Ultraviolet-visible and surface-enhanced Raman scattering spectroscopy studies on self-assembled films of ruthenium phthalocyanine on organic monolayer-modified silver substrates

A self-assembled film of ruthenium phthalocyanine (RuPc) fabricated on a silver substrate pre-modified with a monolayer of 4-mercaptopyridine (PySH) or 1,4-bis[2-(4-pyridyl)ethenyl]-benzene (BPENB) was studied by ultraviolet-visible (UV-Vis) and surface enhanced Raman scattering (SERS) spectroscopy. PySH or BPENB was used as a ligand to link RuPc since they not only modify the silver substrate, but also deliver a pyridyl group pointing out from the silver surface. Therefore, we can explore the relationship between the structure and orientation of metallophthalocyanine and the substrate modified by the two kinds of organic-monolayers with the different conjugates and molecular lengths. UV-Vis bands due to the organic-monolayer (PySH or BPENB) modified silver films shift to longer wavelengths and a new band arising from the metallophthlocyanine appears, suggesting the binding of RuPc to PySH/BPENB, as well as the interaction between the marcocycle of RuPc and the ring of PySH/BPENB. Vibrational bands arising from both the RuPc and PySH/BPENB moieties appear clearly in the SERS spectra of the RuPc-PySH/BPENB composite films, indicating that RuPc is successfully assembled on the top of PySH/BPENB film. The shifts and relative intensity changes of bands due to PySH or BPENB in the SERS spectra imply the binding of the metallophthalocyanine to the pyridyl group in the composite films. Furthermore, the comparison of the SERS spectra revealed that the orientations of PySH and BPENB in the two kinds of composite films are different; the BPENB moiety in the RuPc-BPENB composite film is more perpendicular to the silver surface compared with the PySH moiety in the RuPc-PySH composite film.     

Truly Concomitant and Independently Expressed Short‐ and Long‐Term Plasticity in a Bi2O2Se‐Based Three‐Terminal Memristor

Concomitance of diverse synaptic plasticity across different timescales produces complex cognitive processes. To achieve comparable cognitive complexity in memristive neuromorphic systems, devices that are capable of emulating short‐term (STP) and long‐term plasticity (LTP) concomitantly are essential. In existing memristors, however, STP and LTP can only be induced selectively because of the inability to be decoupled using different loci and mechanisms. In this work, the first demonstration of truly concomitant STP and LTP is reported in a three‐terminal memristor that uses independent physical phenomena to represent each form of plasticity. The emerging layered material Bi₂O₂Se is used for memristors for the first time, opening up the prospects for ultrathin, high‐speed, and low‐power neuromorphic devices. The concerted action of STP and LTP allows full‐range modulation of the transient synaptic efficacy, from depression to facilitation, by stimulus frequency or intensity, providing a versatile device platform for neuromorphic function implementation. A heuristic recurrent neural circuitry model is developed to simulate the intricate “sleep–wake cycle autoregulation” process, in which the concomitance of STP and LTP is posited as a key factor in enabling this neural homeostasis. This work sheds new light on the development of generic memristor platforms for highly dynamic neuromorphic computing.     

汽车座椅调角器耐久性试验机的研制

介绍了一种用于汽车座椅调角器疲劳耐久性试验的测试设备,叙述了该设备的设计思想,机械结构,硬件组成,控制系统,软件设计,试验方式等。实际运行表明,设备运行稳定安全可靠,试验方法简单方便。     

露天矿生产车辆安排计划优化设计

本文结合露天矿车辆生产安排计划的特点,全面分析了车辆安排问题约束条件,构建了基于整数规划的线路车次安排数学模型。利用线性规划对电铲进行初始布点,实现对模型的合理简化,加速模型的求解。考虑到电铲利用率很难达到1,为提高模型最优解的实际应用的可行性,增加了车辆调度的弹性,设置了电铲的最大利用率。为保证电铲有一定的利用率,设置了电铲最小利用率。计算表明本模型具有较好的实用性和通用性。     

神经控制（Ⅰ）─—神经元控制

介绍了作者在神经控制──神经元控制方面的研究成果，主要包括面向控制的神经元模型、神经元控制系统、神经元无模型控制方法和应用实例。     

Analysis of the drude model in metallic films

A method, believed to be new, to simulate Drude parameters for collective oscillation of the free carriers in metallic films is proposed. Plasma resonance frequency and relaxation were simulated simultaneously from both the real and the imaginary parts of the dielectric function of a metallic film after consideration of their correlation in the Drude model. As examples, the contributions of the electrons in Ag films and of the free carriers in metallic silicide, NbSi(2) and TaSi(2), films have been studied.     

Microstructure and mechanical property of laser melting deposition (LMD) Ti/TiAl structural gradient material

This article presents fabrication, microstructure and mechanical properties study of Ti/TiAl functional gradient material. Ti–47Al–2.5V–Cr/Ti–6Al–2Zr–Mo–V gradient material was successfully fabricated by the laser melting deposition (LMD) manufacturing process. Microstructure and chemical composition was characterized by OM, SEM, TEM and EPMA. The Vickers hardness and room-temperature tensile property was evaluated on longitudinal direction. Results showed that fully lamellar (FL) microstructure consisted of γ-TiAl and α₂-Ti₃Al was formed on the Ti–47Al–2.5V–Cr side, while coarse basket weave microstructure was formed on the Ti–6Al–2Zr–1Mo–1V side. No cracking was found in the gradient zone after aging at 800 °C for 48 h. The room-temperature tensile strength of the as-deposited specimen is up to approximately 1198.8 MPa in the longitudinal direction, while the tensile elongation is approximately 0.4%, indicating a typical brittle fracture.     

唯物思想者托尼·克拉格雕塑展

有的艺术家通过改变物体的形态来创作艺术品,有的通过改变人们对物体的固有认知来创作艺术品。托尼·克拉格（T0nycragg）两者兼备。9月8日,这位当代雕塑史上的领军人物携177件作品在上海证大喜玛拉雅美术馆展出,这些展品包括50件雕塑作品和100多件绘画作品,贯穿了托尼·克拉格整个的创作历程。克拉格认为：“现在最有力的艺术就是创造全新的形态。”他做到了,并且还会一直做下去。     

A π-extended tetrathiafulvene derivative: Synthesis and photoluminescence properties

Solid-state emissive organic materials have received increasing attention due to their prospective applications in large-area. Here, a novel π-extended tetrathiafulvene derivative DPD with donor-π-donor structure has been newly developed to produce the prominent characteristic of aggregation-induced enhanced emission (AIEE) that exhibits higher fluorescence quantum efficiency in solid film compare to its solutions. The AIEE mechanism of DPD was studied in detail through photophysical investigations and can be dominant attributed to the formed excimer state of DPD and J-aggregates in solid state.