In this paper, lead-free (1-
x)(Bi
0.5Na
0.5)
0.94Ba
0.06TiO
3-
xBiAlO
3 (BNBT-BA,
x?=?0, 0.010, 0.015, 0.020, 0.025, and 0.030) piezoelectric ceramics were synthesized using a conventional solid-state reaction method. The effect of BiAlO
3 concentration on dielectric, ferroelectric and piezoelectric properties were investigated. The ferroelectric and piezoelectric properties of BNBT ceramics are significantly influenced by the presence of BA. In the composition range studied, X-ray diffraction revealed a perovskite phase with the coexistence of rhombohedral and tetragonal phases. The temperature dependence of dielectric properties showed that the depolarization temperature (
T d) shifted towards lower temperatures and that the degree of diffuseness of the phase transition around
T d and
T m became more obvious with increasing BiAlO
3 content. The remanent polarization increased with increasing BA, and reached a maximum value of 30 μC/cm
2 at
x?=?0.020. As a result, at
x?=?0.020, the piezoelectric constant (
d 33) and the electromechanical coupling factor (
k p) of the ceramics attained maximum values of 188 pC/N and 34.4 %, respectively. These results indicate that BNBT-BA ceramics is a promising candidate for lead-free piezoelectric materials.
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