全文获取类型
收费全文 | 288637篇 |
免费 | 22355篇 |
国内免费 | 11076篇 |
专业分类
电工技术 | 15370篇 |
技术理论 | 31篇 |
综合类 | 17432篇 |
化学工业 | 50202篇 |
金属工艺 | 16861篇 |
机械仪表 | 18430篇 |
建筑科学 | 22877篇 |
矿业工程 | 9524篇 |
能源动力 | 7955篇 |
轻工业 | 16666篇 |
水利工程 | 4780篇 |
石油天然气 | 20257篇 |
武器工业 | 2234篇 |
无线电 | 31501篇 |
一般工业技术 | 34381篇 |
冶金工业 | 15266篇 |
原子能技术 | 2858篇 |
自动化技术 | 35443篇 |
出版年
2024年 | 1218篇 |
2023年 | 4676篇 |
2022年 | 7920篇 |
2021年 | 11407篇 |
2020年 | 8527篇 |
2019年 | 7273篇 |
2018年 | 8171篇 |
2017年 | 9219篇 |
2016年 | 8026篇 |
2015年 | 11172篇 |
2014年 | 13771篇 |
2013年 | 16447篇 |
2012年 | 17753篇 |
2011年 | 19406篇 |
2010年 | 16754篇 |
2009年 | 15902篇 |
2008年 | 15439篇 |
2007年 | 15084篇 |
2006年 | 15975篇 |
2005年 | 14151篇 |
2004年 | 9050篇 |
2003年 | 7913篇 |
2002年 | 7314篇 |
2001年 | 6486篇 |
2000年 | 7100篇 |
1999年 | 8501篇 |
1998年 | 6847篇 |
1997年 | 5824篇 |
1996年 | 5450篇 |
1995年 | 4507篇 |
1994年 | 3757篇 |
1993年 | 2628篇 |
1992年 | 2138篇 |
1991年 | 1602篇 |
1990年 | 1173篇 |
1989年 | 933篇 |
1988年 | 759篇 |
1987年 | 523篇 |
1986年 | 389篇 |
1985年 | 266篇 |
1984年 | 183篇 |
1983年 | 120篇 |
1982年 | 130篇 |
1981年 | 86篇 |
1980年 | 70篇 |
1979年 | 24篇 |
1978年 | 2篇 |
1965年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
121.
122.
123.
124.
Meifang Luo Chaozhong Guo Xinyi Luo Zhaoxu Li Yuan Qin Weizhong Zhang 《International Journal of Hydrogen Energy》2021,46(2):2117-2127
It is of great urgency to design inexpensive and high-performance oxygen reduction reaction (ORR) electrocatalysts derived from biowastes as substitutes for Pt-based materials in electrochemical energy-conversion devices. Here we propose a strategy to synthesize three-dimensional (3D) porous nitrogen-doped network carbons to catalyze the ORR from two-step pyrolysis engineering of biowaste scale combined with the use of a ZnCl2 activator and a FeCl2 promotor. Electrochemical tests show that the synthesized network carbons have exhibited comparable ORR catalytic activity with a half-wave potential (~0.85 V vs. RHE) and outstanding cyclical stability in comparison to the Pt/C catalyst. Beyond that, a high electron transfer number (~3.8) and a low peroxide yield (<7.6%) can be obtained, indicating a four-electron reaction pathway. The maximum power density is ~68 mW cm?2, but continuous discharge curves (at a constant potential of ~1.30 V) for 12 h are not obviously declined in Zn-air battery tests using synthesized network carbons as the cathodic catalyst. The formation of 3D porous structures with high BET surface area can effectively expose the surface catalytic sites and promote mass transportation to boost the ORR activity. This work may open a new idea to prepare porous carbon-based catalysts for some important reactions in new energy devices. 相似文献
125.
Bing Yang Yu Zhou Wenjie Yu Song Zhang Hongxiang Chen Ju Ye 《Polymer International》2019,68(4):675-683
In order to improve the dispersity and stability of the nano‐SiO2 aqueous system with high solid content, a kind of polyacrylic acid dispersant with methoxysilicon end groups (KH590‐PAA) was synthesized by photopolymerization of acrylic acid (AA) initiated with (3‐mercaptopropyl)trimethoxysilane (KH590). After adding KH590‐PAA into the nano‐SiO2 aqueous dispersion system (20 wt% solid content), the viscosity and the curing time of the system were measured with a rotational viscometer and the inverted bottle method. Moreover, the dispersion mechanism of KH590‐PAA for the nano‐SiO2 aqueous system was researched by measuring the adsorption capacity, the particle size and the zeta potential of the nanoparticles with a conductivity meter, dynamic light scattering, SEM and TEM, respectively. The results showed that the methoxysilicon groups in KH590‐PAA could react with hydroxyl groups on the surface of nano‐SiO2 in the process of stirring, which enhanced the adsorption capacity of the dispersant and then increased the surface charge of the particles. Therefore, electrostatic repulsion and steric hindrance effects between the SiO2 nanoparticles could be further enhanced by adding the KH590‐PAA dispersant, and then the nano‐SiO2 aqueous system exhibited better dispersity and stability. Besides, the dispersion properties of SiO2 nanoparticles in water were closely related to the addition amount and the molecular weight of the KH590‐PAA dispersant. © 2018 Society of Chemical Industry 相似文献
126.
Ionomics is a novel multidisciplinary field that uses advanced techniques to investigate the composition and distribution of all minerals and trace elements in a living organism and their variations under diverse physiological and pathological conditions. It involves both high-throughput elemental profiling technologies and bioinformatic methods, providing opportunities to study the molecular mechanism underlying the metabolism, homeostasis, and cross-talk of these elements. While much effort has been made in exploring the ionomic traits relating to plant physiology and nutrition, the use of ionomics in the research of serious diseases is still in progress. In recent years, a number of ionomic studies have been carried out for a variety of complex diseases, which offer theoretical and practical insights into the etiology, early diagnosis, prognosis, and therapy of them. This review aims to give an overview of recent applications of ionomics in the study of complex diseases and discuss the latest advances and future trends in this area. Overall, disease ionomics may provide substantial information for systematic understanding of the properties of the elements and the dynamic network of elements involved in the onset and development of diseases. 相似文献
127.
Kang Zhang Rong‐rong Wang Kai‐rui Zhang Fei Cheng Yu Tian Yi Lin Mi Zhou Pu‐xin Zhu 《Polymer International》2020,69(3):274-279
A series of hyperbranched poly(citric polyethylene glycol) (PCPEG) materials with varied polyethylene glycol (PEG) chain lengths as plasticizers were mixed with maize starch (MS) via cooking and film‐forming. The structure, pasting property, plasticization, aging property, moisture absorption and compatibility of plasticized starches were studied by means of Fourier transform infrared spectroscopy, X‐ray diffraction, rapid viscosity analysis, tension testing, moisture absorption measurements and scanning electron microscopy. Compared with PEG and citric acid, PCPEG was more effective in promoting starch chain movement and inhibiting the retrogradation of starch film. Also, PCPEG/MS had smaller moisture content. The longer the plasticizer chain, the better were the aging resistance and moisture resistance of starch. But with an increase of PEG chain length, mechanical properties of PCPEG/MS deteriorated and the compatibility between PCPEG and MS decreased. The hyperbranched derivative of PEG with longer chain exhibited improved plasticization and compatibility with starch. © 2019 Society of Chemical Industry 相似文献
128.
使用气-质联用仪测定餐饮废油生物柴油(WCME)和-10号柴油(-10PD)的组成,使用冷滤点试验器和运动黏度试验器测定WCME的低温流动性,同时使用调合、添加低温流动性改进剂的方法改进WCME的低温流动性。实验结果表明,WCME主要由饱和脂肪酸甲酯和不饱和脂肪酸甲酯组成,质量分数分别为27.63%和71.81%;WCME冷滤点为0℃,运动黏度(40℃)为4.41mm2/s;WCME与-10PD调合后,冷滤点降低,其中B20的冷滤点最低,为-13℃,运动黏度随着WCME的体积分数的减少,逐渐接近-10PD的运动黏度。通过添加低温流动性改进剂,WCME,B10,B20的冷滤点分别从0,-8,-13℃降至-4,-26,-25℃。 相似文献
129.
130.
基于目前中国改进型三环路压水堆(CPR1000)部分机组存在因中间量程电流饱和导致无法在48%额定功率(Pn)完成定值标定及核电厂大修经济性考虑,采用MCNP程序及核设计软件包SCIENCE,研究分析中间量程保护定值标定的新方法。分析结果表明,中间量程保护定值标定调整至30%Pn功率平台实施,采用改进方法标定的保护定值更接近于设计值。 相似文献