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111.
112.
Ling Tan Kipkorir Peter Jing Ren Baoyang Du Xiaojie Hao Yufei Zhao Yu-Fei Song 《Frontiers of Chemical Science and Engineering》2021,15(1):99-108
The rational design of photocatalyst that can effectively reduce CO2 under visible light(l>400 nm),and simultaneously precise control of the products syngas(CO/H2)ratio is highly desirable for the Fischer-Tropsch reaction.In this work,we synthesized a series of CeO2-decorated layered double hydroxides(LDHs,Ce-x)samples for photocatalytic CO2 reduction.It was found that the selectivity and productivity of CO and H2 from photoreduction of CO2 in conjunction with Ru-complex as photosensitizer performed an obvious“volcano-like”trend,with the highest point at Ce-0.15 and the CO/H2 ratio can be widely tunable from 1/7.7 to 1/1.3.Furthermore,compared with LDH,Ce-0.15 also drove photocatalytic CO2 to syngas under 600 nm irradiation.It implied that an optimum amount of CeO2 modifying LDH promoted the photoreduction of CO2 to syngas.This report gives the way to fully utilize the rare earth elements and provides a promising route to enhance the photo-response ability and charge injection efficiency of LDH-based photocatalysts in the synthesis of syngas with a tunable ratio under visible light irradiation. 相似文献
113.
Junpeng Xiong Weili Shao Ling Wang Chen Cui Yurui Jin Hongqin Yu Pengju Han Yanfei Gao Fan Liu Qingqing Ni Jianxin He 《大分子材料与工程》2021,306(11):2100371
Recently, because of the outbreak of COVID-19, the demand for various types of filter elements in protective materials has increased globally. Furthermore, new requirements for the filtration performance of PM2.5 liquid (oil) particles have been put forward. In this work, Superhydrophobic and superoleophobic composite nanofibers with excellent filtration capacity for oil and salt particles are developed through the modification of polyacrylonitrile (PAN) by fluoro-polyurethane (FPU) doping. The results show that the PAN/FPU composite nanofibers doped with 9 wt% FPU has a uniform fiber morphology with a diameter of 240 ± 30 nm. Compared to the pure PAN nanofibers, the water-based contact angle of PAN/FPU increases from 90 ± 5° to 151 ± 5°, and the oil-based contact angle increases from 58 ± 2° to 152 ± 3°. Importantly, at a high flow rate of 95 L min−1, the filtration efficiency of the PAN/FPU nanofiber membrane for 0.3 µm oil particles increases from 92 ± 1% to 99.2 ± 0.1%. After cyclic loading, the filtration efficiency of 0.3 µm oil particles remains above 98%. Meanwhile, the filtration efficiency for 0.3 µm salt particles remains at 98.23 ± 0.1%. The PAN/FPU nanofiber membrane developed in this work is effective in applications and has good market prospects as a protective filtration material. 相似文献
114.
Flow stress and softening behavior of wrought magnesium alloy AZ31B at elevated temperature 总被引:3,自引:0,他引:3
1 INTRODUCTIONThewroughtmagnesiumalloyshaveexcellentspecificstrengthandstiffness ,machinability ,dampcapacity ,dimensionalstability ,lowmeltingcostsandare ,hence ,veryattractiveinsuchapplicationsasau tomobile ,aviation ,electronicandcommunicationin dustry[16 ] .Investigationsontheflowstressandsofteningbehaviorofmagnesiumalloysathigherformingtem peratureandstrainratehavebeenanimportantsub jectinwroughtmagnesiumalloysforming[710 ] .InthispapertheflowstressandsofteningbehaviorofAZ31Bdeform… 相似文献
115.
以曲面零件悬空区上径向最大拖动阻力为优化的目标函数,在模具几何约束、压筋时不诱发外皱、完全包筋等条件下,建立了拉深筋结构参数优化的数学模型。对拉深筋的高度H、圆角半径Rn、位置半径Rj、凹槽入口圆角半径rd等参数进行了优化,从而为合理选择拉深筋的参数提供了依据。文中还以实例进行了示算。 相似文献
116.
Intelligent temperature control system of quench furnace 总被引:1,自引:0,他引:1
1 INTRODUCTIONQuenchfurnaceisakindofkeyequipmentusedtoheattreatlargecomplexcomponentsofaircraftsorrockets ,withheightof 2 4m ,containingtwoheatingroomsandaworkroom ,withsteelboardssetbetweentherooms .Bothheatingroomsareseparatedintosixsections ,eachofwhichcontainsaheatingresistancecontrolledbyapoweradjuster .Workpiecesareputinworkroom .Acentrifugalelectromotorisusedtoblowhotairintoworkroomfromheatingroom .Thede mandofalloyintemperature risingrateandstableve racityatfixedtemperaturepointi… 相似文献
117.
118.
WANG Bowen CAO Shuying WENG Ling HUANG Wenmei SUN Ying 《稀有金属(英文版)》2006,25(5):538-542
The structure, magnetization, and magnetostriction of Sm0.9Pr0.1Fex and Sm1-xNdxFel.9 thin films have been investigated using X-ray diffraction, vibrating sample magnetometer, and optical cantilever method. It is found that the structure of Sm0.9Pr0.1Fex thin films consists of an Sm-Pr-Fe amorphous phase when x≤2.69 and that of Sm1-xNdxFel.9 thin films consists of an Sm-Nd-Fe amorphous phase. The in-plane magnetization of Sm0.91Pr0.1Fex thin films increases with increase in the Fe content, and low values of the in-plane coercivity occur in the range of 1.62≤ x≤ 2.28. The magnetostriction value of Sm0.91Pr0.1Fex thin films increases with increasing the Fe content when x ≤ 1.94 and decreases when x 〉 1.94. The in-plane magnetostriction of Sm1-xNdxFe1.9 thin films under low magnetic fields has been improved by the substitution of Nd for Sm when x = 0.2. 相似文献
119.
120.
模具盐浴稀土钒硼共渗的组织与性能 总被引:1,自引:0,他引:1
研究了Cr12Mov.Cr12,9CrSi和T8等钢的盐浴稀土钒硼共渗共艺,渗层组织与性能;讨论了共渗工艺参数、共渗剂成分配比及稀土元素添加量等因素对共渗层的影响。冷作模具的使用寿命经RE-V-B共渗处理后比常规工艺处理的提高3~7倍。 相似文献