Synthesis of some new disperse anthraquinone dyes

1-Hydroxy and/or 1-aminoanthraquinone was allowed to react with formaldehyde in an alkaline medium to give 1-hydroxy or 1-amino-2-hydroxymethyl-9,10-dihydroxy-anthracenes, which gave on air oxidation, hydroxymethylanthraquinone derivatives (I). Interaction of 1-amino-2-hydroxymethylanthraquinone or its 4-bromo derivative with carbonyl compounds in the presence of an acid catalyst gave (1,3)oxazine derivatives (II). The methylene group in position-2 of the (1,3)oxazine ring was found to be highly reactive and reacted with carbonyl compounds to form the corresponding arylidenes (III). Selective oxidation of dimethyl oxazine derivatives with SeO₂ gave the corresponding dialdehyde (IV), which interacted with aromatic amines to give the corresponding Schiff bases (V). The bromine atom in the 6-position of II was easily replaced by aromatic amines to give blue disperse dyes (VI).     

Toxicity of Phenolic Compounds Extracted from Bark Residues of Different Ages

In Quebec, Canada, industrial bark wastelands cover several hundred hectares of land. Bark residue that has piled up for decades tends to remain free of vegetation for years. To assess the revegetation potential of such sites, we sought to determine those factors responsible for poor plant growth. Phenolic compounds from fresh to 20-year-old bark residues were extracted with four solvents and quantified by high-performance liquid chromatography (HPLC). We simulated solutions (mixtures of standard phenolic compounds) to evaluate the potential toxic effects of phenolic compounds on the rhizobial growth, germination index, plant growth, nodule number, and nitrogen fixation activity of two legume species under laboratory conditions. The concentration of individual phenolic compounds varied from none detected to 350 μg/g bark residue. The extracted phenolic compounds differed among solvents and bark residues. The highest concentration of total phenolic compounds was from fresh bark; most of these were soluble in water or 0.1 M NaOH. For older bark residues, the total phenolic content depended on solvent strength, generally in the order of 2.0 M NaOH > 0.1 M NaOH = hot water > cold water. The biological activity of the simulated bark extracts was not established with the rhizobial growth inhibition test but with the germination index and rhizobium–legume symbiosis tests. With these, the toxicity of the simulated phenolic extracts decreased from fresh to the older bark residues. Plant dry weight, nodule number, and nitrogen fixation activity of vetch (Vicia sativa L.) were less negatively affected by high concentrations of phenolics than birdsfoot trefoil (Lotus corniculatus L.), although birdsfoot trefoil grew at lower concentrations. The rhizobium–legume symbiosis has potential for revegetating bark wastelands with less than 1 year old and older bark residues.     

On the use of large time steps with ELLAM for transport with kinetic reactions over heterogeneous domains

An Eulerian Lagrangian localized adjoint method (ELLAM) is considered for the resolution of advection‐dominated transport problems in porous media. Contrary to standard Eulerian methods, ELLAM can use large time steps because the advection term is approximated accurately without any CFL restriction. However, it is shown in this article that special care must be taken for the approximation of the dispersive and reactive terms when large time steps are used over heterogeneous domains. An alternative procedure is proposed. It is based on an equivalent dispersion coefficient or an equivalent reaction rate when different zones are encountered during the tracking. Numerical experiments are performed with variable dispersion or variable reaction rates over space (including nonlinearity). When classical ELLAM require numerous time steps to handle heterogeneity, the alternative procedure is shown to perform with the same accuracy in a single time step. © 2009 American Institute of Chemical Engineers AIChE J, 2009     

Investigation de la gestion de qualité de service dans le réseau UMTS

Bit rate announced for the future standards of telecommunication, as well as the level of integration reached are, as many factors, determining for the establishment of new applications in mobile terminals. Nowadays, mobile video streaming services are possible. Mobile users expect to receive multimedia traffic with some performance guarantees, so we must ensure the necessary quality of service during the video transmission. This paper aims at investigating quality of service issue inUmts network. More specifically, we explore the main challenge of quality of service management to dynamically optimize the distribution of load inUmts networks. Our investigation is organized in the following way. We formalize the optimization problem which is based on the graph theory and modellingUmts network as well as mobile users and applications to be used. The simulation of our optimization model show a clear improvement of the quality of service perceived by anUmts user in terms of bit rate, blocking and connection drop.     

Numerical study of n-heptane/benzene separation by thermal diffusion column

In this article,numerical simulations are performed to investigate the performance of the thermal diffusion column for the separation of n-heptane/benzene mixture.The present work tried to optimize column by analyzing significant parameters such as feed flow rate,temperature and cut.In order to obtain the hydrodynamic and temperature and mass distribution inside thermal diffusion column,computational fluid dynamic(CFD) method is applied to solve the Navier-Stocks equations.Numerical simulations are conducted to study the main parameters in both stationary and time-dependent conditions.By using the separation work unit as a function of cut,the optimal cut for maximum SWU occurs within a limited range of 0.47-0.5 for feed rate between 0.5 and 4 g min-1.Our findings reveal that the optimum feed rate in the range of optimum cut is about 1 g min~(-1).In transient study,results show that the best cut for reaching to steady-state condition is θ=0.5.     

A performance evaluation of a fault-tolerant path recommendation protocol for smart transportation system

Recommending traveling vehicles to take a certain path towards their targeted destinations have received great interest recently. At the downtown area several paths can lead to the same located destination, this is due to the grid-layout architecture of modern downtowns. Drivers always wish to reach their destinations as fast as possible and without traveling drastically long distance or without consuming extra fuel. The best path towards any destination is determined based on the relative location of the vehicle from its destination and based on other vehicles traffic distribution on the road network. Although numerous studies have investigated this issue over the road network, the communication failures and their effects on the obtained path have been neglected in those previous studies. In this paper, we investigate these potential faults and their effects on the correctness of the selected paths. We then proposed a new protocol to tackle these potential failures while selecting the best path towards each destination over the road network, fault tolerant path recommendation protocol (FT-PR). From the experimental results, we can see that the FT-PR protocol has a higher success ratio than previous path recommendation protocols, such as ICOD. This is demonstrated by obtaining paths with shorter traveling time and shorter traveling distance. The FT-PR protocol also eliminates extra loops over the road network in each selected path.     

Advances of nanofluids in heat exchangers—A review

Recently, many researchers have focused on their studies on the analysis of nanofluid flows due to their participation in the enhancement of heat transfer rates in industrial processes. The ordinary fluids, such as water, mineral oils, and so on, are known for their low thermal conductivity in heat transfer processes. A significant enhancement in the thermal properties of ordinary fluid may be obtained by adding nanoparticles having a diameter of less than 100 nm or suspension of fibers. Better spreading, wetting, dispersion, and stability and with acceptable viscosity are the main advantageous properties of nanofluids on a solid surface. The nanofluids are encountered in various thermal engineering systems such as in heat exchangers, refrigeration, thermal management of fuel cells, cooling of nuclear reactors, microelectromechanical systems, and others. In particular, the thermal conversion is known as a great application of nanotechnology, and many studies have been achieved with such fluids in heat exchangers. Therefore, this paper aims to present a global insight into the different applications of nanofluids in various heat exchangers, that is, heat pipe and plate-fin heat exchangers. All research works have been summarized into three main parts: laminar, transition, and turbulent nanofluid flow regimes.     

The Effect of Ti Addition on Microstructure and Magnetic Properties of Nanocrystalline FeAl40 Alloy Powders Prepared by Mechanical Alloying

Powder Metallurgy and Metal Ceramics - Recent research on nanocrystalline FeAl alloys has shown that these alloys are of high importance due to their promising structural and mechanical properties,...     

Exopolysaccharide from Pantoea sp. BCCS 001 GH isolated from nectarine fruit: production in submerged culture and preliminary physicochemical characterizations

Food Science and Biotechnology - Exopolysaccharide (EPS), as potential microbial base polysaccharide source, has plenty of applications due to its unique physicochemical structure. A Pantoea sp....