Sub-nanomolar sensing of ionic mercury with polymeric electrospun nanofibers

Ethyl cellulose (EC) based electrospun nanofibers were exploited for sub-nanomolar level optical chemical sensing of ionic mercury. An azomethine ionophore was used as Hg (I) and Hg (II) sensing material. Ethyl cellulose nanofibers with varying amounts of the ionic liquid; 1-ethyl-3-methylimidazolium tetrafluoroborate (EMIMBF₄) were prepared and characterized. The nanofibers were fabricated by electrospinning technique. The offered chemosensor allow determination of mercury ions in a large linear working range between 1.0 × 10⁻¹⁰ and 1.0 × 10⁻⁴ mol L⁻¹. Limit of detection was found to be 0.07 nM which makes this technique alternative to cold-vapor atomic absorption spectrometry (CV-AAS), flame emission methods and to inductively coupled plasma-mass spectrometry (ICP-MS).     

Double Threshold Energy Based Spectrum Sensing with Copulas

Wireless Personal Communications - As it is known, Energy based detection is widely used in Cognitive Radio and radar systems. In order to reduce the disruptive effects of wireless channels, Energy...     

Landfill Settlement with Decomposition and Gas Generation

A one-dimensional multiphase numerical model is developed to simulate the vertical settlement involving liquid and gas flows in a deformable (settling) municipal solid waste (MSW) landfill. MSW is represented by a chemical composition, and a global stoichiometric reaction is used to estimate the maximum yield of gas generation. Following the general assumption accepted in the literature, the gas generated by waste decomposition is assumed to comprise of methane (CH4) and carbon dioxide (CO2). The gas generation rate follows an exponentially decaying function of time. The gas generation model developed based on a first-order kinetic single-bioreactor approach includes the governing equations of gas migration, liquid flow, and landfill deformation. The Galerkin finite element method is used to solve the resulting equations. The model developed can be used to estimate the transient and ultimate settlements due to waste decomposition and gas generation in MSW landfills. The proposed model can estimate the waste porosity, gas pressure, liquid pressure, gas saturation, liquid saturation, and stress distributions in settling landfills. The results obtained for a deformable landfill are compared with a landfill having a rigid solid skeleton. Due to settlement, the depth of waste is 27% smaller in deformable landfills than that of the rigid ones.     

Flow field and heat transfer characteristics in an oblique slot jet impinging on a flat plate

An experimental study was performed to determine the effects of inclination of an impinging two dimensional slot jet on the heat transfer from a flat plate. Local Nusselt numbers and surface pressure distributions were determined depending on inclination angle, jet-to-plate spacing and Reynolds number. The results showed that the location of maximum heat transfer was mainly due to the angle of inclination. As the inclination angle increases, the location of the maximum heat transfer shifts towards the uphill side of the plate and the value of the maximum Nusselt number gradually increases at lower jet-to-plate spacings.     

Effect of rock properties on the Los Angeles abrasion and impact test characteristics of the aggregates

Aggregate is the most fundamental and widely used component of construction. It is used as an unbound material which constitutes about 100% of the volume of base courses, 95 to 93% of the volume of asphalt and about 85 to 75% of the volume of Portland cement concrete. Aggregate is exposed to a number of physical and chemically degrading forces during processing, transporting, and construction. As the main load carrying component of unbound and bituminous and Portland cement concretes, the aggregate must be clean, hard, sound, durable, resistant to abrasion, uniform in quality and free of any detrimental quantities of soft, friable, thin, elongated or laminated pieces, disintegrated material, alkali or other deleterious substance. For assesing the abrasion resistance of aggregates, the most common method is the Los Angeles abrasion and impact test (LAAI) which determines the relative competence or resistance to abrasion of the aggregates.In this study, four limestones, four travertines, three crystalline marbles and one andesite were tested to evaluate the correlations between the LAAI values and the physical properties covering bulk density, Schmidt hardness, shore hardness, P-wave velocity and mechanical properties such as uniaxial compressive strength, point load index, and indirect tensile strength of rocks. Since these properties are of great importance as a source of aggregates, tests on the rock can give an indication of the strength of the aggregates.The above rock properties were determined through standard testing methods in order to investigate the correlation between LAAI and each rock property by using regression analysis. A simple equation predicting the LAAI value based on each rock property was suggested. From the statistical tests, rock properties were found to be significant in estimating the LAAI values of rocks.     

Ion imprinted beads embedded cryogels for in vitro removal of iron from β-thalassemic human plasma

Molecular recognition based Fe³⁺ imprinted poly(GMA-MAC) (MIP) beads embedded PHEMA composite cryogel was prepared for selective removal of Fe³⁺ ions from β-thalassemia patient plasma. The precomplexation was achieved by the coordination of Fe³⁺ ions with N-methacryloyl-(L )-cysteine methyl ester (MAC-Fe³⁺). MIP beads were prepared by dispersion polymerization in the presence of MAC-Fe³⁺ complex and glycidyl methacrylate (GMA) monomer. Then the MIP beads were embedded into poly(hydroxyethyl methacrylate) (PHEMA) cryogel. The specific surface area and the swelling degree of the PHEMA-MIP composite cryogel were found to be 76.8 m²/g and 7.7 g H₂O/g cryogel, respectively. The maximum adsorption amount of Fe³⁺ ions was 2.23 mg/g. The relative selectivity of PHEMA-MIP composite cryogel towards the Fe³⁺ ions was 135.0, 61.4, and 57.0 times greater than that of the PHEMA-NIP cryogel as compared with the Ni²⁺, Zn²⁺, and Fe²⁺ ions, respectively. PHEMA-MIP composite cryogel was recovered and reused many times without any significant decrease in its adsorption capacity. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012     

Immobilization of glucoamylase on the plain and on the spacer arm‐attached poly(HEMA‐EGDMA) microspheres

Immobilization glucoamylase onto plain and a six‐carbon spacer arm (i.e., hexamethylene diamine, HMDA) attached poly(2‐hydroxyethylmethacrylate‐ethyleneglycol dimethacrylate) [poly(HEMA‐EGDMA] microspheres was studied. The microspheres were prepared by suspension polymerization and the spacer arm was attached covalently by the reaction of carbonyl groups of poly(HEMA‐EGDMA). Glucoamylase was then covalently immobilized either on the plain of microspheres via CNBr activation or on the spacer arm‐attached microspheres via CNBr activation and/or using carbodiimide (CDI) as a coupling agent. Incorporation of the spacer arm resulted an increase in the apparent activity of the immobilized enzyme with respect to enzyme immobilized on the plain of the microspheres. The activity yield of the immobilized glucoamylase on the spacer arm‐attached poly(HEMA‐EGDMA) microspheres was 63% for CDI coupling and 82% for CNBr coupling. This was 44% for the enzyme, which was immobilized on the plain of the unmodified poly(HEMA‐EGDMA) microspheres via CNBr coupling. The K_m values for the immobilized glucoamylase preparations (on the spacer arm‐attached microspheres) via CDI coupling 0.9% dextrin (w/v) and CNBr coupling 0.6% dextrin (w/v) were higher than that of the free enzyme 0.2% dextrin (w/v).The temperature profiles were broader for both immobilized preparations than that of the free enzyme. The operational inactivation rate constants (k_iop) of immobilized enzymes were found to be 1.42 × 10^?5 min^?1 for CNBr coupled and 3.23 × 10^?5 min^?1 for CDI coupled glucoamylase. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 81: 2702–2710, 2001     

Characterization of Turkish Olive Oils by Triacylglycerol Structures and Sterol Profiles

A characterization study of Turkish monovarietal olive oils using chemical variables such as fatty acid, sn‐2 fatty acid, triacylglycerol, and sterol composition is presented. A total of 101 samples of Olea europaea L. fruits from 18 cultivars were collected for two crop years from west, south, and southeast regions of Turkey. Olives were processed to oil and olive oil samples were evaluated for their triacylglycerol structures and sterol composition. Oleic acid content ranged from 60.15 to 80.46 % of total fatty acids and represented 70.90–89.02 % of sn‐2 position triacylglycerols. Major triglycerides of oil samples were triolein, palmitodiolein, dioleolinolein, palmitooleolinolein, dipalmitoolein, and stearodiolein. Triolein values were between 24.72 and 48.64 % and compatible with the fatty acid composition. Total sterol content varied from 1,145.32 to 2,211.77 mg/kg and Edremit yagl?k stood out because of its high sterol content. A one‐way analysis of variance revealed significant differences for variables among cultivars. Principle component analysis enabled the classification of common varieties on the basis of analytical data. Sterol composition achieved more relevant discrimination than fatty acid and triglyceride composition. Classification according to geographical origin was performed by discriminant analysis.