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101.
Comb‐type grafted hydrogels composed of polyacrylamide (PAAm) and chitosan (CT) were prepared and used for DNA adsorption. Instead of direct grafting of the acrylamide monomer onto the CT chain, semitelechelic PAAm with carboxylic acid end groups (PAAm–COOH) was synthesized by free‐radical polymerization with mercaptoacetic acid as the chain‐transfer agent, and it was grafted onto CT with amino groups. The synthesis of telechelic PAAm–COOH and the formation of comb‐type grafted hydrogels were confirmed by attenuated total reflectance/Fourier transform infrared spectroscopy and scanning electron microscopy measurements. The prepared comb‐type grafted hydrogels were used as sorbents in DNA adsorption experiments conducted at +4°C in a tris(hydroxymethyl)aminomethane/ethylenediaminetetraacetic acid solution of pH 7.4. DNA adsorption capacities as high as 2.0 × 103 μg of DNA/g of dry gel could be achieved by the comb‐type hydrogels with higher PAAm contents. This value was approximately 6 times higher than that of CT alone. In addition, the comb‐type hydrogels showed a high adsorption/desorption rate depending on the PAAm content in the hydrogel. As a result, these comb‐type hydrogels carrying higher amounts of DNA may be considered good candidates for achieving higher removal rates for anti‐DNA antibodies and for effective gene therapy systems. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
102.
Macroporous temperature‐sensitive poly {N‐[3‐(dimethylaminopropyl)] methacrylamide} hydrogels were synthesized by free‐radical crosslinking polymerization of the monomer N‐[3‐(dimethylaminopropyl)] methacrylamide and the crosslinker N,N′‐methylenebisacrylamide in aqueous solutions at 22°C. Poly(ethylene glycol) (PEG) with a molecular weight of 1000 g/mol was used as the pore‐forming agent during the polymerization reaction. The concentration of PEG in the polymerization solutions was varied between 0 and 18 wt %, whereas the crosslinker (N,N′‐methylenebisacrylamide) concentration was fixed at 2 wt % (with respect to the monomer). The effects of the PEG concentration on the thermo‐induced phase‐transition behavior and the chemical structure, interior morphology, and swelling/deswelling kinetics were investigated. Normal‐type hydrogels were also prepared under the same conditions without PEG. An interesting feature of the swelling behavior of both the normal‐type and macroporous hydrogels was the reentrant phase transition, in which the hydrogels collapsed once and reswelled as the temperature was continuously increased. Scanning electron micrographs revealed that the interior network structure of the hydrogels prepared in PEG solutions became more porous with an increase in the PEG concentration in the polymerization solution. This more porous matrix provided numerous water channels for water diffusion in or out of the matrix and, therefore, an improved responsive rate to external temperature changes during the deswelling and swelling processes. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
103.
104.
M. Çağil Akkaya Serkan Emik Gamze Güçlü Tülin Banu İyim Saadet Özgümüş 《应用聚合物科学杂志》2009,114(2):1150-1159
In this study, Acrylic acid (AA)/2‐acrylamido‐2‐methlypropane sulfonic acid (AMPS) hydrogels were prepared by free radical polymerization in aqueous solutions of AA, AMPS, and N,N‐methylenebisacrylamide (NMBA) as crosslinker. Potassium persulfate (PPS)/potassium bisulfide (PBS) were used as initiator and accelerator pair. The water absorption capacities and dye adsorption properties of the hydrogels were investigated. Adsorption properties of the hydrogels were evaluated by depending on different adsorption conditions such as different initial dye concentration and contact time. The concentrations of the dyes were determined using UV/Vis Spectrophotometer at wavelength 530 nm for safranine T (ST) and 622 nm for brilliant cresyl blue (BCB). Adsorption kinetic studies showed that pseudo‐first order kinetic model is suitable to explain the adsorption kinetic data of the hydrogels. Langmuir and Freundlich isotherm models were used to describe adsorption data. The result revealed that the adsorption of basic dyes onto hydrogels fit very well both Langmuir and Freundlich isotherms. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
105.
The electroanalytic performances of glassy carbon paste electrode (GCPE), multi-walled carbon nanotube (MWCNT)-GCPE and double-walled carbon nanotube (DWCNT)-GCPE, which include HNO3 washed/unwashed materials, were compared by monitoring cyclic voltammograms of potassium ferricyanide and catechol. Electrodes were prepared by introducing proper amount of DWCNT and MWCNT into GCPE. First untreated materials (DWCNT, MWCNT, GC μ-particles) were used in the electrodes and then HNO3-treated materials were utilized for comparing difference in electrochemical performances. The effect of treatment procedure was also examined by applying Raman spectroscopy to treated and untreated materials. Moreover, TEM images were obtained for further investigation of MWCNT and DWCNT. 相似文献
106.
Although sound AA6061-T6 joints can be produced by friction stir welding, a loss in strength takes place in the weld region. In this study, it was demonstrated that the strength of the nugget could be increased by the use of a higher strength interlayer during friction stir welding. This strength recovery cannot, however, be attainable in the heat affected zone. Although an external cooling was applied during welding in order to increase strength in the heat affected zone, it was not sufficient for achieving the required cooling condition for improved strength. 相似文献
107.
CIMT特种加工机床评述专家组 《电加工与模具》2021,(3):6-18
通过对第十七届中国国际机床展览会(CIMT 2021)参展特种加工机床的现场观摩、资料收集以及与参展厂商的交流座谈,对国内外电加工机床、激光加工机床、增材制造机床的技术特点及发展趋势进行了比较深入和系统的评述,并对特种加工机床的应用与市场发展进行了分析. 相似文献
108.
Ali Tuncay Ozyilmaz Gul Ozyilmaz Ercan Yılmaz Nureddin Çolak 《Korean Journal of Chemical Engineering》2008,25(4):846-853
The electrochemical synthesis of poly(o-anisidine) (POA) was achieved on brass (CuZn) electrode by applying two scan rates
(50 and 20 mVs−1). The synthesized polymer films were strongly adherent and homogeneous in both cases. Their corrosion performance was investigated
by AC impedance spectroscopy (EIS) technique, anodic polarization plots and open circuit potential-time curves, in 3.5% NaCl
solution. It was clearly seen that poly(o-anisidine) films provided a significant physical protection for longer exposure
time. It was shown that polymer film coated at high scan rate (CuZn/POA-H) exhibited better barrier property against the attack
of corrosive agents when compared with polymer film obtained at low scan rate (CuZn/POA-L). It was found out that poly(o-anisidine)
film synthesized at high scan rate caused a significant increase in corrosion resistance by its catalytic behavior on formation
of protective oxide layers on the surface in longer time. 相似文献
109.
The polymerization and grafting of the monomers p‐acryloyloxybenzoic acid and p‐methacryloyloxybenzoic acid were studied. Poly(acryloyloxybenzoic acid) was obtained by γ‐radiation‐induced solution polymerization and bulk melt polymerization initiated by dicumyl peroxide. Poly(methacryloyloxybenzoic acid) could be obtained only by bulk melt polymerization. The graft copolymerization of the monomers onto isotactic polypropylene was carried out in bulk. The maximum grafting was reached in shorter times at higher temperatures, and it also increased with the concentration of the monomers in the reaction medium. The thermal and crystallization behavior of the graft copolymers was studied with differential scanning calorimetry and wide‐angle X‐ray diffraction. The graft copolymerization of p‐acryloyloxybenzoic acid did not have any influence on the formation of both α forms (monoclinic) of polypropylene, whereas p‐methacryloyloxybenzoic acid led to the α2 form. The β‐crystalline modification (hexagonal) formed in poly(acryloyloxybenzoic acid)‐g‐polypropylene products at 185°C and at higher grafting temperatures and also in the second run of differential scanning calorimetry studies after fast cooling. The β form was not observed in graft copolymers of poly(methacryloyloxybenzoic acid). © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
110.
Hakan Aşkun Basri Gülbakan Ömür Çelikbıçak Cengiz Uzun Olgun Güven Bekir Salih 《应用聚合物科学杂志》2008,107(4):2714-2722
Poly(styrene-divinylbenzene), PS-DVB, microbeads were modified with 8-hydroxyquinoline (8-HQ) following nitration, reduction of NO2 to NH2, and conversion of NH2 to diazonium salt. Characterization of pristine, NO2, NH2, NN+Cl−, and 8-QH functional groups modified microbeads was made by Fourier transform-infrared spectrometry (FTIR) and porosimetry. Total reflectron-X-ray florescence spectrometer (TXRF) was used to test the affinity of the 8-HQ modified microbeads to toxic metal ions. 8-HQ-modified microbeads were used to examine the adsorption capacity, recovery, preconcentration, and the matrix elimination efficiency for Pb(II), Cd(II), Ni(II), and Co(II) ions as a function of changing pH, initial metal-ion concentrations, and also equilibrium adsorption time of the studied metal ions. Preconcentration factors for the studied toxic metal ions were found to be more than 500-fold and recovery between 93.8% and 100.6%. Ultratrace toxic metal-ion concentrations in sea water were determined easily by using modified microbeads. Reference sea-water sample was used for the validation of the method, and it was found that recovery, preconcentration, and the matrix elimination were performed perfectly. For the desorption of the toxic metal ions, 3M of HNO3 was used and desorption ratio shown to be more than 96%. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献