Chemical desulfurization of petroleum fractions for ultra-low sulfur fuels

An improved desulfurization process for removing sulfur from hydro treated diesel oil based on the oxidation of thiophenic type sulfur-containing compounds with H₂O₂ and acetic acid (AcOH) using H₂SO₄ as catalyst has been studied. The experimental results show that the sulfone content in the oxidation product increased rapidly with an increase in acetic acid and sulfuric acid ratios from 1:0 to 2:1 mole ratios. The maximum DBT conversion (wt.%) was at 2:1 mole ratio of acetic acid/sulfuric acid. This oxidation process is found to be capable of removing up to 90% of the sulfur compounds in hydro treated real fuels and can provide an alternative way to meet the future sulfur environmental requirements.     

Application of pulse detonation technology for boiler slag removal

Pulse detonation technology for removing slag and fouling deposits in coal-fired utility power plant boilers offers great potential. This technology offers a potentially convenient, inexpensive, yet efficient way for on-line slag removal. This paper presents a feasibility study that includes both Computational Fluid Dynamics (CFD) simulations and laboratory experiments. CFD simulations provided visual and quantitative data to study the potential mechanisms for removal of slag. Mechanisms included direct impact, flow scrubbing, wave reflection and negative velocity impact on the back side of the tubes. Several experiments were carried out to verify the potential of the pulse detonation technology. Experiments were done using a pulse detonation engine and heat exchanger tubes with different types of slag placed in different orientations on the tubes. Tubes were placed at various distances from the detonation tube and in different configurations. The results present a strong case for the application of this technology for online slag removal. It is especially effective for removal of slag on the back sides of the tubes where other traditional methods are not very successful. A preliminary cost analysis indicated that the technology can be paid for within the first year itself and provide substantial savings in the subsequent years.     

Microbial conversion of androst‐1,4‐dien‐3,17‐dione by Mucor racemosus to hydroxysteroid‐1,4‐dien‐3‐one derivatives

BACKGROUND: A large number of bacterial, fungal and microalgal species are able to bio‐transform steroid compounds. Among them, fungi from the Mucor genus have been shown to mediate hydroxylation, oxidation, and desaturation by the double bond formation and epoxidation of various steroid substances. Mucor racemocus has not been studied for its ability to modify androst‐1,4‐dien‐3,17‐dione, a pharmaceutically important steroid precursor. RESULTS: The filamentous fungus M. racemosus was applied for bioconversion of androst‐1,4‐dien‐3,17‐dione (ADD, I ) in a 5‐day fermentation. Microbial metabolites were purified chromatographically and identified on the basis of their spectral data as 17β‐hydroxyandrost‐1,4‐dien‐3‐one ( II ), 14α‐hydroxyandrost‐1,4‐dien‐3,17‐dione ( III ), 15α‐hydroxyandrost‐1,4‐dien‐3,17‐dione ( IV ), 15α,17β‐dihydroxyandrost‐1,4‐dien‐3‐one ( V ), 14α,17β‐dihydroxyandrost‐1,4‐dien‐3‐one ( VI ), and 6β,17β‐dihydroxyandrost‐1,4‐dien‐3‐one ( VII ). CONCLUSION: Observed modifications included hydroxylation at C‐6β, C‐14α, C‐15α positions and 17‐carbonyl reduction. The best fermentation conditions for production of hydroxysteroid‐1,4‐dien‐3‐one derivatives were found to be 25 °C at 150 rpm for 5 days with a substrate concentration of 0.5 g L^?1. Copyright © 2009 Society of Chemical Industry     

Thermal,mechanical and rheological properties of poly (lactic acid)/epoxidized soybean oil blends

Summary  Poly(lactic acid) (PLA) was melt blended with epoxidized soybean oil (ESO) in an internal mixer and thermal, mechanical and rheological properties of the blends were investigated by means of differential scanning calorimetry, dynamic mechanical analysis, tensile test and small amplitude oscillatory shear rheometry. ESO lowered glass transition temperature and increased the ability of PLA to cold crystallization. The blend exhibited improved elongation-at-break along with a plastic deformation. The plasticization effect by ESO was also manifested by the lowering of dynamic storage modulus and viscosity in the melt state of the blends compared with neat PLA.     

A new study on binder performance and formulation modification of anti-corrosive primer based on ethyl silicate resin

Zinc-rich ethyl silicate coatings are quite successful in protecting steel against corrosion under severe exposing conditions. In spite of providing excellent cathodic protection to steel structure after film curing, two-component zinc-rich ethyl silicate coatings have some limitations, one of which is inadequate shelf life as a result of in-can binder gelation.     

Will energy regulations in the Gulf States make buildings more comfortable – A scoping study of residential buildings

Building envelope impacts upon energy consumption and indoor environment. The relationship between envelope components and indoor environment has become increasingly important, especially with the new emphasis on visual comfort, thermal comfort and indoor air quality. This paper examines the interaction between occupant thermal comfort and envelope component regulations in the Gulf States. The country chosen for this study is the Kingdom of Bahrain, the smallest country in the Gulf region. Simulation results and comparative studies were employed to investigate the impact of the current envelope component regulations on the internal environment. The paper focuses on residential buildings and concludes that the envelope component regulations contribute positively to the internal thermal performance. Although these envelope components are not generally the primary elements that impact upon internal thermal comfort there are circumstances when the components become very warm and occupants positioned close to them will experience discomfort. This paper shows that the thermal insulation regulation makes a small impact on thermal comfort, whereas the window regulation, particularly glazing, is more influential and that for most window areas, solar impacts are generally large.     

A study on performance of solid oxide fuel cell‐organic Rankine cycle combined system

This study presents an energetic performance analysis for a combined power generation system consisting of a solid oxide fuel cell (SOFC) and an organic Rankine cycle (ORC). In order to simulate the SOFC–ORC combined system under steady‐state conditions, a mathematical model is developed. The developed model is used to determine the potential effects caused by the changes of the design parameters on the energetic performance of the combined system. As design parameters, turbine inlet pressure, condenser temperature, fuel utilization, current density, compressor pressure ratio, and cell operating temperature are taken into account. In this regard, the electrical power and First Law efficiency are estimated by parametrical analysis and discussed comprehensively. Results of these analyses show that the efficiency is increased about 14–25% by recovering SOFC waste heat through ORC based on investigated design parameter conditions. Copyright © 2008 John Wiley & Sons, Ltd.     

Antioxidant and free radical-scavenging activities of smooth hound (Mustelus mustelus) muscle protein hydrolysates obtained by gastrointestinal proteases

We have investigated the antioxidative activity of five hydrolysates from smooth hound (Mustelus mustelus) meat obtained by various gastrointestinal proteases: crude enzyme extract, low molecular weight (LMW) alkaline protease and trypsin-like protease from M. mustelus intestine, pepsin from M. mustelus stomach, and bovine trypsin.     

Optimization of biohydrogen production by Clostridium butyricum EB6 from palm oil mill effluent using response surface methodology

Clostridium butyricum EB6 successfully produced hydrogen gas from palm oil mill effluent (POME). In this study, central composite design and response surface methodology were applied to determine the optimum conditions for hydrogen production (P_c) and maximum hydrogen production rate (R_max) from POME. Experimental results showed that the pH, temperature and chemical oxygen demand (COD) of POME affected both the hydrogen production and production rate, both individually and interactively. The optimum conditions for hydrogen production (P_c) were pH 5.69, 36 °C, and 92 g COD/l; with an estimated P_c value of 306 ml H₂/g carbohydrate. The optimum conditions for maximum hydrogen production rate (R_max) were pH 6.52, 41 °C and 60 g COD/l; with an estimated R_max value of 914 ml H₂/h. An overlay study was performed to obtain an overall model optimization. The optimized conditions for the overall model were pH 6.05, 36 °C and 94 g COD/l. The hydrogen content in the biogas produced ranged from 60% to 75%.     

The stability of hydrogen evolution activity and corrosion behavior of NiCu coatings with long-term electrolysis in alkaline solution

In this study, NiCu composite coating was electrochemically deposited on a copper electrode (Cu/NiCu) and tested for hydrogen evolution reaction (HER) in 1 M KOH solution for long-term electrolysis with the help of cathodic current–potential curves and electrochemical impedance spectroscopy (EIS) techniques. The bulk and surface composition of the coating was determined using atomic absorption spectroscopy (AAS) and energy dispersive X-ray (EDX) analysis. The surface morphology was investigated by scanning electron microscopy (SEM). The effect of electrolysis on the corrosion behavior of the Cu/NiCu electrode was also reported. It was found that the NiCu coating had a compact and porous structure with good time stability. The HER activity of the coating was stable over 120 h electrolysis and the HER mechanism was not modified during the operation. The corrosion tests showed that the corrosion resistance of the Cu/NiCu electrode changed when a cathodic current was applied to the electrolysis system.