Stabilization of PCC dispersions prepared directly in the mother-liquid after synthesis through the carbonation of (hydrated) lime

Various CaCO₃-based products are often used in the form of concentrated aqueous dispersions. This study investigates the stabilization of PCC dispersions prepared directly in the mother-liquid after the carbonation of (hydrated) lime through the adsorption of a commercial sodium polyacrylate dispersant. The results demonstrate that the composition of the mother-liquid, particularly the Ca²⁺ activity, profoundly influences virtually all processes pertinent to dispersion stabilization—from the initial charging of the CaCO₃ surface in base PCC dispersions, to the surface charge regulation and dispersion stabilization efficiency of the polyacrylate dispersing agent. Rising prominence of the counterion condensation effects in Ca²⁺ rich solutions limits the conditions conducive to the surface charge regulation through dispersant adsorption to an optimum pH range of about 8-11. Furthermore, dispersion stability analysis, based on the classical DLVO theory of colloid stability, and corroborated by experimental evidence in the form of particle size distribution analyses, also indicates that optimum stability conditions for such PCC dispersions are established with small dispersant doses (0.25-0.5% per dry weight) in the pH range of about 9-11.     

添加石英对莫来石－刚玉制品结构的影响

探讨了引入石英颗粒的莫来石－刚玉制品中大气孔的成因。认为与液相的生成及其在毛细管力作用下的转移有关；与莫来石生成膨胀效应对颗粒拉紧的阻碍有关；与石英相交所引起的体积膨胀有关。     

Scalable Realistic Rendering with Many‐Light Methods

Recent years have seen increasing attention and significant progress in many‐light rendering, a class of methods for efficient computation of global illumination. The many‐light formulation offers a unified mathematical framework for the problem reducing the full lighting transport simulation to the calculation of the direct illumination from many virtual light sources. These methods are unrivaled in their scalability: they are able to produce plausible images in a fraction of a second but also converge to the full solution over time. In this state‐of‐the‐art report, we give an easy‐to‐follow, introductory tutorial of the many‐light theory; provide a comprehensive, unified survey of the topic with a comparison of the main algorithms; discuss limitations regarding materials and light transport phenomena and present a vision to motivate and guide future research. We will cover both the fundamental concepts as well as improvements, extensions and applications of many‐light rendering.     

对二位六通事故配压阀油路切换的探讨

通过对平班水电站两种不同油路切换方式的事故配压阀的结构分析以及在极端情况下两种不同油路切换方式所造成的影响,探讨了两种不同油路切换方式的事故配压阀的优劣。     

A new set distance and its application to shape registration

We propose a new distance measure, called Complement weighted sum of minimal distances, between finite sets in ${\mathbb Z }^n$ and evaluate its usefulness for shape registration and matching. In this set distance the contribution of each point of each set is weighted according to its distance to the complement of the set. In this way, outliers and noise contribute less to the new similarity measure. We evaluate the performance of the new set distance for registration of shapes in binary images and compare it to a number of often used set distances found in the literature. The most extensive evaluation uses a set of synthetic 2D images. We also show three examples of real problems: registering a set of 2D images extracted from synchrotron radiation micro-computed tomography (SR $\upmu $ CT) volumes depicting bone implants; the difficult multi-modal registration task of finding the exact location of a 2D slice of a bone implant, as imaged by a light microscope, within a 3D SR $\upmu $ CT volume of the same implant; and finally recognition of handwritten characters. The evaluation shows that our new set distance performs well for all tasks and outperforms the other observed distance measures in most cases. It is therefore useful in many image registration and shape comparison tasks.     

Photocatalytic degradation rate of oxalic acid on the semiconductive layer of n-TiO2 particles in the batch mode plate reactor Part I: Mass transfer limits

Organic compounds dissolved in water can be decomposed on a layer of n-TiO2 particles irradiated by u.v. light, which generates holes and electrons in the TiO2 material. Dissolved oxygen was used as electron scavenger and holes reacted with water to give OH radicals. The rate of degradation of the dissolved organic compounds by OH radicals is limited by the transfer of either oxygen or of theorganic compounds to the surface of n-TiO2 particles. The consequence of these limits is that, in the batch mode reactor with recirculation of the liquid, the dependence of the concentration of an organic compound on time has either a linear or an exponential form. Experiments with decomposition of oxalic acid in aqueous solutions using a plate reactor (60 cm × 120 cm) confirmed the analysis. Equations for evaluation of the mass transfer coefficient of the dissolved species to the surface of the plate reactor with a moving liquid fil m were developed for the case of the thickness of the Nernst diffusion layer being thinner than the thickness of the liquid. The experimentally obtained decomposition rate of oxalic acid was about 60 to 80% of the theoretical decomposition rate limited by oxygen flux through the film of a moving liquid. The present theory neglects the diffusion of oxygen into the porous layer of n-TiO2.     

The determination of molecular weights of polymers from critical concentrations of ternary systems polymer-polymer-solvent

The dependence of the critical concentration of the ternary system polymer-polymer-solvent on the molecular weight can be expressed by the relation where c_c is the critical concentration, M? the appropriate average of the molecular weight of both polymers; A and c_c∞ are constants for the given system. The possibility of determining the molecular weight of one of the polymers from the value c_c and the molecular weight of the known polymer with the aid of equation (1) is discussed.     

Theory of porous electrodes—XI. The positive plate of the lead-acid battery

Partial differential equations describing the transport of mass and electricity in the pores of the positive electrode of a lead acid battery were derived. The theory is based on exact transport equations and on the assumption that the solid porous matrix has a metallic conductivity. Volume changes in both phases are taken into account. Numerical solutions obtained on a computer are presented for the case where the influence of electrolyte between the electrodes can be neglected. The solutions depend on the product of electrode thickness times current density, and on the initial porosity.     

Synthesis,characterization, and antitumor activity of poly(maleic anhydride‐co‐vinyl acetate‐co‐acrylic acid)

The ternary copolymerization of maleic anhydride (MA), vinyl acetate (VA), and acrylic acid (AA) [P(MA‐co‐VA‐co‐AA)], which is considered to be an acceptor–donor–acceptor system, was carried out in 1,4‐dioxane with benzoyl peroxide as an initiator at 70°C under a nitrogen atmosphere. Constants of complex formation for the monomer systems in the study were determined by UV–visible (hydrogen‐bonding complex) and ¹H‐NMR (charge transfer complex) methods, respectively. The results show that polymerization of the P(MA‐co‐VA‐co‐AA) system proceeds by an alternating terpolymerization mechanism. It is shown that the synthesized copolymers have typical polyelectrolyte behavior, ability for reversible hydrolysis–anhydrization reactions, and semicrystalline structures. In these cases, including radical polymerization, and formation of semicrystalline structures, the hydrogen‐bonding effect plays a significant role. The in vitro cytotoxicities of the synthesized terpolymer and alternating copolymer were evaluated using Raji cells (human Burkitt lymphoma cell line). The antitumor activities of prepared anion‐active copolymers were studied using methyl–thiazol–tetrazolium colorimetric assay and 50% of the cytotoxic dose of each copolymer and terpolymer were calculated. Hydrolyzed P(MA‐co‐VA‐co‐AA) and P(MA‐alt‐AA) copolymers have sufficiently high antitumor activity, which depends on the amount of hydrogen‐bonding carboxylic groups and their regular distribution in the side chain of functional macromolecules. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 3425–3432, 2006     

CJ18．2tex赛络纱的生产实践

阐述了赛络纺纱技术的原理,探讨了F1510细纱机改造赛络纺的方法,优选了工艺参数．试验结果表明,在相同的配棉条件下,CJ18．2tex赛络纱的条干、粗细节、强力和毛羽均优于相同线密度的传统环锭纱．