Mensuration and simulation of mold filling process in semi-solid die-cast of aluminum alloy

To understand the flow trace of semi-solid slurry in mold cavity, some thermocouples were inserted in mold cavity, and the reaction timing of thermocouples showed the arrival of fluid. The filling time and rate were estimated by comparison between the experiment and calculation. The introduction of computer simulation technique based on ADSTEFAN was to predict injectionforming process and to prevent defects during trial manufacture of various parts. By comparing the formed appearance of parts in experiment and in simulation, and observing the relationship between internal defects inspected by X-ray or microscope and the flow field obtained in simulation, it was indicated that both have quite good agreement in simulation and experiment. Right predictions for cast defects resulted from mold filling can be carried out and proper direction was also proposed. The realization of numerical visualization for filling process during semi-solid die-cast process will play an important role in optimizing technology plan.     

以师范类专业认证为契机,构建完善的教学质量保障体系

以商丘师范学院为例,化学专业以专业认证为契机,以培养卓越中学化学教师为目标,为全面提升化学专业教育质量,构建与完善化学专业课程教学质量保障体系、课堂教学过程常态化内部监控机制以及化学专业本科师范类毕业生社会满意度跟踪反馈机制等方面,提出具体实施措施,并取得了初步成效.     

含钛高炉渣制备CaTiO3-多孔地质聚合物光降解吸附材料

含钛高炉渣作为固体废弃物,国内存量巨大,且其中的钛组元难以提取,导致含钛高炉渣综合利用一直没有得到有效解决。针对当前含钛高炉渣利用率低、附加值低等问题,基于含钛高炉渣成分特点,通过选择性析晶(CaTiO₃优势析出)、碱激发,制备出CaTiO₃-多孔地质聚合物的复合材料。试验结果表明,析晶温度1 400 ℃、保温1 h能够促进CaTiO₃的优势析出,而剩余氧化物以玻璃相形式存在。制备出的CaTiO₃-多孔地质聚合物材料结合了CaTiO₃高光催化活性与多孔地质聚合物比表面积大的优点,对亚甲基蓝具有优异的吸附效果,最大吸附量可达60.4 mg/g。在投加量为50 mg,2 h吸附、3 h光降解条件下,对亚甲基蓝去除率可达94.5%,在治理有机污染领域有良好的应用前景。     

黄铜中纳米级微裂纹的形核与钝化

黄铜薄膜试样在透射电镜中原位拉伸观察表明，在平衡条件下加载裂发出的位错纯化成无位错区，它是一个应变很高的异常弹性区。当缺口足够锐，外加载荷足够大时，这个非线弹性区中的应力有可能达到原子键合力，从而使纳米级微裂纹在无位错区中不连续形核，或从钝化的原裂纹顶端形核。这个微裂纹一昊形核，即使保持恒位移，也将钝化成空洞或缺口。     

Technological condition in slurry electrolysis of high-silver galena concentrate

Effects of various technological conditions such as ρ(C1^- ), ρ(Fe)T, pH value and temperature on the cell voltage, lead leaching rate and the cathodic current efficiency of the slurry electrolysis of high-silver galena concentrate were studied, and the behavior regularity of lead and silver was investigated. As a result, the suitable condition was determinedas, ρ(C1^-)230g/L, ρ(Fe)T15g/L, pH 1, temperature 70℃, electrolysis time 6h. Under such condition,adopting the cathodic current density of 150 A/m2 and the liquid-solid ratio of 15 : 1, lead powder with a purity degree of 91. 18% was got. At the same time, leaching rate of lead, leaching rate of silver and cathodic current efficiency amounted to 96.88%, 70.88% and 75.68% respectively.     

热处理对A356/6082复合板界面组织及力学性能的影响

采用液-固轧制复合技术制备A356/6082复合板,研究热处理温度对A356/6082复合板界面组织及力学性能的影响。结果表明,随着热处理温度的升高,A356铝合金一侧共晶Si组织发生颈缩、溶断、球化,并且球化现象首先在界面处发生,界面区剪切强度逐渐增大。当热处理温度为550℃时,复合界面处组织分布均匀,Si颗粒细小圆整,界面区元素得到充分扩散,元素扩散宽度约为136μm,复合板剪切强度最大值约为145MPa,复合界面在受到均匀塑性变形时,其剪切断裂方式为脆性断裂。     

我国强力推行十项措施确保节能减排目标实现

“做好下半年节能减排工作，关键是要把思想和行动统一到中央的方针政策和工作部署上来，深入贯彻落实科学发展观，继续加强和改善宏观调控，防止经济由偏快转为过热，加快结构调整和增长方式转变，把《节能减排综合性工作方案》落到实处，努力实现国民经济又好又快发展。”[第一段]     

开、停车阶段工艺冷凝液回收方法的改进

1 中压汽提装置流程及存在的问题 河南省中原大化集团公司合成氨装置采用的是Unde-AMV技术，生产工艺为天然气蒸汽转化法，在脱碳工序有大量的工艺冷凝液生成。这些冷凝液在汽提塔中利用中压蒸汽进行汽提，达标冷凝液经水处理装置处理后重新利用。其流程为：低变气进入脱碳工序，经气体冷却器（05E001）、再沸器（05E002）和脱盐水预热器（05E009）换热，冷凝的水蒸气（约35t／h）在分离器（05F001）分离后，用泵（05P006A／B）送至汽提塔（05C003）；冷凝液从塔的上部进入，     

固体超强酸合成乙酸丁酯

本文讨论了固体超强酸催化剂合成乙酸丁酯的方法，比较了各类固体超强酸的优劣，为工业化生产乙酸丁醋筛选超强酸催化剂提供极具价值的参考依据。     

交通部恢复对新沿海跨省运输油船化学品船运力审批

交通部日前发布了《关于国内沿海跨省运输油船化学品船运力调控政策的公告》，恢复对新增国内沿海跨省运输油船化学品船运力的审批。