Tribological Behavior of TiAlN,AlTiN, and AlCrN Coatings at Boundary Lubricating Condition

In this study, ~?3.5 µm thick multilayer titanium alumina nitride (TiAlN), alumina titanium nitride (AlTiN), and alumina chromium nitride (AlCrN) coatings were deposited on the H13 steel surface by cathodic arc physical vapor deposition (CAPVD) method. The tribological performance of the coatings was evaluated by a tribometer at boundary lubrication condition. Then, coating surfaces were observed by optical microscope, optical profilometer, and atomic force microscope to evaluate the morphological changes, wear volumes, and tribofilm thickness. Also, scanning electron microscopy (energy dispersive X-ray) and X-ray photoelectron spectrometry analyses were applied to coating surfaces for the tribochemical evolution of the tribofilm. Results showed that AlCrN coating performed the best tribological behavior at boundary lubricated condition, when compared to TiAlN and AlTiN coatings and it can be used as a wear resistant cam tappet coating in internal combustion engines.     

Optimum design of cam-roller follower mechanism using a new evolutionary algorithm

Selection of tooling to perform specific operations like drilling and milling on ceramic materials using rotary ultrasonic machining process is an important aspect to meet stringent dimensions on workpiece as well as intended performance of tool. This phenomenon is more critical for micro rotary ultrasonic machining. In the present study, an effort was made to do micro drilling operation of Ø0.3 mm tool with varying geometry, having different wall thicknesses and abrasive grain sizes using design of experiments. The effect of tool-based parameters like grain size and wall thickness has been studied on axial cutting force, radial cutting force, tool wear, edge chipping area and taper. After examining axial and radial cutting forces, it has been concluded that lower wall thickness (80 μm) tool is good for drilling operation; and higher wall thickness (100 μm) tool is good for milling operation under same material removal rate conditions. It has been also investigated that lower wall thickness (80 μm) tool has less edge chipping area and less taper and can impart high drilling depth as compared to higher wall thickness (100 and 150 μm) tool. It is also concluded that lesser grain size (15 μm) tools are advantageous in terms of edge chipping area and cutting force for drilling and milling operations as compared to higher grain size (30, 35 and 45 μm) tool at constant material removal rate. Higher grain size tools have been broken at 1.13 mm³/h material removal rate conditions due to bad profile accuracy. But higher grain size tools have worked fairly well at less material removal rate condition. Higher grain size tools produced less wear. Tool wear was found minimum in higher wall thickness (100 μm) tool having higher abrasive grain size (30 μm). Using inferred results, Ø0.3 mm drilling experiments have been carried out on six aerospace ceramic materials. Also, groove of 0.5 mm size using Ø0.3 mm optimised tool has been successfully carried out in sintered SiC.     

Investigation of current‐voltage characteristics and current conduction mechanisms in composites of polyvinyl alcohol and bismuth oxide

Temperature dependent current‐voltage (I–V) measurements of Au/Polyvinyl Alcohol + Bi₂O₃/n‐Si structure were conducted between 100 and 350 K for investigating the temperature dependence of I–V characteristics and current conduction mechanisms in the structure. Series resistance of the structure is calculated using Ohm's law and Cheungs' method. Ideality factor (n) and zero‐bias barrier height (Φ_Bo) were obtained considering thermionic emission theory. From 100 to 350 K, n changed from 32.1 to 3.54, and Φ_Bo changed from 0.27 to 0.99 eV. Obtained temperature dependent values of n and Φ_Bo suggested that thermionic emission is not the dominant current conduction mechanism. Therefore, Ln(I)–Ln(V) curves of the studied structure were plotted for investigating current conduction mechanisms in the structure and current flow is explained considering space charge limited current. Moreover, density of interface states (D_it) in the structure were calculated and its temperature dependence was investigated such that D_it values are reduced to the order of ～10¹³ eV^?1 cm^?2 from ～10¹⁴ eV^?1 cm^?2 with increasing temperature. POLYM. ENG. SCI., 54:1811–1816, 2014. © 2013 Society of Plastics Engineers     

The effect of replacing fat with oat bran on fatty acid composition and physicochemical properties of meatballs

Oat bran was used as a fat substitute in the production of meatballs. The effect of oat bran addition on the fatty acid composition, trans fatty acids, total fat, some physicochemical and sensory properties of the samples was studied. Meatballs were produced with four different formulations; the addition of 5, 10, 15 and 20% oat bran. Control samples were formulated with 25% fat addition as in commercial production. The major fatty acids were cis-oleic, palmitic and stearic acid in all the meatball samples, those with oat bran added as well as the control. Meatballs containing oat bran had lower concentrations of total fat and total trans fatty acids than the control samples. Meatballs made with 20% oat bran had the highest protein, salt and ash contents, L value (lightness), b value (yellowness), and the lowest moisture content and a value (redness). There was no significant difference among the meatball samples with respect to sensory properties, and all samples had high acceptability.     

Determination of industrial pollution effects on citrus honeys with chemometric approach

The aim of this study was to determine the levels of essential, trace and toxic elements, such as K, Ca, Fe, Cu, Al, Ni, Sn, Pb and Cd in citrus honeys from different regions (industrialized and nonindustrialized) of Hatay, Turkey. K, Ca, Na and Mg were the most abundant elements, with mean contents of 363.5, 256.6, 88.1 and 37.7 mg/kg, respectively. The trace element mean contents ranged between 0.032 and 15.58 mg/kg. Significant differences in Fe, Cu, Al, Ni, Sn, Pb, Cd, Co and Sr levels were observed between two different regions. The findings that Fe, Cu, Al, Ni, Sn, Pb, Cd, Co and Sr contents in citrus honeys from industrialized regions were higher than citrus honeys from non-industrialized regions indicate that the honeys were affected by industrial pollution. Chemometric methods were applied to classify honey according to mineral content. Cluster analysis showed three clusters corresponding to the three different regions.     

Infrared drying of button mushroom slices

The effect of different infrared power levels on the drying kinetics of button mushrooms was investigated. Mushroom slices were dried at infrared power levels of 83, 125, 167, and 209 W. The power level affected the drying and rehydration characteristics of mushroom slices. Drying time was reduced from 300 min to 40 min as the infrared power level increased from 83 to 209W. Mathematical models frequently used to represent drying of agricultural products were fitted to experimental data of mushroom drying. The parabolic model was the best for representation of mushroom drying. Effective moisture diffusivity varied from 3.81×10^?10 to 4.20×10^?9 m²/s over the infrared power levels used. The activation energy was estimated using a modified Arrhenius-type equation and calculated to be 7.55 kW/kg.     

Anticonvulsant activity of furanocoumarins and the essential oil obtained from the fruits of Heracleum crenatifolium

The anticonvulsant activity of furanocoumarins, coumarin mixture and the essential oil obtained from the fruits of Heracleum crenatifolium was examined against maximal electroshock (MES)-induced seizures in mice. Bergapten showed significant anticonvulsant activity. The furanocoumarins isolated from the fruits of the plant were identified using thin-layer chromatography, melting points and spectroscopic methods (IR, MS, ¹H NMR) as isobergapten (1), pimpinellin (2), bergapten (3), isopimpinellin (4), sphondin (5) and byak-angelicol (6). The essential oil content of the fruits were found as 5.5%. Twenty-two compounds representing 99.3% of the essential oil obtained from the fruits of H. crenatifolium were determined and the major components were identified as octanol and octyl acetate (3.1% and 88.4% respectively) by GC and GC–MS.     

Increasing single-lap joint strength by adherend curvature-induced residual stresses

Single-lap joint (SLJ) geometry is the most widely used type of adhesive joint geometry. In this joint, peel stresses occur at the overlap ends due to load eccentricity and the presence of shear-free adhesive termination surfaces. These peel stresses, along with the transverse tensile stresses which occur along the overlap longitudinal axes, and adhesive shear stresses, ultimately cause joint failure. Obviously, reductions in these stresses should result in higher joint strength and increased load capacity. To this end, we exploited elastic spring-back capability of (steel) metal adherends by initially forming curved segments of varying arc lengths and radii at overlap ends. These adherends with curved-end sections were then bonded in single-lap configuration, simply by applying sufficient bonding pressure to elastically flatten the curved segments to result in typically flat overlap sections subsequent to adhesive cure and the removal of bonding pressure. Since the elastic adherend overlap ends tend to revert back to their initial curved form, they exert compressive residual stresses on the adhesive layer in the overlap end regions. We determined that the compressive residual stresses induced in this fashion considerably increased the load capacity of SLJs subjected to tension.     

A comparative study on water-based coatings prepared in the presence of oligomeric and conventional protective colloids

Poly(vinyl acetate-co-butyl acrylate) latexes were prepared by using semi-continuous emulsion polymerization method in presence of two different protective colloids which were oligomeric N-methylol acrylamide and conventional poly(vinyl alcohol). The effects of these protective colloids on colloidal, surface and film properties of latexes were examined. Poly(vinyl acetate-co-butyl acrylate) synthesized with oligomeric N-methylol acrylamide, which was characterized by FT-IR, NMR and MALDI-TOF MS, was found to have lower viscosity, finer particle size, better latex stability, lower polydispersity, higher T_g and better film forming behavior compared to those synthesized from the poly(vinyl alcohol).