Environmental effect on mechanical properties of recrystallized L12-type Ni3(Si,Ti) intermetallics

The environmental effect on the mechanical properties of boron-doped and undoped Ni₃(Si, Ti) polycrystals was investigated by tensile testing in air from room temperature to 1073 K, and the results were compared with those obtained previously by tensile testing in vacuum. The environmental effect for the Ni₃(Si, Ti) alloys was significant at ambient temperatures whereas that for the boron-doped Ni₃(Si, Ti) alloys was considerable at elevated temperatures. When these samples at associated temperatures were tensile tested in air and also at low strain rate, intergranular fracture was dominant. It was suggested that the environmental embrittlements at low and high temperatures were due to hydrogen and oxygen absorbed from the air, respectively, and were caused by the weakening of the grain-boundary cohesion. It was proposed that boron competing with hydrogen, for site occupation or for its effectiveness at grain boundaries, has the effect of suppressing hydrogen embrittlement, whereas it was suggested that the low-melting phases, consisting of boron and oxygen (and/or constituent atoms), may be responsible for the ductility loss in the boron-doped Ni₃(Si, Ti) alloys.     

Self oscillation phenomena of turbulent jets in a channel

A new method based on the Coanda effect for self oscillation of a circular jet bounded by rectangular enclosure is suggested. The experiments in both air and water reveal regions of stable oscillation wherein relationships are obtained between the Strouhal number and the shape factor of the channel. This oscillation method can also be used to mix different liquids in a vessel. For such applications, an improvement of mixing by oscillation is shown by means of a residual concentration diagram for a salt solution.     

Effects of viscosities on the transient current in homeotropic nematic liquid crystal cells

Effects of the Leslie viscosity coefficients α_i (i = 1, 2, …, 5) of nematic liquid crystals (NLCs) with negative dielectric anisotropy (Δε < 0) on the electric-field-induced director reorientation in homeotropic NLC cells have been studied from the analysis of the transient current induced by step voltage application. The transient current in a homeotropic NLC cell with Δε < 0 was well reproduced by computer simulation, based on the theory of NLCs in which the flow effects and the free-slip boundary condition are taken into account. It is found that the response time of vertical alignment NLC displays is dominantly governed by α₂ and α₄ + α₅ of NLCs with Δε < 0.     

PROGRESSIVE HYDROTREATMENT OF HOKKAIDO COALS (JAPAN)

Hokkaido coals were subjected to benzene extraction and non-catalytic hydrotreatment, alternatively, under progressive increase of temperature from 200 to 400 °C. For Taiheiyo coal the aliphatic materials in the hydrogen-rich part of the coal were converted to benzene soluble products at lower temperatures. With the increasing reaction temperature, aromaticity of the benzene solubles increased gradually. On the other hand, for Ohyubari coal, the structure of the benzene solubles were essentially the same for products obtained under all temperatures. Also, in the case of Taiheiyo coal (C : 76.9 %) the plastic state was not observed up to 400 °C, but for Ohyubari coal (C : 85.6 %) the onset of the plastic state was evident. It was assumed that there was an intimate relationship between the occurrence of plastic state and the structural uniformity of coal.     

Iodine-initiated,solid-state copolymerization of tetraoxane with 1,3-dioxolane in the presence of methylal. II. Properties of copolymer obtained by beaker-scale copolymerization

In order to elucidate the copolymerization mechanism, the properties of the copolymer obtained by the iodine-initiated copolymerization of the tetraoxane–1,3-dioxolane–methylal system have been studied using gas chromatography, microscopy, scanning electron microscopy, differential scanning calorimetry, and gel permeation chromatography. From the behavior of the thermal stability and gas chromatography of the reaction mixture, it was found that reactivity of 1,3-dioxolane with active center is larger than that of tetraoxane, i.e., more than 90% 1,3-dioxolane is consumed at an early stage of the polymerization. The results obtained by microscopy, DSC, and GPC of the copolymer suggested that the copolymerization proceeds from the surface to the center of the tetraoxane crystal as if it were a core model. It was also suggested that the heterogeniety in copolymer properties can be explained not only by heterogeneous dispersion of 1,3-dioxolane in tetraoxane crystal, but also by the difference of reactivity of 1,3-dioxolane with the active center.     

Iodine-initiated,solid-state copolymerization of tetraoxane with 1,3-dioxolane in the presence of methylal. IV. Fractional dissolution of copolymer

A fractional dissolution on the oxymethylene copolymer obtained by the iodine-initiated, solid-state copolymerization of the tetraoxane–1,3-dioxolane-methylal system has been carried out using a mixed solvent which consists of tetrachloroethane, phenol, and cyclohexanol. On the fractional dissolution, the oxymethylene copolymer was divided mainly into two parts: one was the copolymer containing a larger amount of ethylene oxide unit in its main chain and having lower molecular weight; the other was copolymer containing a smaller amount of ethylene oxide unit and having a higher molecular weight. It was reasonably concluded that in this copolymerization system, the reaction proceeds from the surface to the center of the tetraoxane crystal to give a divided copolymer due to the heterogeneous properties such as copolymer composition and molecular weight.