Onset of buoyancy-driven convection in melting from below

When a horizontal homogeneous solid is melted from below, convection can be induced in a thermally unstable melt layer. In this study the onset of buoyancy-driven convection during time-dependent melting is investigated by using similarly transformed disturbance equations. The critical Rayleigh numbers based on the melt-layer thickness are found numerically for various conditions. For small superheats, the present predictions approach the well known results of classical Rayleigh-Bénard problems, that is, critical Rayleigh numbers are located between 1,296 and 1,708, regardless of the Prandtl number. However, for high superheats the critical Rayleigh number increases with an increase in phase change rate but with decrease in Prandtl number.     

新疆油田微生物开采稠油技术研究及矿场试验

通过室内筛选复壮,选育出对克拉玛依稠油具有显著降粘作用的微生物菌种.室内降粘实验结果表明,菌种对稠油的降粘率可达70%,同时菌种可以改善稠油的流体性质.原油族组分分析结果表明,菌种能够降解稠油中的非烃和长链饱和烃.首次在克拉玛依油田进行了6口井的微生物吞吐开采稠油矿场试验,累计增油865t.     

Characteristics of Milk Powders Produced by Spray Freeze Drying

Skim and whole milk powders were manufactured at lab scale by spray freeze drying (SFD), using liquid nitrogen as the cryogen. The polydispersity of droplet/particle sizes was limited using an encapsulator nozzle to atomize the feed. Particle morphology was examined using a scanning electron microscope. Samples were compared with equivalent spray-dried powders in tests of wettability and dissolution in water. The spray freeze-dried powders were found to be highly porous, with a uniform structure of pores throughout the entire particles. When tested in water, SFD skim milk powders wetted roughly three times as fast as industrially spray-dried agglomerated skim milk powders and were observed to dissolve rapidly by breaking down into smaller particles.     

Ionothermal synthesis of a three-dimensional zinc phosphate with DFT topology using unstable deep-eutectic solvent as template-delivery agent

A three-dimensional zinc phosphate compound with DFT topology, designated as ZnPO₄-EU1, has been synthesized by an ionothermal approach from the system HF-ZnO–P₂O₅-choline chloride-imidazolidone. Ethylenediamine, derived from decomposition of the imidazolidone component of the deep-eutectic solvent (DES) itself, is delivered to the synthesis and serves as an appropriate template for ZnPO₄-EU1. Experiments in which the synthesis conditions were varied showed that ZnPO₄-EU1 may be prepared over a wide molar ratio of P/Zn = 0.55–13.0. Powder X-ray diffraction patterns have been obtained at intervals to track the crystallization process of this material. The experimental data show that Zn₃(PO₄)₂ · 4H₂O (a dense phase) was first isolated from the DES after reaction for 1 h. Subsequently, the pure phase of ZnPO₄-EU1 was obtained with increasing crystallization time from 12 h to 72 h. The experimental results show that the nucleation and crystallization take place with relatively low levels of solvent degradation, demonstrating that zinc phosphate with a three-dimensional framework can be synthesized by in situ generation of an appropriate template using an unstable DES at high temperatures (150–200 °C).     

C语言学习方法与实践的探讨

针对C语言程序设计课程本身的特点，分析学习过程中存在的问题，强调实践的必要性。结合一些学校课程改革和实践的经验．提出面向应用的，科学的学习内容、方法和模式。同时提高学习者的专业动手能力。     

多测井曲线的综合处理合成

测井曲线是地质分层的基础，但在利用单一测井曲线解决复杂地质问题时也存在多解性和局限性。为克服多解性，人们采用多种测井曲线进行地质分层，提高了分层的精度。本文在此基础上提出把多条曲线分别赋予不同的加权因子，然后进行归一化处理，形成一条标准综合参数测井曲线。此综合参数曲线突出了所选的多条测井曲线的公共信息，减少或削弱了单一测井曲线中的偶然误差，提高了综合后测井资料的可信度。该方法可应用于地质分层、岩性分析、含油气预测等诸多领域。应用时要注意，并非所选择的测井曲线种类越多越好，而是要选择那些最能反映地层单元特征信息的测井曲线。     

重油催化裂化装置的环保对策

对重油催化裂化过程中的环境影响因素、硫分布状况及硫平衡等进行了分析，指出了重油催化裂化过程中的环境污染问题；从对装置污染源的分析出发，提出了相关的治理措施。     

裂齿矩形翅片板翅式换热器优化设计的分析

对裂齿矩形翅片板翅式换热器中的裂齿矩形翅片的传热效率作了分析,并以单位质量材耗的换热能力最大为目标函数,分析研究了在不同雷诺数(Re)的操作条件下裂齿矩形翅片间角度、翅片厚、长度、宽度及极厚之间的关系。结果表明:在气体换热的场合下,当Re在某一范围时翅片可有效地起到强化传热的作用。当板厚为5mm,翅片厚为3mm,翅片间夹角为45°～70°,Re为2×10~3～8×10~3,最佳翅片纵向间距与翅片长度和翅片厚度乘积的平方根的比为1.5～2.5,最佳翅片尺寸系数为3～5时,传热强化效果较好。     

Preparation of CeO2-ZrO2 mixed oxide with high surface area and high thermal stability

Ceria-zirconia solid particles have been recognized as a key material of the automotive exhaust catalysts since they can release and uptake oxygen owing to the rapid reversible oxidation states of cerium between Ce³⁺ and Ce⁴⁺. Several methods have recently been described to prepare the CeO₂-ZrO₂ solid particles used in the catalysts. In this paper, a new coprecipitation method is used to prepare the CeO₂-ZrO₂ solid particles. The Ce-Zr alcogel is dried and calcined in flowing N₂ not in flowing air under atmospheric pressure. The results show that the ceria-zirconia sample calcined at 650 °C has high surface area over 90 m²g⁻¹, which drops to 40 m²g⁻¹ following treatment at 900°C.