Porous Glass-Ceramics with a Skeleton of the Fast-Lithium-Conducting Crystal Li1+xTi2−xAlx(PO4)3

Porous glass-ceramics with a skeleton of the fast-lithium-conducting crystal Li_{1+ x} Ti_{2− x} Al _x (PO₄)₃ (where x = 0.3–0.5) were prepared by crystallization of glasses in the Li₂O─CaO─TiO₂─Al₂O₃–P₂O₅ system and subsequent acid leaching of the resulting dense glass-ceramics composed of the interlocking of Li_{1+ x} Ti_{2− x} Al _x (PO₄)₃ and β-Ca₃(PO₄)₂ phases. The median pore diameter and surface area of the resulting porous Li_{1+ x} Ti_{2− x} Al _x (PO₄)₃ glass-ceramics were approximately 0.2 μm and 50 m²/g, respectively. The electrical conductivity of the porous glass-ceramics after heating in LiNO₃ aqueous solution was 8 × 10⁻⁵ S/cm at 300 K or 2 × 10⁻² S/cm at 600 K.     

Formation of Sm2+ lons in Sol-Gel-Derived Glasses of the System Na2 O-Al2O3-SiO2

Samarium ions (Sm²⁺) incorporated into aluminosilicate glasses by a sol-gel process showed persistent spectral hole burning at room temperature. Gels of the system Na₂O-Al₂O₃SiO₂ synthesized by the hydrolysis of Si(OC₂H₅)₄, Al(OC₄H₉)₃, CH₃ COONa, and SmCl₃·6H₂O were heated in air at 500°C, then reacted with H₂ gas to form Sm²⁺ ions. Whereas Al³⁺ ions effectively dispersed the Sm³⁺ ions in the glass structure, Na⁺ ions were not effective. The Al₂O₃-SiO₂ glasses proved appropriate for reacting the Sm³⁺ ions with H₂ gas and exhibited the intense photoluminescence of Sm²⁺ ions. The reaction of Sm³⁺ ions with H₂ in the Al₂O₂-SiO₂ glasses was determined by first-order kinetics, and the activation energy equaled 95 kJ/mol. At 800°C, the maximum photoluminescence of the Sm²⁺ ions was achieved within 20 min.     

Creep fracture modeling by use of continuum damage variable based on Voronoi simulation of grain boundary cavity

A new approach to creep cavitation damage is developed by combining the basic features of continuum damage mechanics and mechanism-based cavitation models. Based on a polycrystal microstructures simulated by Voronoi tessellation, an anisotropic continuum damage variable is defined, and its evolution is given by applying the mechanism-based equations of cavity nucleation and growth to each grain boundary. Macroscopic creep deformation coupled with the damage variable is calculated by damage mechanics equations. The proposed method has been applied to investigate the damage evolution under uniaxial tension and reversed shear loading conditions.     

Efficient electrochemical decomposition of perfluorocarboxylic acids by the use of a boron-doped diamond electrode

The electrochemical decomposition of environmentally persistent perfluorooctanoic acid (PFOA) was achieved by the use of a boron-doped diamond (BDD) electrode. The PFOA decomposition follows pseudo-first-order kinetics, with an observed rate constant (k₁) of 2.4 × 10^− 2 dm³ h^− 1. Under the present reaction conditions, k₁ increased with increasing current density and saturated at values over 0.60 mA cm^− 2. Therefore, the rate-limiting step for the electrochemical decomposition of PFOA was the direct electrochemical oxidation at lower current densities. In the proposed decomposition pathway, direct electrochemical oxidation cleaves the C-C bond between the C₇F₁₅ and COOH in PFOA and generates a C₇F₁₅ radical and CO₂. The C₇F₁₅ radical forms the thermally unstable alcohol C₇F₁₅OH, which undergoes F⁻ elimination to form C₆F₁₃COF. This acid fluoride undergoes hydrolysis to yield another F⁻ and the perfluorocarboxylic acid with one less CF₂ unit, C₆F₁₃COOH. By repeating these processes, finally, PFOA was able to be totally mineralized to CO₂ and F⁻. Moreover, whereas the BDD surface was easily fluorinated by the electrochemical reaction with the PFOA solution, medium pressure ultraviolet (MPUV) lamp irradiation in water was able to easily remove fluorine from the fluorinated BDD surface.     

Densification and Cell Performance of Gadolinium-Doped Ceria (GDC) Electrolyte/NiO–GDC Anode Laminates

A thin film (60 μm thick) of a gadolinium-doped ceria (GDC) electrolyte was prepared by the doctor blade method. This film was laminated with freeze-dried 42 vol% NiO–58 vol% GDC mixed powder and pressed uniaxially or isostatically under a pressure of 294 MPa. This laminate was cosintered at 1100 °–1500 °C in air for 4–12 h. The laminate warped because of the difference in the shrinkage of the electrolyte and electrode during the sintering. A higher shrinkage was measured for the electrode at 1100 °–1200 °C and for the electrolyte at 1300 °–1500 °C. The increase of the thickness of anode was effective in decreasing the warp and in increasing the density of the laminated composite. The maximum electric power density with a SrRuO₃ cathode using 3 vol% H₂O-containing H₂ fuel was 100 mW/cm² at 600 °C and 380 mW/cm² at 800 °C, respectively, for the anode-supported GDC electrolyte with 30 μm thickness.     

Two types of a passive safety containment for a near future BWR with active and passive safety systems

The paper presents two types of a passive safety containment for a near future BWR. They are named Mark S and Mark X containment. One of their common merits is very low peak pressure at severe accidents without venting the containment atmosphere to the environment. The PCV pressure can be moderated within the design pressure. Another merit is the capability to submerge the PCV and the RPV above the core level. The third merit is robustness against external events such as a large commercial airplane crash. Both the containments have a passive cooling core catcher that has radial cooling channels. The Mark S containment is made of reinforced concrete and applicable to a large power BWR up to 1830 MWe. The Mark X containment has the steel secondary containment and can be cooled by natural circulation of outside air. It can accommodate a medium power BWR up to 1380 MWe. In both cases the plants have active and passive safety systems constituting in-depth hybrid safety (IDHS). The IDHS provides not only hardware diversity between active and passive safety systems but also more importantly diversity of the ultimate heat sinks between the atmosphere and the sea water. Although the plant concept discussed in the paper uses well-established technology, plant performance including economy is innovatively and evolutionally improved. Nothing is new in the hardware but everything is new in the performance.     

面素法加工自由曲面的研究与实验

精密制造中需要对淬硬材料的自由曲面进行精加工。本项目采用磨削中心GC,进行了高效自由曲面磨削加工的基础研究。本文提出了3维自由曲面可以分为9种类型的面素,并从几何角度分析了面素的定义方法。采用球头磨球形磨具进行面素法高效磨削加工时,需要对各类面素与球形磨具的作用状态进行解析。分析了由于加工条件和加工面形状变化,工件与球形磨具随之在接触点周速度、砂轮实际切削深度,以及磨削力的变化。分析模型与实验数值有很好的吻合。     

Dual-Mode Space-Temporal Simultaneous Processing Equalizer

A tapped delayed line adaptive array antenna (TDL-AAA) and a space-temporal simultaneous processing equalizer (ST-SPE) are proposed as simple space-temporal equalizers based on minimum mean square error (MMSE) criterion. The ST-SPE has a compact hardware with a small number of taps compared to that of the TDL-AAA. The ST-SPE can reduce the computational complexity of the space-temporal joint equalization and it works effectively under the minimum phase condition such as appeared at line-of-sight (LOS) propagation environments at a high antenna height base station. However the ST-SPE cannot work under a non-minimum phase condition caused under N-LOS (non-line-of-sight). On the other hand, the TDL-AAA whose reference signal is synchronized at the center tap (TDL-AAA_C) can work even in the non-minimum phase condition. In this paper, we propose a dual-mode space-temporal simultaneous processing equalizer (Dual-mode ST-SPE) which has a simple configuration and also works in non-minimum phase condition. The Dual-mode ST-SPE can reduce the computational complexity compared to the TDL-AAA_C. Yoshihiro Ichikawa received the B.E. degree in department of communication engineering, in National Defense Academy in 1995, and M.E. and D.E. degree from Ibaraki University in 2001 and 2004, respectively. He joined the Japan Air Self Defense Force in 1995. His research interests are an adaptive algorithm, an antenna design, and an adaptive array antenna. Shigeki Obote received his B.E., M.E. and D.E. degrees in electrical and electronic engineering from Tottori University, Tottori, Japan, in 1996, 1998 and 2000, respectively. Since 2000, he has been with department of media and telecommunications engineering, faculty of engineering, Ibaraki University, Ibaraki, Japan, where he is currently a associate professor. His research interests are in adaptive array antenna and wireless communications systems. Kenichi Kagoshima received the B.E., M.E. and D.E. degrees in electronics engineering from the Tokyo Institute of Technology, Tokyo, Japan, in 1969, 1971, and 1974, respectively. He joined the Nippon Telegraph and Telephone Corporation (NTT) Laboratory in 1974 and researched and developed many kinds of radio communication antennas. Since 1997, he has been a professor at Ibaraki University, Ibaraki, Japan. Dr. Kagoshima was a Secretary and Treasure, Vice Chairman, and Chairman of the IEEE AP-S Tokyo Chapter in 1992, 1993, and 1994, respectively. He was a chair of antennas and propagation professional group of IEICE in 1999 and 2000. In 1973, he received the Yonezawa Prize for Young Engineers and 1998, best paper award from IEICE, respectively.     

Metastatic Voyage of Ovarian Cancer Cells in Ascites with the Assistance of Various Cellular Components

Epithelial ovarian cancer (EOC) is the most lethal gynecologic malignancy and has a unique metastatic route using ascites, known as the transcoelomic root. However, studies on ascites and contained cellular components have not yet been sufficiently clarified. In this review, we focus on the significance of accumulating ascites, contained EOC cells in the form of spheroids, and interaction with non-malignant host cells. To become resistant against anoikis, EOC cells form spheroids in ascites, where epithelial-to-mesenchymal transition stimulated by transforming growth factor-β can be a key pathway. As spheroids form, EOC cells are also gaining the ability to attach and invade the peritoneum to induce intraperitoneal metastasis, as well as resistance to conventional chemotherapy. Recently, accumulating evidence suggests that EOC spheroids in ascites are composed of not only cancer cells, but also non-malignant cells existing with higher abundance than EOC cells in ascites, including macrophages, mesothelial cells, and lymphocytes. Moreover, hetero-cellular spheroids are demonstrated to form more aggregated spheroids and have higher adhesion ability for the mesothelial layer. To improve the poor prognosis, we need to elucidate the mechanisms of spheroid formation and interactions with non-malignant cells in ascites that are a unique tumor microenvironment for EOC.     

波形碳纳米管增强复合材料的有效刚度和局部应力的宏微观均质化数值模拟

采用分子动力学方法简化的碳纳米管等效纤维模型,利用具有精确周期性边界条件的均质化理论和宏微观均质化法分析正弦波形非连续碳纳米管的有效刚度和局部应力分布规律.结果表明,纳米增强复合材料的有效刚度和局部应力对碳纳米管的波形非常敏感,碳纳米管稍有弯曲就会导致复合材料有效刚度降低和应力传递能力的下降,为揭示复合材料中碳纳米管的增强机制和改善增强效果提供理论依据.