的历史脉络清晰，深入到设计思维系统的深层，才有助于我们对当前的陶瓷设计作出有效的转化。现代陶瓷设计的观念是对传统陶瓷文化的延续和发展，深入挖掘传统思维方式的源头活水，才是发展中国现代陶瓷设计的关键。     

Experimental Study on Energy Consumption of Combined Conventional and Dehumidification Drying

Conventional drying, dehumidification drying, and combined conventional-dehumidification drying of wood were experimentally studied in this article. The results showed that the energy consumption in the dehumidification drying is the least but its drying time is the longest. The energy consumption in the combined drying is more than that in the dehumidification drying but less than that in the conventional drying, and the drying time is half of that in the dehumidification drying. The advantages of the combined conventional and dehumidification drying are discussed from the experiments results.     

穿黄工程异型接头板研制与应用

本文介绍了新研制的异形接头板结构特点和工作原理,该异型接头板成功应用于南水北调中线一期穿黄工程北岸地下连续墙工程中。     

EC与~（99m）Tc－GH之间的配体交换反应动力学研究

实验表明，ＥＣ浓度与配体交换反应速度常数无关，体系的ｐＨ值对速度常数和９９ｍＴｃ－ＥＣ的标记率影响较大。测定并计算了不同ｐＨ值的交换反应速度常数。结果表明，为保证用配体交换法制备９９ｍｃ－ＥＣ时９９ｍｃ－ＥＣ的标记率大于９０％，体系的ｐＨ值必须≥８。     

温度,压力对漂移室气体增益的影响

研究了温度及气体压力对漂移室（工作于正比区）气体放大倍数的影响，温度和气体压力的变化范围分别是５￣４０℃及９０￣１０５ｋＰａ。用实验数据拟合得到了函数关系并测量了几种饱和度下函数中的参数值。     

入侵检测在存储区域网中的应用

从SAN(存储区域网)的安全隐患出发,分析了SAN在应用环境中受到的三种典型威胁。结合现行的入侵检测技术给出一个可行的解决方案。     

A conditional classification recurrent RBM for improved series mid-term forecasting

In the context of human-robot and robot-robot interactions, the better cooperation can be achieved by predicting the other party’s subsequent actions based on the current action of the other party. The time duration for adjustment is not sufficient provided by short term forecasting models to robots. A longer duration can by achieved by mid-term forecasting. But the mid-term forecasting models introduce the previous errors into the follow-up forecasting and amplified gradually, eventually invalidating the forecasting. A new mid-term forecasting with error suppression based on restricted Boltzmann machine(RBM) is proposed in this paper. The proposed model can suppress the error amplification by replacing the previous inputs with their features, which are retrieved by a deep belief network(DBN). Furthermore, a new mechanism is proposed to decide whether the forecasting result is accepted or not. The model is evaluated with several datasets. The reported experiments demonstrate the superior performance of the proposed model compared to the state-of-the-art approaches.

     

The fractal effect of irregularity of crack branching on the fracture toughness of brittle materials

Microstructural observations of brittle materials indicated that a variety of microdefect events can be responsible not only for inelastic behaviour, but also for macroscopic crack front irregularity. This irregularity produces an increase in the fracture toughness of the material. In this paper, this irregularity is analysed by fractal geometry in a very simple manner; a fractal model of crack branching is established. Both microscopic and macroscopic analytical results show that the toughness can be raised appreciably as a fractal geometric effect of the irregularity.

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Résumé Des observations microscopiques sur des matériaux fragiles ont montré qu'une variété d'évènements à l'échelle du microdéfaut peuvent être responsables non seulement du comportement inélastique, mais aussi de l'irrégularité du front d'une fissure macroscopique. Cette irrégularité provoque un accroissement de la ténacité à la rupture du matériau. Dans cette étude, on analyse de manière très simple cette irrégularité par fractogéométrie (Mandelbrot) et on établit un modèle fractal relatif à une fissure qui se ramifie. Les résultats de l'analyse microscopique et macroscopique montrent qu'un effet fractogéométrique de l'irrégularité du front de fissure est d'accroitre de manière appréciable la ténacité.