Hydrothermal Reaction Mechanism and Pathway for the Formation of K2Ti6O13 Nanowires

Calculations and detailed first principle and thermodynamic analyses have been performed to understand the formation mechanism of K₂Ti₆O₁₃ nanowires (NWs) by a hydrothermal reaction between bulk Na₂Ti₃O₇ crystals and a KOH solution. It is found that direct ion exchange between K⁺ and Na⁺ plus H⁺ interactions with [TiO₆] octahedra in Na₂Ti₃O₇ promote the formation of an intermediate H₂K₂Ti₆O₁₄ phase. The large lattice mismatch between this intermediate phase and the bulk Na₂Ti₃O₇ structure, and the large energy reduction associated with the formation of this intermediate phase, drive the splitting of the bulk crystal into H₂K₂Ti₆O₁₄ NWs. However, these NWs are not stable because of large [TiO₆] octahedra distortion and are subject to a dehydration process, which results in uniform K₂Ti₆O₁₃ NWs with narrowly distributed diameters of around 10 nm.     

木玩世家锻造品牌之路

4月广州，春暖花开。先后召开的广州国际玩具及礼品展和广州春交会，让花城沸腾了。在这盛会上，一位年仅29岁的浙江商人和他的300多款精美的木制玩具格外引人注目，订单接踵而至。     

Armlets and balanced multiwavelets: flipping filter construction

In the scalar-valued setting, it is well-known that the two-scale sequences {q/sub k/} of Daubechies orthogonal wavelets can be given explicitly by the two-scale sequences {p/sub k/} of their corresponding orthogonal scaling functions, such as q/sub k/=(-1)/sup k/p/sub 1-k/. However, due to the noncommutativity of matrix multiplication, there is little such development in the multiwavelet literature to express the two-scale matrix sequence {Q/sub k/} of an orthogonal multiwavelet in terms of the two-scale matrix sequence {P/sub k/} of its corresponding scaling function vector. This paper, in part, is devoted to this study for the setting of orthogonal multiwavelets of dimension r=2. In particular, the two lowpass filters are flipping filters, whereas the two highpass filters are linear phase. These results will be applied to constructing both a family of the most recently introduced notion of armlet of order n and a family of n-balanced orthogonal multiwavelets.     

EPP在便携式数据采集系统中的应用

分析了并口处于EPP(增强型并行端口)模式时和单片机进行数据交换的原理.介绍了有关EPP的基本特性、信号定义、操作模式及其程序设计方法,设计了基于EPP协议的便携式数据采集系统,给出了技术解决方案,讨论了系统的硬件接口电路和软件编程.方案具有可靠性高、速度快、软硬件设计简捷等优点.     

八种新功能晶体的比热及其与相变掺杂物关系的实验研究

本文对八种新型功能晶体Ｌｉ２Ｂ４Ｏ７、Ｂｉ１２ＴｉＯ２０、Ｂｉ１２ＧｅＯ２０、Ｂｉ１２ＧｅＯ２０、Ｂｉ４Ｇｅ３Ｏ１２、Ｓｒ１－ｘＢａｘＮｂ２Ｏ６（ｘ＝０．３３，０．４８）、ＬｉＴａＯ３等在１３０～９７３Ｋ范围内的比热行为及其与相变、组分之间的关系进行了实验研究，给出了比热的多项式拟合方程，并与用纽曼－卡普定律及用Ｗｉｋｅｌｍａｎｎ经验方程的比热计算值作了对比，为晶体比热的估算提供了依据和方法。     

最大熵重建的迭代凸I投影算法

本文探讨了用迭代凸Ｉ投影（ＩｔｅｒａｔｉｖｅＣｏｎｖｅｘＩ－Ｐｒｏｊｅｃｔｉｏｎ，ＩＣＩＰ）算法求解最大熵Ｘ－ＣＴ重建问题．其思路是将这个复杂问题转化为多个简单子问题，然后迭代地求解这种单约束子问题．理论证明，这种算法收敛并能收敛到问题的最大熵解．这种算法形式优美，仿真结果表明算法同时也是有效的．     

1-methyl-4-phenyl-1,2,3,6-tetrahydropyridine as a substrate of cytochrome P450 2D6: allosteric effects of NADPH-cytochrome P450 reductase

1-Methyl-4-phenyl-1,2,3,6-tetrahydropyridine (MPTP), a neurotoxin that produces Parkinsonism symptoms in man, has been examined as a substrate of recombinant human cytochrome P450 2D6. When cumene hydroperoxide is used as an oxygen and electron donor, a single product is formed, identified as 4-phenyl-1,2,3,6-tetrahydropyridine. The K(m) for formation of this product (130 microM) is in agreement with the dissociation constants for MPTP binding to the enzyme determined by optical and nuclear magnetic resonance (NMR) spectroscopy. When the reaction is carried out with nicotinamide adenine dinucleotide phosphate (reduced) (NADPH) and recombinant human NADPH-cytochrome P450 reductase, a second product, identified as 1-methyl-4-(4'-hydroxyphenyl)-1,2,3,6-tetrahydropyridine, is formed in addition to 4-phenyl-1,2,3,6-tetrahydropyridine. The K(m) values for formation of these two products are 19 microM and 120 microM, respectively. Paramagnetic relaxation experiments have been used to measure distances between the protons of bound MPTP and the heme iron, and these have been used to construct models for the position and orientation of MPTP in the active site. For the cytochrome alone, a single mode of binding was observed, with the N-methyl close to the heme iron in a position appropriate for the observed N-demethylation reaction. In the presence of the reductase, the data were not consistent with a single mode of binding but could be explained by the existence of two alternative orientations of MPTP in the active site. One of these, characterized by a dissociation constant of 150 microM, is essentially identical to that observed in the absence of the reductase. In the second, which has a K(d) of 25 microM, the MPTP is oriented so that the aromatic ring is close to the heme iron, in a position appropriate for p-hydroxylation leading to the formation of the product seen only in the presence of the reductase. In the case of codeine, another substrate for cytochrome P450 2D6, the addition of reductase had no effect on the nature of the product formed, the dissociation constant, or the orientation in the binding site. These observations show that NADPH-cytochrome P450 reductase has an allosteric effect on the active site of cytochrome P450 2D6 that affects the binding of some substrates but not others.     

高速冷带轧机垂直自激振动稳定性分析的数值计算方法

本文在充分考虑轧机垂直振动过程中辊缝非线性的基础上，利用轧制理论方程和机械振动理论中的能量判据，给出了更精确的分析高速冷轧机垂直自激振动稳定性的数值计算方法。     

低银医用X光胶片的研制

对几种增黑剂进行了筛选实验研究，选用了两种增黑剂组合使用，提高了遮盖力，使医用Ｘ光胶片涂布银量由原业的９ｇ／ｍ２降到了６．８ｇ／ｍ２，与美国医用Ｘ光胶片涂布银量（６．７ｇ／ｍ２）相当，照相性能不低于国产医用Ｘ光胶片。     

Nucleate Pool Boiling of Pure Liquids and Binary Mixtures：PartI－Analytical Model for Boiling Heat Transfer of Pure Liquids on Smooth Tubes

ＮｕｃｌｅａｔｅＰｏｏｌＢｏｉｌｉｎｇｏｆＰｕｒｅＬｉｑｕｉｄｓａｎｄＢｉｎａｒｙＭｉｘｔｕｒｅｓ：ＰａｒｔＩ－ＡｎａｌｙｔｉｃａｌＭｏｄｅｌｆｏｒＢｏｉｌｉｎｇＨｅａｔＴｒａｎｓｆｅｒｏｆＰｕｒｅＬｉｑｕｉｄｓｏｎＳｍｏｏｔｈＴｕｂｅｓＧｕｏｑｉｎ...