Reversible crosslinking in cellulose. I. Determination of mercaptan and disulfide in modified cotton

Mercaptan and disulfide contents of modified cotton fabrics could be determined by application of Leach's polarographic method for wool, with minor modification. It was found that mercaptocellulose prepared by the reaction of tosyl cellulose and potassium thiolacetate followed by alkaline hydrolysis contained considerable amounts of disulfided in addition to mercaptain. Iodometric titration of mercaptocellulose gave a higher value of mercaptan than that obtained by the polarographic method. The mercaptan and disulfide contents and methylene blue uptake of the iodine-treated samples indicate that some of the mercaptan groups further undergo oxidation to acidic groups as a result of the iodine treatment. The spatial effect in the oxidation of mercapto groups in modified cotton is briefly discussed.     

Computation of thermodynamic properties of liquid ferrous alloys from structural measurements

Relation between X-ray scattering intensities, mean square thermal fluctuations and thermodynamic properties. High temperature X-ray diffraction study of liquid Fe-Ni and Fe-Si alloys using reflection and transmission geometries. Calculation of the structure factor as a function of wave vector. Extrapolation to zero wave vector. Calculation of the concentration-concentration correlation function defined by A. B. Bhatia and D. E. Thorton. Computation of thermodynamic quantities of mixing ΔG, ΔH and ΔS for the binary alloys. Comparison with direct thermodynamic measurements reported in the literature.     

Superconducting to normal transition of type-II Ta by a rectangular current pulse

The superconducting to normal transition by a rectangular pulse current in type-II Ta has been investigated. The potential drop along the specimen is observed as a function of time. The voltage pattern and the magnitude of the potential drop are obtained as functions of current amplitude, temperature, externally applied magnetic field, the angle between magnetic field and specimen axis, and values. The transition mechanisms are discussed. It is also shown in this experiment that the flux flow or flux creep and flux jump occur. A support to the paramagnetic current flow in the presence of longitudinal magnetic field is given.     

Syntheses and properties of B-C-N and BN nanostructures

The current status of research on boron-carbon-nitrogen (B-C-N) and boron nitride (BN) nanotubes is presented. The latest achievements in syntheses, analyses and property measurements of these nanoscale tubular architectures are reviewed. The characteristic features of B-C-N and BN nanotubes, compared with conventional C nanotubes, are paid special attention. In particular, the latest breakthroughs in the chemical vapour deposition synthesis of BN nanotubes and an insight into their unique structures are highlighted. A wide range of potential applications is also envisaged, based on the recent progress, which includes pioneering results in BN nanocable fabrication, gas adsorption, electron transport and field emission measurements.     

Hiding an image with a light-scattering medium and use of a contrast-discrimination method for readout

Hiding image data with a material such as a light-scattering medium is useful as an initial stage of data protection, because the hidden image can be detected only by observation with a specific technique. A light-scattering medium is used to hide the image data, and a low-temporal-coherence interferometer performs the readout processing. A new readout method for detecting pixel values of the image is proposed to overcome spatial variation of the light intensity and distortion of the interference fringes. The introduction of spatial coding further improves the performance by overcoming spatial variations of the light-scattering medium and variations in the reflectance of given pixels.     

Polymer film-type channel electron multipliers: Their characteristics and comparison with bulk-type flexible multipliers

Polymer film-type channel electron multipliers (CEMs) were developed and their characteristics investigated in comparison with bulk-type flexible CEM. As film-type CEMs, a paint-coating-type CEM and a solvent-etching-type CEM were fabricated. The paint-coating-type CEM is made by coating a “paint” which is prepared by dissolving in a solvent an electronically conductive polymeric composition having a high secondary electron emission yield. Up to the present study the mean gain of the film-type CEM, in spite of the lower resistivity of the dynode, seems to be slightly more dependent on the count rate than that of the bulk-type CEM made of the same material. However, the convenience of fabricating the dynode film by coating the dynode-forming paint on the internal surface of any shaped tube or a flexible polymer tube would overcome the slight disadvantage mentioned above.     

Portable sick house syndrome gas monitoring system based on novel colorimetric reagents for the highly selective and sensitive detection of formaldehyde

Formaldehyde (HCHO) emitted from the furniture and the walls in the rooms injures the eyes, nose, and respiratory organs and causes allergies, which is called sick house syndrome. We designed and synthesized novel colorimetric HCHO-sensing molecules (KD-XA01 and KD-XA02) which possess an enaminone structure and developed a hand-held instrument to monitor indoor HCHO gas with the use of KD-XA01. These sensing molecules produced speedy color changes from colorless to yellow under mild conditions, which was caused by the fact that the enaminone structure in the reagent reacts with HCHO to give a lutidine derivative. This reaction took place not only in the solution phase but also in the solid phase (surface of the cellulose paper). To take advantage of this phenomena, a handy and rapid monitoring system has been developed for detecting indoor HCHO gas using a highly sensitive and selective detection tablet constructed from the porous cellulose paper that contains silica gel as an adsorbent, KD-XA01, and phosphoric acid under optimum conditions. This instrument detected the surface color change of the tablet from white to yellow, which was monitored as a function of the intensity of the reflected light illuminated by an LED (475 nm). The response was proportional to the HCHO concentration at a constant sampling time and flow rate; 0.05 ppm HCHO, which is under the standard value set by the World Health Organization, was able to be detected in 5 min. The detection limit was 0.005 ppm. This monitoring system was not interfered by carbonyl compounds such as acetaldehyde and acetone, alcohols, hydrocarbons, and typical gases such as carbon monoxide, carbon dioxide, nitrogen dioxide, etc., which contributes to the measurement of correct HCHO concentrations. It was possible to monitor the HCHO gas in the room of a new apartment and school using this instrument; the response values were in good agreement with those obtained by the standard DNPH method. This highly sensitive, selective, and handy HCHO gas monitor is widely applicable and convenient for users who are not specialists in this field.