含硫氰酸盐、硫化物固体废物中总氰化合物测定方法

实验建立了含硫氰酸盐、硫化物固体废物中总氰化合物的测定方法,采用硝酸银滴定法、异烟酸-吡唑啉酮分光光度法分别测定总氰化合物含量高、低的样品。通过条件实验优化了前处理方式、称样量和干扰去除方法。该方法测定结果的相对标准偏差为0.43%～1.33%,加入标准物质回收率为91.5%～101.5%,精密度和准确度良好,符合测定要求。     

氧化铝超浓相输送系统计量新装置的研究开发

本文介绍了我国首例铝电解大组氧化铝超浓相输送管路上安装电子秤进行氧化铝静态称量连续下料自动计量新方法、新装置及其使用精度的有关基本情况。     

准贝氏体铸钢正火热处理工艺的研究

研究了准贝氏体铸钢不同奥氏体温度正火对其组织与力学性能的影响 ,结果表明 ,随奥氏体化温度的提高 ,准贝氏体铸钢的强韧性改善 ,在 10 4 0℃正火 ,准贝氏体铸钢具有最佳强韧性配合。分析了高温奥氏体化正火强韧性提高的原因。     

Extraction of Metal(Ti,V,Mo)-oxyl Cations by Monoacidic Phosphates and Phosphonates

The extraction of TiO~(2+),VO~(2+),VO_2~+ and MoO_2~(2+)by HDEHP,HEHEHP and HDTMPP was studiedrespectively.The orders of extraction ability for the three extractant systems are as follows:for TiO~(2+),VO~(2+):HDEHP>HEHEHP>HDTMPP;for VO_2~+, MoO_2~(2+):HDEHP< HEHEHP< HDTMPP.The experimental results were discussed from the point of view of extractant structures.     

半导体硫化银纳米管的制备与光学性能

在以Triton X-100为表面活性剂形成的反相胶束体系中,成功地制备了半导体硫化银纳米管,管径88 nm～120nm、长度大于2.6 μm.X射线衍射测定表明,产物为纯单斜结构.紫外-可见光谱在275 nm处发现新的吸收峰,最大发射波长与体相材料相比,蓝移了38 nm.     

EAF-CSP流程铌微合金化管线钢的连铸工艺

基于珠钢采用铌微合金化技术成功地开发了管线钢X52和X56的事实,结合CSP薄板坯连铸工艺特点,探索出一套适合含铌钢薄板坯连铸的浇注温度制度、结晶器保护渣、连铸拉速和结晶器热流密度匹配及二次冷却曲线等工艺控制技术.     

9SiCr钢中的筐篮编结状马氏体及其性能

将9SiCr钢的粒状原始组织改变为片状,再经830℃淬火后,其马氏体形态为筐篮编结状。而传统工艺所获得的马氏体形态为针状.这种筐篮编结状马氏体是9SiCr钢中一种崭新的组织形态,其精细结构为平行成束的板条。亚结构为高密度缠结位错.它有良好的综合机械性能,强韧性高,耐磨性高。     

类球形低硫磷酸铁的制备技术研究

磷酸铁（FePO₄）是锂电池正极材料磷酸铁锂（LiFePO₄）的核心前驱体,FePO₄形貌及硫含量对合成的LiFePO₄材料性能有重要影响。为得到类球形低硫FePO₄产品,在传统液相沉淀法技术基础上做了改进优化,添加十六烷基三甲基溴化铵（CTAB）作为形貌助剂提高产品球形度,添加氨水作为配体形成磷酸铁铵配合物改善结晶过程,降低产品硫含量。结果表明：所制备的FePO₄产品硫质量分数低,达到2.6×10 ^-5,形貌为均一的微米类球形颗粒,D₅₀=11.4 μm,振实密度达到1.22 g/cm ³,有望成为制备高压实密度LiFePO₄材料的核心前驱体。     

Preparation of ketoprofen‐loaded high‐molecular‐weight poly(vinyl alcohol) gels

High‐molecular‐weight atactic poly(vinyl alcohol) (a‐PVA) gels loaded with (R,S)‐2‐(3‐benzoylphenyl)propionic acid (ketoprofen) were prepared from 5, 6, 7, and 8 g/dL solutions of a‐PVA with a number‐average degree of polymerization of 4000 in an ethylene glycol/water mixture with an aging method to identify the effect of the initial polymer concentration on the swelling behavior, morphology, and thermal properties of a‐PVA gels. Then, the release behavior of ketoprofen from a‐PVA gels was investigated. As the polymer concentration decreased, the ability for network formation decreased, and the degree of swelling of the a‐PVA gels increased. In addition, the enthalpy increased with an increase in the a‐PVA concentration, but the melting temperatures of the gels prepared at different initial polymer concentrations were the same; this indicated that tighter gel networks would be formed by a higher polymer chain density. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

Unusual kinetic inhibitor effects on gas hydrate formation

Gas hydrate formation experiments were conducted with a methane-ethane mixture at 273.7 or 273.9 K and 5100 kPa and using water droplets or water contained in cylindrical glass columns. The effect of kinetic inhibitors and the water/solid interface on the induction time for hydrate crystallization and on the hydrate growth and decomposition characteristics was studied. It was found that inhibitors GHI 101 and Luvicap EG delayed the onset of hydrate nucleation. While this inhibition effects has been reported previously some unusual behaviour was observed and reported for the first time. In particular, the water droplet containing GHI 101 or Luvicap EG was found to collapse prior to nucleation and spread out on the Teflon surface. Subsequently, hydrate was formed as a layer on the surface. Catastrophic growth and spreading of the hydrate crystals was also observed during hydrate formation in the glass columns in the presence of the kinetic inhibitor. Finally, when polyethylene oxide (PEO) was added into the kinetic inhibitor solution the memory effect on the induction time decreased dramatically.