On the drop-weight testing of alumina/aluminum laminated composites

Laminated composites with ceramic front layers and metallic or composite backing layers have gained attractiveness as lightweight armours, as they exhibit the same ballistic performance with lower areal densities as compared to steels. Drop-weight testing (DWT) has potential for evaluating the low velocity impact behaviour of materials. This testing gives significant ideas and information about failure mechanisms and behaviour of materials under low velocity impact. In this study, DWT of alumina/aluminum laminated composites was done in order to investigate the effects of lamination type, density with respect to area and mechanical property of backing material on the low velocity ballistic performance of these composites. The experimental results showed that the laminated composite with ceramic front layer and aged-aluminum alloy as backing layer was the most effective among different investigated specimens against low velocity impact loads.     

Increasing the conversion fraction of sulfur to sodium thiosulfate with the ultrasound energy

The usage of ultrasound has gained popularity in the recent years. Ultrasonic processing means blasting liquids, usually water, with very intense sound at high frequency, producing very well mixed powerful chemical and physical reactions. This paper deals with the investigation of the effect of ultrasonic energy on the conversion fraction of sulfur in the production reaction of sodium thiosulfate which was obtained from sulfur and Na₂SO₃ solution. Concentration of Na₂SO₃ solution parameter was chosen as the constant parameter. The experiments were performed with various amplitudes of ultrasound power and in the absence and presence of ultrasound energy in various temperatures with various particle sizes. The results indicate that the conversion fraction values increase in the presence of ultrasound energy and increase at high amplitude values.     

Palladium-Catalyzed Suzuki–Miyaura Reaction Using Saturated N-Heterocarbene Ligands

Recent studies have pointed to the heptamethylbenzenium cation as a prominent intermediate in the methanol to hydrocarbons (MTH) reaction. The reactions of the heptamethylbenzenium cation in a H-beta zeolite was studied at 300 °C by feeding its corresponding base (WHSV = 0.4 h^?1). The reactant was converted completely into aliphatic products, polymethylbenzenes and coke under the employed conditions. The results testify that the proposed reaction intermediate yields the same product spectrum as methanol. The composition of the material retained in the catalyst micropores after 15 min of reaction was determined by dissolving the catalyst in 15% HF. Polymethylated benzenes (predominantly pentamethylbenzene), dihydro-trimethylnaphthalenes, and hexamethylnaphthalene were the major components. The results also support the idea that the lowest naphthalene derivative is formed from the heptamethylbenzenium cation by a molecular rearrangement. Hence, the heptamethylbenzenium cation is inherently linked to both product formation and catalyst deactivation in the MTH reaction.     

Realizations of mutative 4-ports and their applications to memstor simulations

In this paper, in addition to the universal 4-port mutator circuit introduced earlier with an adder and a subtractor block, two more 4-port mutator circuits, one with plus type (CCII+) and minus type current conveyors (CCII?), the other with a plus type current conveyor (CCII+) and one minus type current follower (CF?) are presented, their port relation matrix and their realization of different memstors are tabulated. How the transfer characteristics of the ideal mutative 4-ports with respect to frequency hold is verified using their transistor level simulations. By terminating properly two ports of the mutative 4-port simulations of a memristor with three different mutators, of a meminductor and of a memcapacitor are presented and compared also with some mutators existing in the literature.     

Single and multilayered a-SiOx:H (x < 1) thin film samples analyzed by optical absorption and small-angle X-ray scattering

Hydrogenated amorphous silicon oxygen alloy thin films (a-SiO_x:H) were prepared on glass and crystalline silicon substrates, with two different oxygen contents: x = 0.15 and x = 0.32. The deposition was realized in an RF-PECVD reactor by using the plasma of the gas mixture SiH₄ and CO₂ with tunable flow rates. The optical characterization data of the single layers were received from the optical transmittance experiments. Multilayered samples were designed upon the results of the single layers. In depositing the multilayers the repetition of the a-SiO_0.15:H/a-SiO_0.32:H kernel-pair was used. The samples were prepared as 25-pair of λ/4 layers, 3-pair of λ/4 layers and 3-pair of λ/2 layers. The inner morphologies and nanostructural contents of the films were investigated by Small-Angle X-ray Scattering (SAXS) method.     

The optimization of welding parameters for friction stir spot welding of high density polyethylene sheets

Friction stir spot welding parameters affect the weld strength of thermoplastics, such as high density polyethylene (HDPE) sheets. The strength of a friction stir spot weld is usually determined by a lap-shear test. For maximizing the weld strength, the selection of welding parameters is very important. This paper presents an application of Taguchi method to friction stir spot welding strength of HDPE sheets. An orthogonal array, the signal to noise ratio (S/N), and the analysis of variance (ANOVA) are employed to investigate friction stir welding parameter effects on the weld strength. From the ANOVA and the S/N ratio response graphs, the significant parameters and the optimal combination level of welding parameters were obtained. Experimental results confirmed the effectiveness of the method.     

Effect of ultraviolet and far infrared radiation on microbial decontamination and quality of cumin seeds

Abstract: Cumin seeds might be exposed to a high level of natural bacterial contamination, and this could potentially create a public health risk besides leading to problems in exportation. Ultraviolet (UVC) and far infrared (FIR) radiation has low penetration power, and due to that, there might be no detrimental defects to the products during a possible decontamination process. Therefore, the objective of this study was to determine the effect of UVC and FIR treatment on microbial decontamination and quality of cumin seeds. For this purpose, FIR treatment at different exposure times and temperatures were applied followed by constant UVC treatment with an intensity of 10.5 mW/cm² for 2 h. Total mesophilic aerobic bacteria of the cumin seeds were decreased to the target level of 10⁴ CFU/g after 1.57, 2.8, and 4.8 min FIR treatment at 300, 250, and 200 °C, respectively, following a 2 h UVC treatment. Under the given conditions, a complete elimination for total yeast and molds were obtained while there were no significant changes in volatile oil content and color of the cumin seeds. Consequently, combined UVC and FIR treatment was determined to be a promising method for decontamination of the cumin seeds. Practical Application: This research attempts to apply UVC and far infrared (FIR) radiation for pasteurization of cumin seeds. The data suggested that combined UVC and FIR radiation treatments can become a promising new method for pasteurization of cumin seeds without causing any detrimental defect to the quality parameters. The results of this industry partnered (Kadioglu Baharat, Mersin, Turkey— http://www.kadioglubaharat.com ) study were already applied in industrial scale production lines.     

Synthesis, characterization, UV and dielectric properties of hexagonal disklike ZnO particles embedded in polyimides

A series of novel ZnO/polyimide composite films with different ZnO contents was prepared through incorporation hexagonal disklike ZnO particles into poly(amic acid) of the pre polymer of the polyimide. The hexagonal disklike ZnO particles with a diameter of 300-500 nm were synthesized from zinc acetate and NaOH in water with citric acid. The prepared zinc oxide-polyimide composites were characterized for their structure, morphology, and thermal behavior employing Fourier transform infrared spectroscopy, scanning electron micrograph, X-ray diffraction and thermal analysis techniques. Thermal analyses show that the ZnO particles were successfully incorporated into the polymer matrix and these ZnO/polymer composites have a good thermal stability. Scanning electron microscopy studies indicate the ZnO particles were uniformly dispersed in the polymer and they remained at the original size (300-500 nm) before immobilization. All composite films with ZnO particle contents from 1 to 5 wt% show good transparency in the visible region and luminescent properties.     

Poly(azomethine-imide)s containing siloxane moities: Optical,thermal, mechanical,and morphological properties

A new series of poly(azomethine-imide)s having siloxane moities in backbone was prepared using different dianhydrides.Thermal, optical, and morphological properties of these polymers were clarified. Also, bulky  CO and  CF₃ group effects and meta or para-substituted aldeyhde effects on the mentioned properties were evaluated. The structural characterization of poly(azomethine-imide)s was carried out using a FT-IR spectroscopy. The optical properties of the polymers were performed via an UV–Vis spectrophotometer. Optical band gap of the poly(imide)s containing azomethine was calculated between 2.20 and 2.33 eV. Thermal behavior of poly(azomethine-imide)s was also studied using TG-DTA, DSC, and DMA techniques. The onset degradation temperature and percentage char values of the polyimides were found in the range from 429 to 545 °C and 22 to 35%, respectively. Thermal stability results demonstrated that benzophenone bearing poly(azomethine-imide)s have higher onset temperature, percentage char, and the glass transition temperature than poly(azomethine-imide)s derived from hexafluoroisopropylidene. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48364.     

An architectural evaluation method for conservation of traditional dwellings

Historic urban sites and traditional houses are the most important evidence of the past life style. The conservation of these traditional values in the context of conservation and revitalization of architectural heritage is in a sense the preservation of culture. The main goal of conservation is to enliven cultural properties by evaluating their architectural, historical, environmental, visual and aesthetic characteristics. These evaluation studies, which are essential in the context of conservation plans, are inevitable phases to determine the principles of the plans. This study is aimed to propose a method for the architectural evaluation phase, which is essential before conservation decisions. The proposed method is based on a gradation system. Odunpazar? district in Eski?ehir/Turkey is determined as the area to test this gradation method. It is proposed that this method explains the systematic way for evaluating architectural features belonging to historic sites whose conservation plans are to be prepared. In the study, traditional buildings are evaluated from the point of their exterior and interior architectural characteristics and classified as different value groups: A, B, C and D. This grouping will be advantageous to conservation decisions. Different technical teams may be organized to be responsible for these various value groups. As a result, a systematic approach for the determination of specialized teams and required equipment will be achieved. Thus, an accurate determination of required time and cost estimates will be realized.