An evaluation of the alternative transport fuel policies for Turkey

The search for alternative fuels and new fuel resources is a top priority for Turkey, as is the case in the majority of countries throughout the world. The fuel policies pursued by governmental or civil authorities are of key importance in the success of alternative fuel use, especially for widespread and efficient use. Following the 1973 petroleum crisis, many users in Turkey, especially in transportation sector, searched for alternative fuels and forms of transportation. Gasoline engines were replaced with diesel engines between the mid-1970s and mid-1980s. In addition, natural gas was introduced to the Turkish market for heating in the early 1990s. Liquid petroleum gas was put into use in the mid-1990s, and bio-diesel was introduced into the market for transportation in 2003. However, after long periods of indifference governmental action, guidance and fuel policies were so weak that they did not make sense. Entrepreneurs and users experienced great economical losses and lost confidence in future attempts to search for other possible alternatives. In the present study, we will look at the history of alternative fuel use in the recent past and investigate the alternative engine fuel potential of Turkey, as well as introduce possible future policies based on experience.     

Design and installation of solar photovoltaic powered water pumping system at Usmanu Danfodiyo University, Sokoto

The paper presents the outcome of the powering of a conventional a.c. type water pump by photovoltaic (pv) solar modules which were 28 in number connected 7 in series giving a total of 4 parallel strings. An assesment of the system, which provides water to the University Mechanical Workshop and a nearby village, shows that the system has been operating continously since October 1993 and on average 20 m³ of water is pumped daily at average solar radiation level of 5kWh/m²/day.     

Enhancement of hydrogen storage properties in 4MgH2 Na3AlH6 composite catalyzed by TiF3

In this work, we have investigated the hydrogen release and uptake pathways storage properties of the MgH₂Na₃AlH₆ with a molar ratio of 4:1 and doped with 10 wt% of TiF₃ using a mechanical alloying method. The doped composite was found to have a significant reduction on the hydrogen release temperature compared to the un-doped composite based on the temperature-programme-desorption result. The first stage of the onset desorption temperature of MgH₂Na₃AlH₆ was reduced from 170 °C to 140 °C with the addition of the TiF₃ additive. Three dehydrogenation steps with a total of 5.3 wt% of released hydrogen were observed for the 4MgH₂Na₃AlH₆-10 wt% TiF₃ composite. The re/dehydrogenation kinetics of 4MgH₂Na₃AlH₆ system were significantly improved with the addition of TiF₃. Kissinger analyses showed that the apparent activation energy, E_A, of the 4MgH₂Na₃AlH₆ doped composite was 124 kJ/mol, 16 kJ/mol and 34 kJ/mol lower for un-doped composite and the as-milled MgH₂, respectively. It was believed that the enhancements of the MgH₂Na₃AlH₆ hydrogen storage properties with the addition of TiF₃ were due to formation of the NaF, the AlF₃ and the Al₃Ti species. These species may played a synergetic catalytic role in improving the hydrogenation properties of the MgH₂Na₃AlH₆ system.     

A study on the hydrogen storage properties and reaction mechanism of Na3AlH6LiBH4 composite system

In this work, the hydrogen storage properties of different molar ratio (in mole of 1:3 and 1:4) Na₃AlH₆LiBH₄ system is investigated for the first time. X-ray diffraction and Fourier transform infrared results show that the Na₃AlH₆LiBH₄ with molar ratio of 1:3 and 1:4 composite was transformed to Li₃AlH₆ and NaBH₄ phases via a metathesis reaction during a ball-milling process for 6 h. Temperature-programmed-desorption (TPD) results show three stages of decomposition for the Na₃AlH₆LiBH₄ (in mole ratio of 1:3 and 1:4) composite resulting from Li₃AlH₆ and NaBH₄ phases. From the TPD graph, the Na₃AlH₆LiBH₄ composite with molar ratio of 1:4 had showed better performance of hydrogenation properties compared to with molar ratio of 1:3. The composite began to release hydrogen at 180 °C in relation to decomposition of the Li₃AlH₆ stage into LiH and Al. The NaBH₄ stage then began to decompose at approximately 380 °C, after reacting with Al to form an intermetallic phase, AlB₂, which occurred at 100 °C lower than as-milled NaBH₄. At 430 °C, the un-reacted NaBH₄ was decomposed after catalysing with AlB₂. Kissinger analysis shows the apparent activation energy of NaBH₄ decomposition in the hydrides composite was reduced by about 75 kJ/mol compared to the as-milled NaBH₄. The rehydrogenation process evidenced the reversibility of NaBH₄. Based on these results, the intermetallic phase, AlB₂, is considered to have played an important role by lowering the operating temperature and providing access to the full hydrogen content in the Na₃AlH₆LiBH₄ composite system.     

Platinum‐promoted fibrous silica Y zeolite with enhanced mass transfer as a highly selective catalyst for n‐dodecane hydroisomerization

A fibrous silica zeolite Y (HY@KCC‐1) catalyst with a high surface area of 568 m²/g and unique core‐shell morphology was successfully synthesized via a modified KCC‐1 synthesis method. Characterization of the catalysts was achieved with X‐ray powder diffraction (XRD), field emission scanning microscope (FESEM), N₂ adsorption/desorption, and 2,6‐dimethylpyridine adsorbed Fourier‐transform infrared spectroscopy (FTIR). The Pt/HY@KCC‐1 has displayed complete n‐dodecane conversion coupled with an incredibly enhanced isomer yield of 72% at 350°C, nearly two‐fold higher than that of unmodified Pt/HY catalyst. Remarkably, Pt/HY@KCC‐1 had an internal effectiveness factor (η) of unity and negligible internal diffusion limitation, thus suggesting its potential application in hydroisomerization of higher hydrocarbons for enhancing fuel properties.     

Fabrication of oxide pellets containing lumped Gd2O3 using Y2O3‐stabilized ZrO2 for burnable absorber fuel applications

In this paper, the fabrication of novel burnable absorber fuel concepts with oxide pellets, containing either a lumped Gd₂O₃ rod, a mini‐pellet, or a spherical particle in the centerline of the oxide pellet, is investigated to propose the lumped Gd₂O₃ burnable absorber fuel concept to improve nuclear fuel performance with longer fuel cycle lengths and better fuel utilization. The unique characteristic of the lumped Gd₂O₃ burnable absorber fuel is its high spatial self‐shielding factor that reduces its burnout rate and, therefore, improves the reactivity control. Oxide pellets containing lumped Gd₂O₃ were fabricated by using a combination of cold isostatic pressing and microwave sintering at 1500°C to understand the potential technical issues in the fabrication of duplex burnable absorber fuel. The effect of the sintering temperature on the densification and phase transformation of 8 wt.% yttria‐stabilized zirconia, a surrogate for UO₂, was investigated. Spherical Gd₂O₃ particles were fabricated by the drip casting of a Gd₂O₃‐based Na alginate solution. The fabrication of duplex oxide pellets by using presintered Gd₂O₃ mini‐pellets resulted in internal cracks at the interface between the Gd₂O₃ and 8 wt.% yttria‐stabilized zirconia layers because of the mismatch of their densification. However, the formation of interfacial cracks was eliminated by controlling the initial sintered density of the lumped Gd₂O₃.     

A parametric study of coupled‐mode flutter for MW‐size wind turbine blades

With the increasing size of offshore wind turbine rotors, the design criteria used for the blades may also evolve. Current offshore technology utilizes three relatively stiff blades in an upwind configuration. With the goal of minimizing the mass, there is an interest in the lightweight rotors that instead utilize two flexible blades oriented downwind. These longer blades are more flexible and thus susceptible to experience flow‐induced instability. Coupled‐mode flutter is one of the destructive aeroelastic instabilities that can occur in flexible structures subjected to aerodynamic loading. Because of variation in one of the system parameters, e.g., flow velocity, structural modes coalesce at a critical flow velocity, and coupled‐flutter occurs. In the present work, a parametric study is conducted in order to study the influence of the natural frequencies in the torsional and flapwise directions on the critical flutter speed for wind turbine blades. Three MW‐size wind turbine blades are studied using a three‐dimensional blade model, which includes coupled flapwise and torsional displacements. The results show that the three blades have very similar behavior as the system parameters vary. It is shown that the first torsional natural frequency and the ratio of the first torsional natural frequency to the first flapwise natural frequency are the most critical parameters affecting the onset of instability. Critical flutter speeds even lower than the blade rated speed can be observed for blades with low torsional natural frequencies. Copyright © 2015 John Wiley & Sons, Ltd.     

Degradation kinetics of β-carotene in carrot slices during convective drying

The β-carotene degradation was investigated in carrot (Daucus carota L. cv Nantes) slices during convective drying at three temperatures (45, 55, and 65°C) at an airflow rate of 0.2 m s^–1. Degradation kinetics of β-carotene in carrot slices during convective drying followed a first-order reaction. Drying temperature showed a significant effect on the degradation of β-carotene in carrot slices. The range of the reaction rate constants for β-carotene loses were 0.23 ± 0.08 –0.48 ± 0.04 h^–1. The activation energy of β-carotene degradation is found 33.33 ± 0.05 kJ mol^–1. Half-life time was calculated as 3.02 ± 0.04 h at 45°C, which dropped to 1.43 ± 0.03 h at 65°C.