Classification,characterization, and the production processes of biopolymers used in the textiles industry

This article is focused on biopolymers as intelligent environmentally friendly polymers, the production processes, and coatings of biotextiles used in different industries for next generation environmental applications. Furthermore, classification and composition of biodegradable polymers, the theoretical techniques, and factorial experimental designs for the optimization of processes with intelligent biotextiles used as an alternative to commercial chemical-based textiles at reasonable cost with a zero to low environmental footprint are discussed. This article will also provide how these novel modeling methodologies will assist polymer designers in making the best decision. The present work also discusses how the fully biodegradable polymers support the textiles industry by decreasing the processing energy, material, and manufacturing costs. Finally, current development as well as potential future applications and trends of biodegradable polymers in modern biodegradable textiles industry will be presented.     

Magnetic immobilization of recombinant E. coli producing extracellular asparaginase: An effective way to intensify downstream process

Purification is one of the most important steps in biotechnological downstream process. This procedure is associated with some difficulties including several separation steps. Common cell separation procedures are usually time and energy consuming that also compromises cell growth, viability and reusability. Magnetic immobilization was introduced as a novel separation technique to provide a quick, easy and convenient alternative vs. traditional cell harvesting methods. In this study, recombinant E. coli producing extracellular asparaginase was decorated by synthesized L-lysine coated iron oxide nanoparticles and cell growth, immobilization efficiency and asparaginase productivity was evaluated.     

Modelling of the blend ratio effect on the mechanical properties of the biofibres

This work investigates the effect of the blend ratios of three different environmental-friendly biopolymers on fibres’ properties made by water bath extrusion machine and multi-stage drawing frame. Tensile test, shrinkage test, differential scanning calorimetry and scanning electron microscopy are used to study the mechanical and thermal properties of composed fibres. In the modelling stage, stepwise regressions were used as faster and less prone technique to over fit the results by watching the order in which blend ratios are increased or decreased, that help to meet the requirements of specific applications. The statistical-based models control the biodegradable fibre properties beyond the selected range of the blend ratios more than that can be obtained from single polymer equivalents. The forecasting designed program simulates the relationship between the blend ratios and the biofibre’ properties to save both time and cost of the production process, this novel method steps could be applied on different polymers.     

Development of Emu oil-loaded PCL/collagen bioactive nanofibers for proliferation and stemness preservation of human adipose-derived stem cells: possible application in regenerative medicine

Adipose tissue-derived stem cells (ASCs) are promising candidate in stem cell therapies, and maintaining their stemness potential is vital to achieve effective treatment. Natural-based scaffolds have been recently attracted increasing attention in nanomedicine and drug delivery. In the present study, a polymeric nanofibrous scaffold was developed based on the polycaprolactone/Collagen (PCL/Coll) containing Emu oil as a bioactive material to induce the proliferation of ASCs, while simultaneously preserving the stemness property of those cells. Fabrication of the electrospun Emu oil-loaded PCL/Coll nanofibers was confirmed by using FE-SEM, FTIR, and tensile test. ASCs were seeded on two types of nanofibers (PCL/Coll and Emu oil-loaded PCL/Coll) and their proliferation, cell cycle progression, and stemness gene expressions were evaluated using MTT, propidium iodide staining, and qPCR during 14?days, respectively. The results indicated that ASCs displayed improved adhesion capacity with the higher rates of bioactivity and proliferation on the Emu oil-loaded nanofibers than the other groups. The proliferation capacity of ASCs on Emu oil-loaded PCL/Coll nanofibers was further confirmed by the cell cycle progression analysis. It was also found that Emu oil-loaded nanofibers significantly up-regulated the expression of stemness markers including sox-2, nanog, oct4, klf4, and c-Myc. The results demonstrated that the nanofibers containing Emu oil can reinforce the cell adhesion and enhance ASCs proliferation while preserving their stemness; therefore, using scaffolds containing natural products may have a great potential to enhance the in vitro expansion capacity of ASCs in the field of stem cell therapy and regenerative medicine.     

SOURCE ROCK CHARACTERIZATION BASED ON BIOLOGICAL MARKER DISTRIBUTIONS OF CRUDE OILS IN THE SOUTHERN GULF OF SUEZ, EGYPT

The depositional environment and maturity of source rocks in the southern Gulf of Suez were evaluated using biomarker and isotope data from crude oils derived from a variety of source rock types of different geological ages. Two oils families were identified and are referred to as types A and B. Type A oils are characterized by a predominance of oleanane and relatively low gammacerane concentrations, suggesting that they were derived from a terrigenous source rock with a significant input of angiosperm material inferred to occur within the marginally-mature syn-rift Lower Miocene Rudeis Shale. By contrast, type B oils are distinguished by a predominance of gammacerane and relatively low oleanane concentrations, suggesting that they were generated from mature marine carbonate source rocks inferred to occur within the Upper Cretaceous Brown Limestone and Middle Eocene Thebes Formation. Maturity parameters including the sterane isomerisation ratios C ₂₉αββ/(αββ+ααα), C₂₉ααα20S/(S+R) and TAS/(TAS+MAS), together with aromatic sulphur compound ratios (4-MDBT / I-MDBT; 4,6- / 1,4-DMDBT; 2,4–/ 1,4-DMDBT; and DBT / phenanthrenes), support the higher thermal maturity of type B oils relative to type A oils.
The biomarker variablility reflects the occurrence of two distinct source rocks in the southern Gulf of Suez and suggests that two independent petroleum systems are present here. These appear to be confined to the pre-rift (pre-Miocene) and syn-rift megasequences respectively.     

A Reference Benchmark Solution for Free Convection in A Square Cavity Filled with A Heterogeneous Porous Medium

The Fourier-Galerkin (FG) method is used to produce a highly accurate solution for free convection in a square cavity filled with heterogeneous porous medium. To this end, the governing equations are reformulated in terms of the temperature and the stream function. These unknowns are then expanded in infinite Fourier series truncated at given orders. The accuracy of the FG solution is investigated for different truncation orders and compared to the results of an advanced finite-element numerical model using fine-mesh discretization. The obtained results represent a set of high-quality data that can be used for benchmarking numerical models.     

Birefringent approach for assessing the influence of the extrusion temperature profile on the overall orientation of as‐spun aliphatic‐aromatic co‐polyester fibers

Since the success of a production process depends on its good planning and having a clear plan from the raw materials until the final product, the focus of this research is in modeling of the extrusion temperature profile of as‐spun aliphatic‐aromatic co‐polyester fibers. The extrusion temperature profile affects the properties, productivity and product cost. In this work, as‐spun aliphatic‐aromatic co‐polyester fibers were spun under a fractional factorial design as a function of the extrusion temperature profile using appropriate statistical methods. The influence of the extrusion temperature profile on the optical birefringence of the as‐spun fibers was characterized. From the obtained results the overall orientation of the spun filaments has been modeled. For measuring the birefringence, an interferometric technique was employed and its microinterferograms were included for illustration. POLYM. ENG. SCI., 2009. © 2009 Society of Plastics Engineers     

Faceting, composition and crystal phase evolution in III-V antimonide nanowire heterostructures revealed by combining microscopy techniques

III-V antimonide nanowires are among the most interesting semiconductors for transport physics, nanoelectronics and long-wavelength optoelectronic devices due to their optimal material properties. In order to investigate their complex crystal structure evolution, faceting and composition, we report a combined scanning electron microscopy (SEM), transmission electron microscopy (TEM), and scanning tunneling microscopy (STM) study of gold-nucleated ternary InAs/InAs(1-x)Sb(x) nanowire heterostructures grown by molecular beam epitaxy. SEM showed the general morphology and faceting, TEM revealed the internal crystal structure and ternary compositions, while STM was successfully applied to characterize the oxide-free nanowire sidewalls, in terms of nanofaceting morphology, atomic structure and surface composition. The complementary use of these techniques allows for correlation of the morphological and structural properties of the nanowires with the amount of Sb incorporated during growth. The addition of even a minute amount of Sb to InAs changes the crystal structure from perfect wurtzite to perfect zinc blende, via intermediate stacking fault and pseudo-periodic twinning regimes. Moreover, the addition of Sb during the axial growth of InAs/InAs(1-x)Sb(x) heterostructure nanowires causes a significant conformal lateral overgrowth on both segments, leading to the spontaneous formation of a core-shell structure, with an Sb-rich shell.     

Experimental Study of the Corona Discharge in a Modified Coaxial Wire-Cylinder Electrostatic Precipitator

Coaxial wire-cylinder electrode arrangements are widely used for the electrostatic precipitation of dust particles contained in flue gases. The aim of this paper was to evaluate a new design, which was expected to increase the particle collection efficiency. The collector electrode of the several models under study consisted of a cylinder with alternate small- and large-diameter sections. In a first set of experiments, the current–voltage characteristics of each model were compared with those obtained for a standard wire-cylinder electrode arrangement, at both polarities of the high-voltage supply, and for three values of the inlet airflow rate, namely, 0, 4.5, and 6 $hbox{dm}^{3}/hbox{min}$, with the corresponding air velocities in the large-diameter sections being 0, 6.0, and 8.0 cm/s. A second set of experiments showed that the current density distribution inside the models depends on the geometry of the electrode system but is roughly the same at 4.5 and 6 $hbox{dm}^{3}/hbox{min}$. The particle collection efficiency of the different models was evaluated in a third set of experiments, performed with 2-g samples of starch powder, under various operating conditions. Data analysis revealed that the modified precipitators have higher efficiency than the standard model. As expected, for a given geometry of the electrode arrangement, the efficiency was found be lower at higher inlet airflow rates. These findings could serve in the design of new industrial electrostatic precipitators.