In Situ Observation of Deformation in Semi-solid Fe-C Alloys at High Shear Rate

Synchrotron X-ray radiography at 125 frames per second was used to study deformation mechanisms in semi-solid Fe-C alloys at high solid fraction and shear strain rates of 10^?1/s. An image correlation approach was also used to quantify the shear strain fields and study shear-induced dilation and the origin of shear cracking. It was shown that, at high solid fraction (90 to 93 pct solid), rearrangement including rotation and translation of solid particles became restricted and shear strain localized into narrow liquid-filled channels/fissures. Shear cracking was shown to originate from inadequate liquid flow into the expanding spaces between solid particles caused by shear-induced dilation. At lower solid fraction (~85 pct solid), solid particles rearranged with a significantly higher component of rotation leading to more shear-induced dilation and a wider shear band.     

Acid catalytic hydrothermal conversion of carbohydrate biomass into useful substances

Acidic hydrothermal degradation of glucose was examined in the presence of HCl, H₂SO₄, and H₃PO₄ with pH varying from 1.5 to 2.5 and reaction time varying from 1 to 10 min at 523 K, to investigate the effect of different acid catalysts and acid concentration on the production of 5-hydroxymethyl-2-furaldehyde (HMF) and levulinic acid from glucose. At lower acidities of pH 2.5, a considerably higher amount of HMF was produced. The increase in acid concentration accelerated the conversion of HMF to levulinic acid. The order for the production of HMF using the three acids is in the sequence of H₃PO₄ > H₂SO₄ > HCl. On the contrary, the order for production of levulinic acid follows HCl > H₂SO₄ > H₃PO₄. In the experimental conditions used in this study, the highest yield of levulinic acid is about 55%, which was obtained at pH 1.5 for 5 min in the case of HCl as an acid catalyst, and the total highest yields of HMF and levulinic acid are about 50%, which occurred at pH 2.0 for 5 min in the case of H₃PO₄ as an acid catalyst.     

Fabrication and Mechanical Properties of Continuously Graded MoSi2–ZrO2(2Y) Materials Using Wet-Molding

Continuously graded MoSi₂-ZrO₂(2Y) materials with high density (97.5% of theoretical) have been fabricated by uniaxial wet-molding, followed by hot pressing (1000°C/1 h/30 MPa) and hot isostatic pressing (1400°C/2 h/196 MPa). Their composition profiles are greatly influenced by the viscosity of mixed solutions of glycerin and ethanol used as a dispersion medium; a linear compositional gradient from MoSi₂/ZrO₂(2Y) 70/30 to 20/80 mol% is obtained from the solution (50/50 vol%) with a viscosity of 20 mPa s. Vickers hardness (Hv) and fracture toughness (KIC) increase from 9.7 to 12.4 GPa and from 5.1 to 12.5 MPa m1/2, respectively, with increasing ZrO₂(2Y) composition.     

GaAs/AlGaAs directional coupler switch with submillimetre device length

A GaAs/AlGaAs directional coupler switch, for the first time with a device length shorter than 1 mm, has been fabricated by utilising the good controllability of molecular beam epitaxy and reactive ion beam etching. The switching voltage is as low as 5V. The extinction ratio is 17dB for a crossover state and 14dB for a straight-through state.