Effect of crystal structure on the luminescence properties of CaF2-PrF3 solid solutions

The structure and luminescent properties of lightly doped CaF₂:Pr crystals and Ca_0.65Pr_0.35F_2.35 solid solution have been studied. The results demonstrate that the evolution of the emission spectra of the crystals with increasing PrF₃ concentration can be understood in terms of the structural changes in the fluorite solid solutions, namely, the formation of defect clusters.     

CD317 功能研究进展

CD317 (Tetherin,BST-2或HM1.24)于1994年被发现并命名,是终末分化B细胞的特异性表面标志.2008年首次被鉴定为干扰素诱导型宿主抗病毒因子,此后越来越多的科学家加入到该领域的探索中.经过近十年的研究,目前已经阐述了CD317结构、抗病毒及免疫特性等问题,也陆续发现了一些诸如参与肿瘤进展、束缚外泌体释放等新功能,研究热度不减当年.因此,文章对近几年CD317功能的研究进展进行一个系统的总结,以期为病毒感染、肿瘤发病以及治疗等方面的理论进步和技术发展提供新的思路.     

Fast and scalable rendezvousing

In an asymmetric rendezvous system, such as an unfair synchronous queue or an elimination array, threads of two types, consumers and producers, show up and are matched each with a unique thread of the other type. Here we present new highly scalable, high throughput asymmetric rendezvous systems that outperform prior synchronous queue and elimination array implementations under both symmetric and asymmetric workloads (more operations of one type than the other). Based on this rendezvous system, we also construct a highly scalable and competitive stack implementation.     

Utility Dependence in Correct and Fair Rational Secret?Sharing

The problem of carrying out cryptographic computations when the participating parties are rational in a game-theoretic sense has recently gained much attention. One problem that has been studied considerably is that of rational secret sharing. In this setting, the aim is to construct a mechanism (protocol) so that parties behaving rationally have incentive to cooperate and provide their shares in the reconstruction phase, even if each party prefers to be the only one to learn the secret.     

Simultaneous injection locking of couples of high-power broad-area lasers driven by a common current source

We experimentally demonstrate the simultaneous injection locking of pairs of high-power broad-area laser diodes in a 19-laser array driven by a common current source. Each pair is injection locked by use of a single-mode low-power semiconductor laser. The frequency and phase locking are verified bythe optical spectrum and the interference pattern between the injection-locked lasers. The influence of frequency detuning on the (simultaneous) injection behavior has been experimentally clarified. We validate a necessary condition for the injection locking of a broad-area laser array.     

Mixed group ranks: preference and confidence in classifier combination

Classifier combination holds the potential of improving performance by combining the results of multiple classifiers. For domains with very large numbers of classes, such as biometrics, we present an axiomatic framework of desirable mathematical properties for combination functions of rank-based classifiers. This framework represents a continuum of combination rules, including the Borda Count, Logistic Regression, and Highest Rank combination methods as extreme cases. Intuitively, this framework captures how the two complementary concepts of general preference for specific classifiers and the confidence it has in any specific result (as indicated by ranks) can be balanced while maintaining consistent rank interpretation. Mixed Group Ranks (MGR) is a new combination function that balances preference and confidence by generalizing these other functions. We demonstrate that MGR is an effective combination approach by performing multiple experiments on data sets with large numbers of classes and classifiers from the FERET face recognition study.     

Fluorescence correlation spectroscopy at 100 nM concentrations using near-field scanning optical microscopic (NSOM) geometries and highly diffracting force sensing fiber probes

A tapered cantilevered optical fiber probe is introduced for fluorescence correlation spectroscopy (FCS). The probe has an aperture that is coated with metal and its dimension can be very well defined. Its design is based on cantilevered near-field optical fiber probes that allow for on-line atomic force feedback. This permits unprecedented stability in FCS measurements. Even such probes that have large diameters are below the cutoff wavelength of light propagation in optical fibers. Such large diameter probes produce bright spots of light that are highly diffracting. Therefore, only the fluence of light very close to the surface of the glass probe aperture is sufficient to exhibit a high probability of fluorescence excitation. From the results presented in this paper the z extent of such probes seems comparable to what can be obtained from prism-based evanescent wave methods, but with much more flexibility and including force sensing capability. In agreement with theoretical results on prism evanescent field-based excitation, it is shown that even with large xy dimensions for the fiber probes in this paper, fluorescence correlation spectra from 100 nM fluorophore concentrations can be recorded. This is 10 times larger than the concentrations generally required for conventional confocal FCS. The results suggest that such an approach has considerable potential for applications of FCS in membrane, near-membrane, solution, and even within-cell environments. The latter is achieved through atomic force feedback controlled penetration of tapered cantilevered metal-coated glass fibers into cells, and this is also reported in this paper.     

Synthesis and Degradation of Hexamethylene Triperoxide Diamine (HMTD)

The synthesis and decomposition of hexamethylene triperoxide diamine (HMTD) were studied. Mechanisms were proposed based on isotopic labeling and mass spectral interpretation of both condensed phase products and head‐space products. Formation of HMTD from hexamine appeared to proceed from dissociated hexamine as evident from scrambling of the ¹⁵N label when synthesis was carried out with equal molar labeled/unlabeled hexamine. Decomposition of HMTD was considered with additives and in the presence and absence of moisture. In addition to mass spectral interpretation, density functional theory (DFT) was used to calculate energy differences of transition states and the entropies of intermediates along different possible decomposition pathways. HMTD is destabilized by water and citric acid making purification following initial synthesis essential in order to avoid unanticipated violent reaction.     

The structure and electro‐mechanical properties of novel hybrid CNT/PANI nanocomposites

Electrically conductive elastomeric nanocomposites containing carbon nanotubes (CNT) and polyaniline (PANI) are reported in the present investigation. The synthesis procedure included an in situ inverse emulsion polymerization of aniline doped with dodecylbenzene sulfonic acid (DBSA) in the presence of CNT and dissolved styrene‐isoprene‐styrene (SIS) block copolymer. The PANI synthesis step was carried out by applying ultrasonic energy. The dispersions obtained were processed by two methods: a recently developed precipitation‐filtration procedure, and a conventional drop‐cast procedure. The techniques developed resulted in homogeneous exfoliated PANI coated nanotubes within the elastomeric matrix. The presence of CNT/PANI in the SIS elastomeric matrix affects thermal, mechanical, and electrical properties of the nanocomposites. The formation of continuous three‐dimensional CNT/PANI networks prepared via the precipitation‐filtration method enhances the nanocomposite properties. Contrarily, the intermittent three‐dimensional network prepared by conventional drop‐cast method leads to inferior properties. Nanocomposites produced by both techniques are observed by HRSEM. The two processing techniques result in different structures, which affect the physical properties of the materials produced. A relatively low percolation threshold for both methods was determined. The Young's modulus of the SIS/CNT/PANI significantly increased in the presence of CNT. The precipitation‐filtration technique yields an improved nanocomposite product compared to the drop‐cast route. POLYM. COMPOS., 35:788–794, 2014. © 2013 Society of Plastics Engineers